Importance of inherited rift margin structures in the early North Alpine Foreland Basin, Switzerland

The earliest evolution of the North Alpine Foreland Basin in Switzerland was characterized by deposition in small, structurally partitioned sub-basins during the Late Cretaceous and Early Tertiary, rather than in a single, large foredeep. These sub-basins, which were probably located between old rift margin fault-blocks reactivated during Alpine compression, were incorporated into the thrust wedge during thin-skinned deformation. In eastern Switzerland, the most external sub-basins with respect to the orogenic wedge (North Helvetic Flysch and Blattengrat units) have at their base an unconformity attributed to flexural forebulge erosion. More internal sub-basins (Sardona and Prättigau units) contain a conformable succession from the underlying passive margin stage and are dominated by deep-water sedimentation. In western Switzerland, both external sub-basins, now found in the Helvetic Diablerets and Wildhorn nappes, and deep-water internal sub-basins (Höchst-Meilleret Flysch, Neisen Flysch, Tarentaise Flysch) preserve a well-developed basal unconformity. Comparison of the eastern and western Swiss transects shows important intrabasinal lateral variations to be present. The western Swiss area was a topographic high for much of the Late Cretaceous and Early Tertiary; this is demonstrated by the increased chronostratigraphic gap at the karstified basal unconformity surface in western Switzerland. The strata onlapping this unconformity young to the west, suggesting that drowning of the emergent area was delayed compared with the east. In addition, reactivation and uplift of the rift margin structures occurred earlier in western Switzerland compared with eastern Switzerland. There is therefore strong evidence for lateral topographic gradients in the early foreland basin caused by differential amounts of tectonic reactivation of rift margin structures. In the early foreland basin-fill, these lateral variations are as important in determining depositional patterns as strike-normal changes across the basin.     

Denitrification and Pesticide Elimination in Drinking Water Treatment with the Biodegradable Polymer Poly(ϵ‐caprolactone) (PCL)

A combination of denitrification and pesticide sorption with the biodegradable polymer poly(?‐caprolactone) (PCL) was examined. The function of PCL is to act as carbon source and carrier for the bacteria and simultaneously as sorbent for the pesticide endosulfan. In a short‐term examination (1 month) the addition of the pesticide endosulfan to a continuous‐flow fixed‐bed reactor resulted in an inhibition of biomass production without reduction of the denitrification performance. However in a long‐term semi‐batch reactor test (6 months) biomass production and partly denitrification rates were affected. No significant differences in microbial composition between the reactors were observed. Regardless of the type of reactor or presence of endosulfan, Acidovorax facilis was the main constituent.     

Impacts « multi-échelle » d'un échange (Mg,Ca)–Pb et ses conséquences sur l'augmentation de la perméabilité d'une bentonite

The article addresses the structural effects of solutions of lead nitrate on a suspended or compacted bentonite. A permeability increase is observed on compacted clay. Investigating the composition of output solution, using X-Rays Diffusion at Small Angles and Scanning Electron Microscopy, this permeability increase is explained from structural variations at nanometric (reduction of particle size) and micrometric scales (microfissuration of aggregates). To cite this article: N. Jozja et al., C. R. Geoscience 335 (2003).     

Understanding the solar dynamo

Paul Bushby and Joanne Mason take a look at the workings of the Sun's dynamo, from the development of physical theory through current ideas and methods, to the possibilities for future understanding of this enigmatic magnetic engine.     

Spatial and temporal variability of coastal storms in the North Atlantic Basin

Over the past three to four decades, there has been a growing awareness of the important controls exerted by large-scale meteorological events on coastal systems. For example, definitive links are being established between short-term (timescales of 5–10 years) beach dynamics and storm frequency. This paper assesses temporal variability of coastal storms (both tropical and extratropical) and the wave climatology in the North Atlantic Basin (NAB), including the Gulf of Mexico. With both storm types, the empirical record shows decadal scale variability, but neither demonstrates highly significant trends that can be linked conclusively to natural or anthropogenic factors. Tropical storm frequencies have declined over the past two or three decades, which is perhaps related to recent intense and prolonged El Niños. Some forecasts predict higher frequencies of tropical storms like that experienced from the 1920s to the 1960s to occur in coming decades. Results from general circulation models (GCMs) suggest that overall frequencies of tropical storms could decrease slightly, but that there is potential for the generation of more intense hurricanes. These data have important implications for the short-term evolution of coastal systems.

There is strong suggestion that extratropical systems have declined overall over the past 50–100 years, but that there is an increase in frequency of very powerful storms, especially at higher latitudes. Both ENSO and the North Atlantic Oscillation (NAO) are shown to have associations with frequencies and tracking of these systems. These empirical results are in general agreement with GCM forecasts under global warming scenarios. Analyses of wave climatology in the NAB show that the last two to three decades have been rougher at high latitudes than several decades prior, but this more recent sea state is similar to conditions from about 100 years ago. The recent roughness at sea seems to be related to high NAO index values, which are also expected to increase with global warming. Thus, when coupled to an anticipated continued rise in global sea level, this trend will likely result in increasing loss of sediment from the beach-nearshore system resulting in widespread coastal erosion.     

Chemical speciation of copper and zinc in surface waters of the western Black Sea

The chemical speciation of Cu and Zn was investigated by voltammetric titration methods in the surface waters (10 m) of the western Black Sea during an Istanbul–Sevastopol cruise conducted in November 1998. Supporting parameters (temperature (T), salinity (S), pH, alkalinity (Alk), suspended particulate matter (SPM) and dissolved and particulate ²³⁴Th) were obtained in order to distinguish hydrographic features against involvement of the metals in biogeochemical processes. In the Turkish continental slope region, the cruise track intersected a narrow vein of colder water originating on the western shelf. The core of this cold water vein was characterised by a relatively low salinity, higher specific alkalinity and higher metal (especially Cu) and metal-binding ligand concentrations.A very large portion of Cu (93–99.8%) and Zn (82–97%) was organically complexed. The degree of complexation was highest in shelf waters and lowest in the central gyre. Titration data for Cu were modelled by two classes of organic binding ligands characterised by (C_L1=3–12 nM, log K₁′=13.1–13.9) and (C_L2=20–70 nM, log K₂′=9.4–11.2). These ligands occurred mainly in the ‘dissolved’ phase, as defined by 0.4-μm filtration. The stronger Cu-binding ligand seemed to be produced in situ in response to Cu concentration, whereas the weaker Cu-binding ligand appeared to be derived from terrestrial sources and/or reducing shelf sediments. Titration results for Zn were generally represented by one class of ligands (C_L1=8–23 nM, log K₁′=9.4–10.2), which were almost uniformly distributed between the ‘dissolved’ (78±8%) and the particulate phase (22±8%). The concentration of these strong Zn-binding ligands showed a very good correlation with SPM (r²=0.64), which improved when the dissolved ligands alone were considered (r²=0.78). It is hypothesised that these ligands were produced in situ by the bacterial breakdown of particulate organic matter.