J-type carbon stars in the Large Magellanic Cloud

A sample of 1497 carbon stars in the Large Magellanic Cloud (LMC) has been observed in the red part of the spectrum with the 2dF facility on the Anglo-Australian Telescope. Of these, 156 have been identified as J-type (i.e. ¹³C-rich) carbon stars using a technique which provides a clear distinction between J stars and the normal N-type carbon stars that comprise the bulk of the sample, and yields few borderline cases. A simple two-dimensional classification of the spectra, based on their spectral slopes in different wavelength regions, has been constructed and found to be related to the more conventional c and j indices, modified to suit the spectral regions observed. Most of the J stars form a photometric sequence in the   K − ( J − K )  colour–magnitude diagram, parallel to and 0.6 mag fainter than the N-star sequence. A subset of the J stars (about 13 per cent) are brighter than this J-star sequence; most of these are spectroscopically different from the other J stars. The bright J stars have stronger CN bands than the other J stars and are found strongly concentrated in the central regions of the LMC. Most of the rather few stars in common with Hartwick and Cowley's sample of suspected CH stars are J stars. Overall, the proportion of carbon stars identified as J stars is somewhat lower than has been found in the Galaxy. The Na D lines are weaker in the LMC J stars than in either the Galactic J stars or the LMC N stars, and do not seem to depend on temperature.     

The evolution of Rapid Burster outbursts

We describe the evolutionary progression of an outburst of the Rapid Burster. Four outbursts have been observed with the Rossi X-Ray Timing Explorer between 1996 February and 1998 May, and our observations are consistent with a standard evolution over the course of each. An outburst can be divided into two distinct phases. Phase I is dominated by type I bursts, with a strong persistent emission component; it lasts for 15–20 d. Phase II is characterized by type II bursts, which occur in a variety of patterns. The light curves of time-averaged luminosity for the outbursts show some evidence for reflares, similar to those seen in soft X-ray transients. The average recurrence time for Rapid Burster outbursts during this period was 218 d, in contrast to an average ∼180‐d recurrence period observed during 1976–1983.     

Densities Probed by Coronal Type III Radio Burst Imaging

We present coronal density profiles derived from low-frequency (80?–?240 MHz) imaging of three Type III solar radio bursts observed at the limb by the Murchison Widefield Array (MWA). Each event is associated with a white-light streamer at larger heights and is plausibly associated with thin extreme-ultraviolet rays at lower heights. Assuming harmonic plasma emission, we find average electron densities of 1.8\(\times10^{8}\) cm^?3 down to 0.20\(\times10^{8}\) cm^?3 at heights of 1.3 to 1.9 R_⊙. These values represent approximately 2.4?–?5.4× enhancements over canonical background levels and are comparable to the highest streamer densities obtained from data at other wavelengths. Assuming fundamental emission instead would increase the densities by a factor of four. High densities inferred from Type III source heights can be explained by assuming that the exciting electron beams travel along overdense fibers or by radio propagation effects that may cause a source to appear at a larger height than the true emission site. We review the arguments for both scenarios in light of recent results. We compare the extent of the quiescent corona to model predictions to estimate the impact of propagation effects, which we conclude can only partially explain the apparent density enhancements. Finally, we use the time- and frequency-varying source positions to estimate electron beam speeds of between 0.24 and 0.60 c.     

Evolution of CO on Titan

The early evolution of Titan's atmosphere is expected to produce enrichment in the heavy isotopomers of CO, ¹³CO and C¹⁸O, relative to ¹²C¹⁶O. However, the original isotopic signatures may be altered by photochemical reactions. This paper explains why there is no isotopic enrichment in C in Titan's atmosphere, despite significant enrichment of heavy H, N, and O isotopes. We show that there is a rapid exchange of C atoms between the CH₄ and CO reservoirs, mediated by the reaction ¹CH₂+*CO→¹*CH₂+CO, where *C is ¹³C. Based on recent laboratory measurements, we estimate the rate coefficient for this reaction to be 3.2×10⁻¹² cm³ s⁻¹ at the temperature appropriate for the upper atmosphere of Titan. We investigate the isotopic dilution of CO using the Caltech/JPL one-dimensional photochemical model of Titan. Our model suggests that the time constant for isotopic exchange through the above reaction is about 800 Myr, which is significantly shorter than the age of Titan, and therefore any original isotopic enhancement of ¹³C in CO may have been diluted by the exchange process. In addition, a plausible model for the evolution history of CO on Titan after the initial escape is proposed.     

The isotopic composition of atmospheric argon and 40Ar/39Ar geochronology: Time for a change?

A redetermination of the isotopic composition of atmospheric argon by Lee, J.-Y., Marti, K., Severinghaus, J.P., Kawamura, K., Yoo, H.-S., Lee, J.B., Kim, J.S. [2006. A redetermination of the isotopic abundances of atmospheric Ar. Geochimica et Cosmochimica Acta 70, 4507–4512] represents the first refinement since the work of Nier [1950. A redetermination of the relative abundances of the isotopes of carbon, nitrogen, oxygen, argon, and potassium. Physical Reviews 77, 789–793]. The new ⁴⁰Ar:³⁸Ar:³⁶Ar proportions imply <1% adjustments to ⁴⁰Ar/³⁹Ar ages in all but exceptional cases of very young and/or K-poor and/or Ca-rich samples, or cases in which samples are grossly under- or over-irradiated. Analytical protocols employing atmospheric argon to determine mass discrimination corrections are insensitive to the effects of revision on the air correction, but are subject to non-negligible adjustments arising from expanded heavy to light isotope ratios attending the increased mass discrimination correction. The competing effects of increased ⁴⁰Ar/³⁹Ar and ⁴⁰Ar/³⁷Ar ratios render the adjustments a function of sample chemistry and neutron irradiation parameters. The improved precision of atmospheric ⁴⁰Ar/³⁶Ar and ³⁸Ar/³⁶Ar permits increasingly sensitive detection of departures from atmospheric values. Non-atmospheric initial ⁴⁰Ar/³⁶Ar values are increasingly well-documented in volcanic materials, including subatmospheric values correlated with ³⁸Ar/³⁶Ar in a trend consistent with kinetic mass fractionation whereby incomplete equilibration between magma and atmosphere favors light isotope enrichment in the magma. The detailed mechanism(s) of such fractionation are unclear and must be clarified by further study. A detectable increase in atmospheric ⁴⁰Ar/³⁶Ar in the past 800 ka [Bender, M.L., Barnett, B., Dreyfus, G., Jouzel, J., Porcelli, D., 2008. The contemporary degassing rate of ⁴⁰Ar from the Earth. Proceedings of the National Academy of Sciences 105, 8232–8237] suggests that ages of late Quaternary (e.g., <100 ka) materials incorporating large amounts of atmospheric argon such as biotite may be underestimated by as much as 100% if a modern atmospheric ⁴⁰Ar/³⁶Ar value is erroneously assumed, unless air argon is used to determine mass discrimination. Further evaluation of the evolution of paleoatmospheric ⁴⁰Ar/³⁶Ar, and the fidelity with which argon trapped in igneous materials reflects this, would be very productive. The use of isochrons rather than model (e.g., plateau) ages mitigates the vagaries associated with uncertain trapped argon isotope ratios, and the importance of strategies to derive statistically valid isochrons is underscored.     

Andesitic magma degassing investigated through H2O vapour–melt partitioning of halogens at Soufrière Hills Volcano, Montserrat (Lesser Antilles)

Magma degassing at Soufrière Hills Volcano (SHV) is characterised by an almost permanent SO₂ flux and a HCl production rate which mainly depends on dome growth rate. Degassing processes have been studied through textural, H₂O and halogen analyses of clasts collected between 1995 and 2006 on the dome and in pyroclastic flows and vulcanian eruption deposits. Cl, Br and I are strongly depleted in melts during H₂O degassing with no significant Cl–Br–I fractionation, whereas F is almost unaffected. All magmas erupted at SHV have followed a multi-step degassing path from the magma chamber up to a shallow depth ( 1 km, P  20 MPa). From that depth, however, effusive and explosive paths are distinct; vulcanian eruptions are the result of closed system degassing (CSD), while effusive dome growth is the result of CSD up to a very shallow depth (≤ 200 m, P  5–2 MPa) followed by open system degassing (OSD). CSD is modelled using the H₂O solubility law, the perfect gas law and partition coefficients of halogens between a rhyolitic melt and H₂O vapour (d_v − lⁱ). Gas loss characteristic of OSD is modelled using a Rayleigh law. Degassing induced crystallisation is introduced through the ratio of crystallisation and degassing rates, which ranges from 150–500. d_v − l^Cl for OSD ranges between 50–300, increasing with melt Cl content. For CSD, the lower effective d_v − l^Cl ( 20) is attributed to kinetic effects.

Dome forming activity has a greater impact on atmospheric chemistry than vulcanian eruptions because OSD is much more efficient at extracting halogens. The model shows that HCl flux is a good proxy for the dome forming eruption rate. Comparison between model and measured gas compositions suggests a high HBr–BrO conversion rate (BrO/Total Br  1/3) in the SHV gas plume.

The degassing behaviour of Cl, Br and I implies similar Cl/Br ( 160) and Br/I ( 90) in initial melts, volcanic clasts and high temperature gases. The low Cl/Br at SHV compared to other island arcs ( 250–300) is attributed to a shallow, pre-eruptive Br enrichment. The almost permanent dome extrusion at SHV since 1995 has likely had a significant regional atmospheric impact because of the very efficient effusive degassing and the high conversion rate of halogens into reactive species within the gas plume.     

Structural controls on groundwater flow and groundwater salinity in the Spicers Creek catchment,Central West region,New South Wales

Saline seepage zone development, and hence the onset of dryland salinity, is a major environmental problem occurring within the Spicers Creek catchment. The primary objective of this paper was to identify previously unmapped faults and show the correlation between these faults and groundwater salinization. As identified from this study, there is a close association between geological structural features and the formation of saline seepage zones. The most saline groundwaters in the catchment were encountered where two geological structures join and form a fault intersection. These saline groundwaters are found at various depths within the fractured aquifers, and changes in groundwater chemistry in the aquifers are associated with the presence of fault zones. ¹⁸O and δ²H stable isotopes, together with ⁸⁷Sr/⁸⁶Sr isotopic ratios, indicate that groundwaters within the fault zones are enriched in ¹⁸O and have a strontium signature similar to seawater. This study identifies several geological structures in the Spicers Creek catchment and demonstrates that groundwaters with the highest salinity arise where fault intersections occur. The results of this study may be used to interpret further the mechanisms leading to seepage zone formation in dryland salinity‐affected catchments located throughout the Central West region of New South Wales, Australia. Copyright © 2006 John Wiley & Sons, Ltd.     

Early‐stage aeolian protodunes: Bedform development and sand transport dynamics

Early‐stage aeolian bedforms, or protodunes, are elemental in the continuum of dune development and act as essential precursors to mature dunes. Despite this, we know very little about the processes and feedback mechanisms that shape these nascent bedforms. Whilst theory and conceptual models have offered some explanation for protodune existence and development, until now, we have lacked the technical capability to measure such small bedforms in aeolian settings. Here, we employ terrestrial laser scanning to measure morphological change at the high frequency and spatial resolution required to gain new insights into protodune behaviour. On a 0.06 m high protodune, we observe vertical growth of the crest by 0.005 m in two hours. Our direct measurements of sand transport on the protodune account for such growth, with a reduction in time‐averaged sediment flux of 18% observed over the crestal region. Detailed measurements of form also establish key points of morphological change on the protodune. The position on the stoss slope where erosion switches to deposition is found at a point 0.07 m upwind of the crest. This finding supports recent models that explain vertical dune growth through an upwind shift of this switching point. Observations also show characteristic changes in the asymmetric cross‐section of the protodune. Flow‐form feedbacks result in a steepening of the lee slope and a decline in lower stoss slope steepness (by 3°), constituting a reshaping of protodune form towards more mature dune morphology. The approaches and findings applied here, (a) demonstrate an ability to quantify processes at requisite spatial and temporal scales for monitoring early‐stage dune evolution, (b) highlight the crucial role of form‐flow feedbacks in enabling early‐stage bedform growth, alluding to a fluctuation in feedbacks that require better representation in dune models, and (c) provide a new stimulus for advancing understanding of aeolian bedforms. Copyright © 2017 John Wiley & Sons, Ltd.