The assessment of environmental pollution caused by mining and metallurgy wastes from highly polluted post-industrial regions in Southern Poland

Stored metallurgy and mining wastes contain relatively high amounts of potentially toxic elements. To monitor the distribution of contaminants originating from dumps, the chemical and physical properties of the wastes must be characterised. In this study, the chemical properties of wastes deposited in two different locations in Southern Poland (Szklary and Zloty Stok) were evaluated. Heaps located in Zloty Stok contain wastes from gold mineralisation comprising arsenic while wastes in Szklary originate from a factory that produced an iron-nickel alloy. In Szklary the total concentrations of Ca, Mg, Fe, Zn, Mn, Cr, Co, Cu, Ni, Tl, Ag, Cd and Pb were determined, while in Zloty Stok also As is an important contaminant. To assess the risk of contamination of the surrounding environment and to select the proper method for removing the contaminants, information on the distribution of elements between operationally defined phases must be obtained. For this purpose, a six-step sequential extraction was used. The mobility of most elements in the wastes from Szklary and Zloty Stok was relatively low; however, the large amount of As, 40–180 mg L^?1, that could be released to environment in case of Zloty Stok was high. The results of fractionation studies indicated that Ag, Cd, Tl, Co, Cu, Cr, Pb, Zn and Mn may be released into environment under low pH and low redox potential conditions, which can be induced by bacterial activity.     

Changes in the biota and sediments of glacial Lake Koźmin, Poland, during the late Saalian (Illinoian)

Upper Saalian (Illinoian) glaciolacustrine deposits in central Poland, preserved in a tectonic graben, were exposed in an opencast lignite mine and investigated using sedimentological and micro-paleontological methods. The extraglacial lake sediments provide the first records of late Saalian cladoceran communities in central Europe, recovered from glaciolacustrine deposits. Sedimentation was dominated by a supply of clastics that fluctuated with the seasons, forming rhythmites. In addition to seasonal cyclicity, sedimentary and environmental conditions changed every several years to decades, with periods of increased inflow to the lake delivering sandy material, and periods of almost stagnant water dominated by suspension settling. The sediments contain Cladocera assemblages that indicate the lake was initially deep, oligotrophic, and filled with moderately cold water. Changes in Cladocera community composition and abundance were perhaps responses to climate seasonality. Zones without Cladocera were associated with seasons of higher inflow and sediment supply, and directly or indirectly, with tectonic activity in the graben. Earthquakes, documented by the presence of seismites, caused not only deformation of unconsolidated lake-bottom sediments, but possibly also changes in habitat characteristics. Combined sedimentological and biological data were used to infer the lake’s history and show that deposits of glaciolacustrine lakes can be used as indicators of past ecological and climate changes.     

Assessment of Alaska’s North Slope Oil Field Capacity to Sequester CO2

The capacity of 21 major fields containing more than 95% of the North Slope of Alaska’s oil were investigated for CO₂ storage by injecting CO₂ as an enhanced oil recovery (EOR) agent. These fields meet the criteria for the application of miscible and immiscible CO₂-EOR methods and contain about 40 billion barrels of oil after primary and secondary recovery. Volumetric calculations from this study indicate that these fields have a static storage capacity of 3 billion metric tons of CO₂, assuming 100% oil recovery, re-pressurizing the fields to pre-fracturing pressure and applying a 50% capacity reduction to compensate for heterogeneity and for water invasion from the underlying aquifer. A ranking produced from this study, mainly controlled by field size and fracture gradient, identifies Prudhoe, Kuparuk, and West Sak as possessing the largest storage capacities under a 20% safety factor on pressures applied during storage to avoid over-pressurization, fracturing, and gas leakage. Simulation studies were conducted using CO₂ Prophet to determine the amount of oil technically recoverable and CO₂ gas storage possible during this process. Fields were categorized as miscible, partially miscible, and immiscible based on the miscibility of CO₂ with their oil. Seven sample fields were selected across these categories for simulation studies comparing pure CO₂ and water-alternating-gas injection. Results showed that the top two fields in each category for recovery and CO₂ storage were Alpine and Point McIntyre (miscible), Prudhoe and Kuparuk (partially miscible), and West Sak and Lisburne (immiscible). The study concludes that 5 billion metric tons of CO₂ can be stored while recovering 14.2 billion barrels of the remaining oil.     

A Bayesian estimator for linear calibration error effects in thermal remote sensing

The Bayesian land surface temperature estimator previously developed has been extended to include the effects of imperfectly known gain and offset calibration errors. It is possible to treat both gain and offset as nuisance parameters and, by integrating over an uninformative range for their magnitudes, eliminate the dependence of surface temperature and emissivity estimates upon the exact calibration error.     

Aqueous alteration affecting the irregular outer planets satellites: Evidence from spectral reflectance

The surface reflectance properties of the irregular outer planets satellites are probed for evidence for the presence of aqueous alteration products on their surfaces using the strong correlation between the 3.0-μm water of hydration absorption feature and the 0.7-μm Fe²⁺ → Fe³⁺ oxidized iron feature seen in low-albedo asteroid reflectances, in an effort to expand our understanding of the composition of the precursor bodies from which the dynamical satellite clusters are derived. Equations converting Johnson V and Kron-Cousins RI photometry to Eight Color Asteroid Survey v (0.550 μm), w (0.701 μm), and x (0.853 μm) photometry are derived from relationships defined by Howell (1995, Ph.D. thesis), and coupled with an algorithm previously defined to detect the presence of the 0.7-μm absorption feature in ECAS asteroid photometry [Vilas, F., 1994. Icarus 111, 456-467]. Broadband VRI photometry of Ch-class Asteroid 19 Fortuna acquired during 2004 confirms the efficacy of this method of identifying the presence of the 0.7-μm feature. Photometric observations of many recently discovered irregular outer jovian, saturnian, uranian, and neptunian satellites, coupled with limited asteroid spectroscopy, were examined for the presence of aqueous alteration. The dynamical clusters of outer irregular jovian satellites are mixed between objects that do and do not show this absorption feature. Multiple observations of some objects test both positively and negatively, similar to the surface variegation that has been observed among many C-class asteroids in the main asteroid belt. Evidence for aqueous alteration on these jovian satellites augers for an origin in or near the same location as the asteroids now occupying the aqueous alteration zone (2.6-3.5 AU), at heliocentric distances internal to Jupiter's orbit. Among the saturnian irregular satellites, only S IX Phoebe shows limited evidence of aqueous alteration from ground-based observations. The other satellites show no sign of this feature, and have general reflectance properties very similar to the D-class asteroids, supporting an origin for their precursor bodies in the outer Solar System, perhaps the Centaur region. Only two uranian satellites were tested: U XVII Caliban tests positively for the feature. The differences in surface reflectance properties support the idea that Caliban and U XVI Sycorax derive from separate parent bodies. One observation of neptunian satellite N II Nereid shows no sign of this absorption feature.     

J-type carbon stars in the Large Magellanic Cloud

A sample of 1497 carbon stars in the Large Magellanic Cloud (LMC) has been observed in the red part of the spectrum with the 2dF facility on the Anglo-Australian Telescope. Of these, 156 have been identified as J-type (i.e. ¹³C-rich) carbon stars using a technique which provides a clear distinction between J stars and the normal N-type carbon stars that comprise the bulk of the sample, and yields few borderline cases. A simple two-dimensional classification of the spectra, based on their spectral slopes in different wavelength regions, has been constructed and found to be related to the more conventional c and j indices, modified to suit the spectral regions observed. Most of the J stars form a photometric sequence in the   K − ( J − K )  colour–magnitude diagram, parallel to and 0.6 mag fainter than the N-star sequence. A subset of the J stars (about 13 per cent) are brighter than this J-star sequence; most of these are spectroscopically different from the other J stars. The bright J stars have stronger CN bands than the other J stars and are found strongly concentrated in the central regions of the LMC. Most of the rather few stars in common with Hartwick and Cowley's sample of suspected CH stars are J stars. Overall, the proportion of carbon stars identified as J stars is somewhat lower than has been found in the Galaxy. The Na D lines are weaker in the LMC J stars than in either the Galactic J stars or the LMC N stars, and do not seem to depend on temperature.