Coastal uplift rate at Matanzas (Cuba) inferred from MIS5e phreatic overgrowths on speleothems

Many morphological elements in Cuba's landscape (e.g. marine terraces, tidal notches) demonstrate that coastal uplift has taken place, but the rate at which this occurs is not known. Carbonate phreatic overgrowths on speleothems have been found in a cave in Central North Cuba, ~1 km from the present coastline at 16 m asl. They form exceptional and unique mushroom‐shaped speleothems and balconies decorating the walls of the rooms. These phreatic overgrowths on speleothems (POS) formed at the oscillating air–water interface in sea‐level controlled anchialine lakes. U/Th dating of these overgrowths suggests ages that are compatible with the Marine Isotope Stage 5e (i.e. 130–115 ka). These POS have fixed this sea‐level highstand and demonstrate that this part of Cuba has been subjected to a much lower uplift rate than previously reported, that is, less than 0.1 mm/year since the last interglacial.     

Fluid‐fluxed melting and melt loss in a syntectonic contact metamorphic aureole from the Variscan eastern Pyrenees

Open‐system behaviour through fluid influx and melt loss can produce a variety of migmatite morphologies and mineral assemblages from the same protolith composition. This is shown by different types of granulite facies migmatite from the contact aureole of the Ceret gabbro–diorite stock in the Roc de Frausa Massif (eastern Pyrenees). Patch, stromatic and schollen migmatites are identified in the inner contact aureole, whereas schollen migmatites and residual melanosomes are found as xenoliths inside the gabbro–diorite. Patch and schollen migmatites record D1 and D2 structures in folded melanosome and mostly preserve the high‐T D2 in granular or weakly foliated leucosome. Stromatic migmatites and residual melanosomes only preserve D2. The assemblage quartz–garnet–biotite–sillimanite–cordierite±K‐feldspar–plagioclase is present in patch and schollen migmatites, whereas stromatic migmatites and residual melanosomes contain a sub‐assemblage with no sillimanite and/or K‐feldspar. A decrease in X _Fe (molar Fe/(Fe + Mg)) in garnet, biotite and cordierite is observed from patch migmatites through schollen and stromatic migmatites to residual melanosomes. Whole‐rock compositions of patch, schollen and stromatic migmatites are similar to those of non‐migmatitic rocks from the surrounding area. These metasedimentary rocks are interpreted as the protoliths of the migmatites. A decrease in the silica content of migmatites from 63 to 40 wt% SiO₂ is accompanied by an increase in Al₂O₃ and MgO+FeO and by a depletion in alkalis. Thermodynamic modelling in the NCKFMASHTO system for the different types of migmatite provides peak metamorphic conditions ~7–8 kbar and 840 °C. A nearly isothermal decompression history down to 5.5 kbar was followed by isobaric cooling from 840 °C through 690 °C to lower temperatures. The preservation of granulite facies assemblages and the variation in mineral assemblages and chemical composition can be modelled by ongoing H₂O‐fluxed melting accompanied by melt loss. The fluids were probably released by the crystallizing gabbro–diorite, infiltrating the metasedimentary rocks and fluxing melting. Release of fluids and melt loss were probably favoured by coeval deformation (D2). The amount of melt remaining in the system varied considerably among the different types of migmatite. The whole‐rock compositions of the samples, the modelled compositions of melts at the solidus at 5.5 kbar and the residues show a good correlation.     

Maada’oonidiwag gete-dibaajimowen (“sharing old stories”): reflections on a place-based reparatory research partnership in Nbisiing Anishinaabeg Territory

In this paper, we reflect on an emerging community-based partnership rooted in place-based reparative research. Braiding knowledges (Atalay, 2012) from Nbisiing Anishinaabeg communities, northern Ontario universities, and multi-scalar museums, the partnership focuses on repatriation, reparative environmental histories, and action-based research in the context of settler colonialism and climate change. We reflect on ongoing projects that attempt to put Anishinaabe gikendaasowin (knowledge) into action alongside historical geographical research. We discuss how the partnership resonates with community geography values of relationship, collaboration, equity, and reciprocity, and urge non-Indigenous geographers to acknowledge how Indigenous knowledges and approaches have shaped these ideas long before geography became a discipline. We contend that historical geographers have a deeper role to play in community geography scholarship, citing examples of two projects related to (1) repatriation of Anishinaabeg cultural heritage and (2) storymapping through historical Geographic Information Systems (HGIS). However, we argue, geographers must continue to acknowledge their own positionality in a discipline that was built through settler colonial violence and knowledge production. Finally, we reflect on the role of academic institutions in facilitating First Nation-university-museum partnerships through access to funding, space, and databases, while addressing the challenges of relying on institutional support for reparatory and decolonizing projects.

     

Influence of dissolved organic carbon on photochemically mediated cycling of hydrogen peroxide in rainwater

The influence of sunlight and dissolved organic carbon (DOC) on the photochemically mediated cycling of hydrogen peroxide (H₂O₂) was investigated in rainwater samples collected in Wilmington, North Carolina USA. Upon exposure to simulated sunlight 14 of 19 authentic rainwater samples exhibited significant decreases in H₂O₂. The concentration of hydrogen peroxide did not change significantly in organic-free synthetic rainwater spiked with H₂O₂ in the light or in dark controls suggesting that the loss was not due to direct photolysis or dark mediated reactions. There was a significant correlation between pseudo-first order rate constants of H₂O₂ decay and initial H₂O₂ concentrations. There was also a significant correlation between the rate constant and the abundance of DOC suggesting that rainwater organic carbon plays an important role during photolytic decay either via direct reaction or indirectly through production of peroxide reactive species or scavenging of peroxide generating radicals. Several rain samples exhibited an initial increase in H₂O₂ during the first 2 h of irradiation. These increases were generally small and most likely do not represent a significant input of peroxide in precipitation. The photo-induced destruction of H₂O₂ is important because it may partly explain the late afternoon decrease of peroxide concentrations observed in earlier field studies and the substantial under saturation (<10%) of this oxidant in rainwater compared with gas phase concentrations.     

Use of stream response functions to determine impacts of replacing surface-water use with groundwater withdrawals

A regional-scale numerical groundwater model is used to study the impacts of replacing surface-water use with groundwater wells to improve low-flow stream conditions for endangered species within the Bertrand and Fishtrap watersheds, southern British Columbia, Canada and Washington, USA. Stream response functions ranging from 0 to 1.0 were calculated for individual wells placed within a steady-state groundwater flow model at varying distances from the streams to determine the impact that these replacement wells, operating under sustained pumping rates, would have on summer instream flows. Lower response ratios indicate groundwater pumping will have less of an impact on streamflow than taking an equivalent amount of water directly from a surface-water source. Results show that replacing surface-water use with groundwater withdrawals may be a viable alternative for increasing summer streamflows. Assuming combined response factors should be ≤0.5 for irrigators to undergo the expense of installing new wells, ~57% of the land area within 0.8 km of Bertrand Creek would be suitable for replacement wells. Similarly, 70% of the land area within 0.8 km of Fishtrap Creek was found to be appropriate. A visual analysis tool was developed using STELLA to allow stakeholders to quickly evaluate the impact associated with moving their water right.     

Paleocene alkaline volcanism in the Nares Strait region: evidence from volcanic pebbles

Paleogene sediments in fault-bounded basins on Judge Daly Promontory, northeast Ellesmere Island, Canadian High Arctic, are rich in volcanogenic material. Volcanic pebbles within the Cape Back basin near Nares Strait were studied for their petrography, geochemistry, Sr and Nd isotopes, and geochronology to identify and characterize their parent rock. The pebbles are derived from lava flows and ignimbrites of a continental rift-related, strongly differentiated, highly incompatible element enriched, alkaline volcanic suite, the proposed Nares Strait volcanic suite, which is distinct from other alkaline volcanic suites on the northern coasts of Ellesmere Island and Greenland. ⁴⁰Ar/³⁹Ar amphibole and alkali feldspar ages indicate that volcanism was active around 61–58 Ma and was probably contemporaneous with sedimentation resulting in Middle to Late Paleocene age for deposition within the Cape Back basin and the other Paleogene basins on Judge Daly Promontory.     

Future changes in Central Europe heat waves expected to mostly follow summer mean warming

Daily output from the PRUDENCE ensemble of regional climate simulations for the end of the twentieth and twenty-first centuries over Europe is used to show that the increasing intensity of the most damaging summer heat waves over Central Europe is mostly due to higher base summer temperatures. In this context, base temperature is defined as the mean of the seasonal cycle component for those calendar days when regional heat waves occur and is close, albeit not identical, to the mean temperature for July–August. Although 36–47% of future Central Europe July and August days at the end of the twenty-first century are projected to be extreme according to the present day climatology, specific changes in deseasonalized heat wave anomalies are projected to be relatively small. Instead, changes in summer base temperatures appear much larger, clearly identifiable and of the same order of magnitude as changes in the whole magnitude of heat waves. Our results bear important consequences for the predictability of central European heat wave intensity under global warming conditions.     

GEOEssential – mainstreaming workflows from data sources to environment policy indicators with essential variables

ABSTRACT

When defining indicators on the environment, the use of existing initiatives should be a priority rather than redefining indicators each time. From an Information, Communication and Technology perspective, data interoperability and standardization are critical to improve data access and exchange as promoted by the Group on Earth Observations. GEOEssential is following an end-user driven approach by defining Essential Variables (EVs), as an intermediate value between environmental policy indicators and their appropriate data sources. From international to local scales, environmental policies and indicators are increasingly percolating down from the global to the local agendas. The scientific business processes for the generation of EVs and related indicators can be formalized in workflows specifying the necessary logical steps. To this aim, GEOEssential is developing a Virtual Laboratory the main objective of which is to instantiate conceptual workflows, which are stored in a dedicated knowledge base, generating executable workflows. To interpret and present the relevant outputs/results carried out by the different thematic workflows considered in GEOEssential (i.e. biodiversity, ecosystems, extractives, night light, and food-water-energy nexus), a Dashboard is built as a visual front-end. This is a valuable instrument to track progresses towards environmental policies.     

Effects of aging on silica solubility: A laboratory study

In three separate experiments, one using a bicarbonate buffered aqueous NaCl solution and two using natural seawater. the solubility of chemically pure X-ray amorphous precipitated silica decreased by approximately 20‰ after aging in contact with solution for several months. The specific surface area of the silica decreased by approximately half during the same experimental time periods. The solubility decrease in buffered NaCl solution occurred at both 2 and 22°C and over the pressure range from 1.01 × 10⁵ to 7.45 × 10⁷ Pa (1–740 atm). The aging process which causes the solubility and surface area decreases may be caused by the formation of a smooth surface silica layer that is more dense than the original surface. No change in the bulk chemistry of the silica could be defined after aging. This short term aging process contributes to the scatter in published solubilities for amorphous silica in seawater.     

High-resolution grain-size characterisation of gravel bars using imagery analysis and geo-statistics

The scarcity of grain-size data from gravel-bed rivers has traditionally hindered hydraulic, sediment transport and river habitat studies. A new remote sensing methodology to estimate grain-size distribution is presented. It combines textural digital images of the riverbed at 1 : 1000 and 1 : 40 scales with grain-size sampling. It was applied to a 12-km reach of the Isábena River (Central Pyrenees NE Spain). First, textural patterns for each grain-size range were obtained, selecting the most closely related texture variables, including the use of semivariograms. Second, multiple linear regression equations were derived from the textural variables to estimate each value of the grain-size distribution. The highest correlation values (r²) were obtained from the central part of the distribution (D₅₀ with a RMS error of 12.7%). Finally, new multiple linear regression equations to estimate the D₅₀ and D₈₄ were obtained from 1 : 1000 images and four textural variables. These were used to derive D₅₀ and D₈₄ maps of the riverbed, re-sampled at a resolution of 1.5 m pixels, with RMS estimation errors of 26% and 32%, respectively. Downstream change in grain-size is also well reproduced by the method. The mean D₅₀ of 72 and 32 mm were estimated in the upper and the lower reaches of the river, respectively. The methodology shows great potential for application, the relation between the spatial resolution of the images and the mean grain-size of the riverbed sediment being the main issue for future development.