Release of volatile mercury from soils and non-vascular plants

Vegetation plays a significant role in the biogeochemical cycling of mercury. This conclusion is drawn from data presented here on bioaccumulation and subsequent release of volatile mercury from non-vascular plants together with the results of previous work. There is no obvious relation between total plant Hg or soil Hg and rate of release from the plant. Heat of vaporization for Hg⁰ was calculated at 13.99 kcal/g-atom; from soil it was experimentally determined at 13.81 kcal/g-atom but from the most active vascular plant was only 9.49 kcal/g-atom.     

Earth observations for sustainable development goals monitoring based on essential variables and driver-pressure-state-impact-response indicators

ABSTRACT

In recent years, researchers of different communities have increased their efforts in formalizing a set of measurements regularly collected for analysing changes in Drivers, States, Impacts and Responses of a given discipline. In some cases, different actors have converged in a minimum set of Essential Variables (EVs), such as for Climate, Biodiversity or Oceans. The definition of such EVs is an ongoing evolution and in extension (e.g. EVs for water) although some communities have not even started (e.g. agriculture and energy). This paper characterizes the Earth Observation (EO) networks and creates a graph representation of their relations. Secondly, this graph is enriched with the EVs produced by each network creating a knowledge base. Finally, an effort has been done to identify links between EVs and Sustainable Development Goals (SDG) indicators in a way that they indirectly connect the EO. An analysis to detect gaps in EO variables due to a lack of observational networks is performed. Several suggestions for improving SDG indicators framework by considering EVs are exposed, as well as proposing new necessary EVs and suggesting new EO based indicators. The complete graph is available in the ENEON website (http://www.eneon.net/graph-ev-sdg/).     

Towards integrated essential variables for sustainability

ABSTRACT

Measuring the achievement of a sustainable development requires the integration of various data sets and disciplines describing bio-physical and socio-economic conditions. These data allow characterizing any location on Earth, assessing the status of the environment at various scales (e.g. national, regional, global), understanding interactions between different systems (e.g. atmosphere, hydrosphere, biosphere, geosphere), and modeling future changes. The Group on Earth Observations (GEO) was established in 2005 in response to the need for coordinated, comprehensive, and sustained observations related to the state of the Earth. GEO’s global engagement priorities include supporting the UN 2030 Agenda for Sustainable Development, the Paris Agreement on Climate, and the Sendai Framework for Disaster Risk Reduction. A proposition is made for generalizing and integrating the concept of EVs across the Societal Benefit Areas of GEO and across the border between Socio-Economic and Earth systems EVs. The contributions of the European Union projects ConnectinGEO and GEOEssential in the evaluation of existing EV classes are introduced. Finally, the main aim of the 10 papers of the special issue is shortly presented and mapped according to the proposed typology of SBA-related EV classes.     

Study of the interaction between U(VI) and the anoxic corrosion products of carbon steel

The objective of this study was to investigate the removal mechanism of U(VI) from groundwater by magnetite as the main product of anoxic steel corrosion. For this purpose, a systematic sequence of batch experiments was conducted to focus the active role of magnetite in the reduction of U under different conditions. Results indicated that under anoxic conditions U(VI) was sorbed at the magnetite surface, whereas under reducing conditions at different H₂(g) pressures, U was present in tetravalent form as amorphous UO₂.     

Synthesis and Preliminary Characterisation of New Silicate, Phosphate and Titanite Reference Glasses

Eleven synthetic silicate and phosphate glasses were prepared to serve as reference materials for in situ microanalysis of clinopyroxenes, apatite and titanite, and other phosphate and titanite phases. Analytical results using different micro-analytical techniques showed that the glass fragments were homogeneous in major and trace elements down to the micrometre scale. Trace element determinations using inductively coupled plasma-mass spectrometry (ICP-MS), multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS), laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) and secondary ionisation mass spectrometry (SIMS) showed good agreement for most elements (Li, Be, B, Cs, Rb, Ba, Sr, Ga, Pb, U, Th, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Er, Tm, Yb, Lu, Zr, Hf, Ta, Nb) studied and provide provisional recommended values.     

A coastal reservoir of terrestrial resources for neanderthal populations in north‐eastern Iberia: palaeoenvironmental data inferred from the small‐vertebrate assemblage of Cova del Gegant,Sitges, Barcelona

Coastal areas as reservoirs of resources for hominid groups have been widely studied in recent years. These areas combine marine with terrestrial and wetland resources and would have been optimum sites for hominids, including Neanderthals. This is the case with the Cova del Gegant, a cave that today opens directly onto the Mediterranean Sea and is located in the north‐eastern Iberian Peninsula. The geomorphological evolution of the Massis del Garraf has provided evidence that during the late Pleistocene there was a littoral platform between 8 and 13 km wide in front of the Cova del Gegant. Within this framework, the data derived from analysis of the small vertebrates and large mammals recovered from Cova del Gegant, including taxa currently absent from the Massis del Garraf, suggest that the landscape surrounding the cave provided a richer terrestrial ecosystem for Neanderthals than is available in this zone today. Analysis of the small‐vertebrate association from the cave reveals that the landscape surrounding the cave was dominated by woodland‐edge and open environments and that the climate was Mediterranean. The results have been compared with the only Iberian site with similar characteristics to the Cova del Gegant, Gorham's cave (southern Iberia, Gibraltar), revealing differences and similarities in the landscape and climate on the basis of the small‐mammal assemblages as well as the differences in the accessibility to terrestrial mammalian resources for the Neanderthal groups. The landscape and the climate were reasonably similar at the two sites, but the differences in the accessibility of resources for the Neanderthals are directly related to the location of the sites and the coastal position. Whereas the Cova del Gegant was on a route of mammal migration (between the Ebro Valley and France) suited for securing terrestrial resources, Gorham's cave is located on a small peninsula with a lower abundance of terrestrial mammal resources. This is probably why the Neanderthal groups at Gorham's cave exploited marine resources, whereas there is no evidence of marine resources having been exploited at Cova del Gegant, even though the seashore was nearby. Copyright © 2011 John Wiley & Sons, Ltd.     

Earthquake early warning scenarios at critical facilities in the Eastern Caribbean

A feasibility study of an earthquake early warning (EEW) system was conducted for the Eastern Caribbean region using scenario earthquakes, corresponding to the maximum credible earthquakes and to the earthquakes associated with a return period of 475 years. Broadband synthetic seismograms were produced at selected critical facilities, where there is potential interest in the installation of an EEW system. The expected damage was derived from the synthetic seismograms and compared with the lead-time determined for both a regional and on-site EEW configuration. Next, the Virtual Seismologist EEW algorithm, as included in SeisComP3, was tested. Additional broadband synthetic seismograms were produced for the stations in the Eastern Caribbean seismic networks in order to simulate the real time behaviour of the seismic networks during the occurrence of the synthetic earthquakes and to assess the predictive capacity of the selected ground motion prediction equation. Expected peak ground parameters and lead-times at the critical facilities constitute the major outcome of the study.     

Oxidative stress, genotoxicity and histopathology biomarker responses in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) liver from Bizerte Lagoon (Tunisia)

The aim of the study was to evaluate the impact of environmental contaminants on oxidative stress, genotoxic and histopathologic biomarkers in liver of mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) collected from a polluted coastal lagoon (Bizerte Lagoon) in comparison to a reference site (the Mediterranean Sea). Antioxidant enzyme activities were lower in fish from the polluted site compared with fish from the reference site, suggesting deficiency of the antioxidant system to compensate for oxidative stress. DNA damage was higher in both fish species from the contaminated site indicating genotoxic effects. The liver histopathological analysis revealed alterations in fish from Bizerte Lagoon. Hepatocytes from both fish species featured extensive lipid-type vacuolation and membrane disruption. Results suggest that the selected biomarkers in both fish species are useful for the assessment of pollution impacts in coastal environments influenced by multiple pollution sources.     

The 5,660?yBP Boquerón explosive eruption, Teide–Pico Viejo complex, Tenerife

Quantitative hazard assessments of active volcanoes require an accurate knowledge of the past eruptive activity in terms of eruption dynamics and the stratified products of eruption. Teide–Pico Viejo (TPV) is one of the largest volcanic complexes in Europe, but the associated eruptive history has only been constrained based on very general stratigraphic and geochronological data. In particular, recent studies have shown that explosive activity has been significantly more frequently common than previously thought. Our study contributes to characterization of explosive activity of TPV by describing for the first time the subplinian eruption of El Boquerón (5,660?yBP), a satellite dome located on the northern slope of the Pico Viejo stratovolcano. Stratigraphic data suggest complex shifting from effusive phases with lava flows to highly explosive phase that generated a relatively thick and widespread pumice fallout deposit. This explosive phase is classified as a subplinian eruption of VEI 3 that lasted for about 9–15?h and produced a plume with a height of up to 9?km above sea level (i.e. 7?km above the vent; MER of 6.9–8.2?×?10⁵?kg/s). The tephra deposit (minimum bulk volume of 4–6?×?10⁷?m³) was dispersed to the NE by up to 10?m/s winds. A similar eruption today would significantly impact the economy of Tenerife (e.g. tourism and aviation), with major consequences mainly for the communities around the Icod Valley, and to a minor extent, the Orotava Valley. This vulnerability shows that a better knowledge of the past explosive history of TPV and an accurate estimate of future potentials to generate violent eruptions is required in order to quantify and mitigate the associated volcanic risk.