Groundwater control on the suspended sediment load in the Na Borges River, Mallorca, Spain

Groundwater dominance has important effects on the hydrological and geomorphological characteristics of river systems. Low suspended sediment concentrations and high water clarity are expected because significant inputs of sediment-free spring water dilute the suspended sediment generated by storms. However, in many Mediterranean rivers, groundwater dominance is characterised by seasonal alternations of influent and effluent discharge involving significant variability on the sediment transport regimes. Such areas are often subject to soil and water conservation practices over the centuries that have reduced the sediment contribution from agricultural fields and favour subsurface flow to rivers. Moreover, urbanisation during the twentieth century has changed the catchment hydrology and altered basic river processes due to its ‘flashy’ regime. In this context, we monitored suspended sediment fluxes during a two-year period in the Na Borges River, a lowland agricultural catchment (319 km²) on the island of Mallorca (Balearic Islands). The suspended sediment concentration (SSC) was lower when the base flow index (i.e., relative proportion of baseflow compared to stormflow, BFI) was higher. Therefore, strong seasonal contrasts explain the high SSC coefficient of variation, which is clearly related to dilution effects associated with different groundwater and surface water seasonal interactions. A lack of correlation in the Q-SSC rating curves shows that factors other than discharge control sediment transport. As a result, at the event scale, multiple regressions illustrate that groundwater and surface water interactions are involved in the sedimentary response of flood events. In the winter, the stability of baseflow driven by groundwater contributions and agricultural and urban spills causes hydraulic variables (i.e., maximum discharge) to exert the most important control on events, whereas in the summer, it is necessary to accumulate important volumes of rainfall, creating a minimum of wet conditions in the catchment to activate hydrological pathways and deliver sediment to the drainage network. The BFI is also related to sediment delivery processes, as the loads are higher with lower BFI, corroborating the fact that most sediment movement is caused by stormflow and its related factors. Overall, suspended sediment yields were very low (i.e., < 1 t km^− 2 yr^− 1) at all measuring sites. Such values are the consequence of the limited sediment delivery attributable to soil conservation practices, low surface runoff coefficients and specific geomorphic features of groundwater-dominated rivers, such as low drainage density, low gradient, steep valley walls and flat valley floors.     

HASSET: a probability event tree tool to evaluate future volcanic scenarios using Bayesian inference

Event tree structures constitute one of the most useful and necessary tools in modern volcanology for assessment of hazards from future volcanic scenarios (those that culminate in an eruptive event as well as those that do not). They are particularly relevant for evaluation of long- and short-term probabilities of occurrence of possible volcanic scenarios and their potential impacts on urbanized areas. In this paper, we introduce Hazard Assessment Event Tree (HASSET), a probability tool, built on an event tree structure that uses Bayesian inference to estimate the probability of occurrence of a future volcanic scenario and to evaluate the most relevant sources of uncertainty from the corresponding volcanic system. HASSET includes hazard assessment of noneruptive and nonmagmatic volcanic scenarios, that is, episodes of unrest that do not evolve into volcanic eruption but have an associated volcanic hazard (e.g., sector collapse and phreatic explosion), as well as unrest episodes triggered by external triggers rather than the magmatic system alone. Additionally, HASSET introduces the Delta method to assess precision of the probability estimates, by reporting a 1 standard deviation variability interval around the expected value for each scenario. HASSET is presented as a free software package in the form of a plug-in for the open source geographic information system Quantum Gis (QGIS), providing a graphically supported computation of the event tree structure in an interactive and user-friendly way. We also include further in-depth explanations for each node together with an application of HASSET to Teide-Pico Viejo volcanic complex (Spain).     

Contrasts among macrophyte riparian species in their use of stream water nitrate and ammonium: insights from 15N natural abundance

We examined the relevance of dissolved inorganic nitrogen (DIN) forms (nitrate and ammonium) in stream water as N sources for different macrophyte species. To do this, we investigated the variability and relationships between ¹⁵N natural abundance of DIN forms and of four different macrophyte species in five different streams influenced by inputs from wastewater treatment plants and over time within one of these streams. Results showed that ¹⁵N signatures were similar in species of submersed and amphibious macrophytes and in stream water DIN, whereas ¹⁵N signatures of the riparian species were not. ¹⁵N signatures of macrophytes were generally closer to ¹⁵N signatures of nitrate, regardless of the species considered. Our results showed significant relationships between ¹⁵N signatures of DIN and those of submersed Callitriche stagnalis and amphibious Veronica beccabunga and Apium nodiflorum, suggesting stream water DIN as a relevant N source for these two functional groups. Moreover, results from a mixing model suggested that stream water DIN taken up by the submersed and amphibious species was mostly in the form of nitrate. Together, these results suggest different contribution to in-stream N uptake among the spatially-segregated species of macrophytes. While submersed and amphibious species can contribute to in-stream N uptake by assimilation of DIN, macrophyte species located at stream channel edges do not seem to rely on stream water DIN as an N source. Ultimately, these results add a functional dimension to the current use of macrophytes for the restoration of stream channel morphology, indicating that they can also contribute to reduce excess DIN in streams.     

Geochronology of Quaternary glaciations from the tropical Cordillera Huayhuash, Peru

The Cordillera Huayhuash in the central Peruvian Andes (10.3°S, 76.9°W) is an ideal mountain range in which to study regional climate through variations in paleoglacier extents. The range trends nearly north-south with modern glaciers confined to peaks >4800 m a.s.l. Geomorphology and geochronology in the nearby Cordillera Blanca and Junin Plain reveal that the Peruvian Andes preserve a detailed record of tropical glaciation. Here, we use ASTER imagery, aerial photographs, and GPS to map and date glacial features in both the western and eastern drainages of the Cordillera Huayhuash. We have used in situ produced cosmogenic ¹⁰Be concentrations in quartz bearing erratics on moraine crests and ice-polished bedrock surfaces to develop an exposure age chronology for Pleistocene glaciation within the range. We have also collected sediment cores from moraine-dammed lakes and bogs to provide limiting ¹⁴C ages for glacial deposits. In contrast to the ranges to the north and south, most glacial features within the Cordillera Huayhuash are Lateglacial in age, however we have identified features with ages that span 0.2 to 38 ka with moraine sets marking the onset of glacier retreat at 0.3 ka, 9–10 ka, 13–14 ka, 20–22 ka, and >26 ka. The range displays a pronounced east-west variation in maximum down-valley distance from the headwall of moraine crests with considerably longer paleoglaciers in the eastern drainages. Importantly, Lateglacial paleoglaciers reached a terminal elevation of 4000 m a.s.l. on both sides of the Cordillera Huayhuash; suggesting that temperature may have been a dominant factor in controlling the maximum glacier extent. We suggest that valley morphology, specifically valley slope, strongly influences down-valley distance to the maximum glacier extent and potential for moraine preservation. While regionally there is an extensive record of older (>50 ka) advances to the north (Cordillera Blanca) and to the south (Junin region), the apparent lack of old moraines in this locality may be explained by the confined morphology of the Cordillera Huayhuash valleys that has inhibited the preservation of older glacial geomorphic features.     

Phase distribution of hydrocarbons in the water column after a pelagic deep ocean oil spill

Spills from wrecks are a potential major source of pollution in the deep ocean. However, not much is known about the fate of a spill at several kilometers depth, beyond the oceans continental shelves. Here, we report the phase distribution of hydrocarbons released from the wrecks of the Prestige tanker, several years after it sank in November 2002 to depths between 3500 and 3800 m. The released oil reached the surface waters above the wrecks without any signs of weathering and leaving an homogenous signature throughout the water column. At depths of several kilometers below the sea surface, the occurrence and spread of the deep sea oil spill could be evaluated better by quantifying and characterizing the dissolved hydrocarbon signature, rather than just the investigation of hydrocarbons in the suspended particulate matter.     

Seasonal and event-controlled export of organic matter from the shelf towards the Gulf of Lions continental slope

To investigate the role of coastal canyons in the transfer of organic matter from the shelf to the slope and basin, we deployed sediment trap/current meter pairs at the head of five canyons in the Gulf of Lions (GoL) between November 2003 and May 2004. Analysis of organic carbon, biogenic silica, Corg isotopic composition, Corg/total nitrogen, chloropigments, and amino acids clearly shows the seasonal influence and effect of extreme meteorological events on the composition of collected particles. The sampling period was divided into three “scenarios”. The first corresponded to a large easterly storm and flood of the Rhone river during stratified water column conditions; the composition of material collected during this event was influenced by increased transfer of riverine and coastal particulate matter, with a lower Corg content. During the second “fall-winter” scenario, northern and northwestern winds blowing over the shelf caused cooling and homogenization of the shelf water column; particles collected at this time reflected the homogeneous source of particulate matter transported through canyons; particles sitting in the vicinity of canyon heads are most likely swept downslope by the general south-westward circulation. Organic tracers indicate a degraded origin for organic matter transported during this period. A third “spring” scenario corresponded to northern winds alternating with eastward windstorms that triggered and/or enhanced the cascading of dense waters accumulated on the bottom of the shelf due to previous cooling. These conditions occurred in conjunction with increased phytoplankton productivity in shelf surface waters. Organic matter advected mainly by dense shelf water cascading was fresher due to the transport of newly produced particles and a variable terrestrial fraction; this fraction depended on the proportion of resuspended material accumulated during previous high discharge periods that was involved in each transport pulse. The tight link shown between meteorological conditions and organic matter transport is important for continental margin geochemical studies as future changes in climatic conditions may lead to dramatic changes in carbon sequestration capability and in the ecosystems of deep margin environments.     

A synoptic parameterization of the drag coefficient

Abstract

The problem areas affecting the evaluation of hail suppression experiments are reviewed. These include the hail sensors and networks, trop damage data, statistical analysis, the hail‐suppression hypothesis, and the technology of cloud seeding. General directions of needed research are proposed.     

Chromophoric Dissolved Organic Matter (CDOM) In Rainwater,Southeastern North Carolina,USA

The abundance and optical characteristics of dissolved organic matter (DOM) were determined in 120 rain samples collected in Wilmington, North Carolina, USA, between February 21, 2002 and August 11, 2003. All rainwater samples contained chromophoric dissolved organic matter (CDOM) as well as fluorescent compounds. The absorbance spectra of CDOM in the samples decreased exponentially with wavelength with little or no measurable absorbance past 550 nm. Fluorescence excitation emission spectra (EEMS) of the precipitation revealed the presence of four major peaks indicating both terrestrial and marine influences. There was a strong positive correlation between total integrated fluorescence and the absorbance coefficient at 300 nm in rainwater samples, suggesting that these optical properties are directly interrelated and that the compounds responsible for absorbance may be the same as those responsible for fluorescence. Air-mass back-trajectory analysis indicated elevated CDOM levels in continentally influenced rainwater relative to marine dominated events implying that anthropogenic and/or terrestrial sources are important contributors to CDOM levels in precipitation. The presence of highly absorbing and fluorescing CDOM in rainwater has significant ramifications in atmospheric chemistry and may play a previously unrecognized role in the wavelength dependent spectral attenuation of solar radiation by atmospheric waters.     

Study of the total lightning activity in a hailstorm

A thunderstorm that developed over northeastern Spain on 16 June 2006 is analyzed. This severe thunderstorm produced hailstones as large as 40 mm and had a lifetime of 3 h and 30 min. Radar cross-sections show strong vertical development with cloud echo tops reaching an altitude of 13 km. The specific characteristics of the lightning activity of this storm were: (i) a large amount (81%) of negative cloud-to-ground (−CG) flashes with very low peak currents (< 10 kA in absolute value), (ii) a very large proportion of intra-cloud (IC) flashes with an IC/CG ratio reaching about 400, (iii) a large number of “short” IC flashes (with only 1-VHF source according to SAFIR detection), (iv) a large increase of the −CG flash rate and of the CG proportion near the end of the storm. The rate of −CG flashes with a low peak current were observed to evolve similarly to the rates of IC flashes. Most of them have been assumed to be IC flashes misclassified by the Spanish Lightning Detection Network (SLDN). They have been filtered as it is usually done for misclassified +CG flashes. After this filtering, CG flash rates remained very low (< 1 min^− 1) with +CG flashes sometimes dominant. All the particular lightning activity characteristics similar to those observed in the Severe Thunderstorm Electrification and Precipitation Study (STEPS) campaigns support the hypothesis that this thunderstorm could have had an inverted-polarity or complex charge structure. The maximum IC flash rate (67 min^− 1) peaked 24 min before the presence of reflectivity higher than 60 dBZ. The IC activity abruptly decreased during the period when reflectivity was dramatically increasing. The time of maximum reflectivity observed by radar was consistent with the times of reported hail at the ground.