Carbonates in CM2 chondrites: constraints on alteration conditions from oxygen isotopic compositions and petrographic observations

High-precision measurements of the oxygen isotopic compositions of carbonates (calcite and dolomite) from five CM2 chondrites are presented and put into context of the previously determined mineralogic alteration index (MAI), which places these meteorites into an alteration sequence. The carbonate oxygen isotopic compositions range from +20.0 to +35.7‰ for δ¹⁸O, +8.0 to +17.7‰ for δ¹⁷O, and −0.7 to −2.7‰ for Δ¹⁷O. Carbonate Δ¹⁷O values are inversely correlated with MAI and track the evolution of fluid composition from higher to lower Δ¹⁷O values with increasing alteration on the CM parent body. Similar Δ¹⁷O values for calcite and dolomite fractions from the same splits of the same meteorites indicate that calcite and dolomite in each split precipitated from a single fluid reservoir. However, reversed calcite dolomite fractionations (δ¹⁸O_dol − δ¹⁸O_cc) indicate that the fluid was subject to processes, such as freeze-thaw or evaporation, that fractionated isotopes in a mass-dependent way. Consideration of the carbonate isotopic data in the context of previously proposed models for aqueous alteration of carbonaceous chondrites has provided important insights into both the evolving alteration conditions and the utility of the models themselves. The data as a whole indicate that the isotopic evolution of the fluid was similar to that predicted by the closed-system, two-reservoir models, but that a slightly larger matrix-water fractionation factor may apply. In the context of this model, more altered samples largely reflect greater reaction progress and thus probably indicate more extended times of fluid exposure. Petrographic observations of carbonates reveal a trend of variable carbonate morphology correlated with alteration that is also consistent with changes in the duration of fluid-rock interaction. The data can also be reconciled with fluid-flow models in a restricted region of the parent body, which is consistent with assertions that the different types of carbonaceous chondrites derive from different regions of their parent bodies. In this case, the model results for a 9-km-radius body, and our data place the location of the CM chondrite formation in a 100-m-thick zone 1 km from the surface. The size of this zone could be increased if the model parameters were adjusted.     

High resolution seismic imaging of faults beneath Limón Bay, northern Panama Canal, Republic of Panama

High-resolution seismic reflection profiles from Limón Bay, Republic of Panama, were acquired as part of a seismic hazard investigation of the northern Panama Canal region. The seismic profiles image gently west and northwest dipping strata of upper Miocene Gatún Formation, unconformably overlain by a thin (<20 m) sequence of Holocene muds. Numerous faults, which have northeast trends where they can be correlated between seismic profiles, break the upper Miocene strata. Some of the faults have normal displacement, but on many faults, the amount and type of displacement cannot be determined. The age of displacement is constrained to be Late Miocene or younger, and regional geologic considerations suggest Pliocene movement. The faults may be part of a more extensive set of north- to northeast-trending faults and fractures in the canal region of central Panama. Low topography and the faults in the canal area may be the result of the modern regional stress field, bending of the Isthmus of Panama, shearing in eastern Panama, or minor deformation of the Panama Block above the Caribbean subduction zone. For seismic hazard analysis of the northern canal area, these faults led us to include a source zone of shallow faults proximal to northern canal facilities.     

Seismic-frequency Laboratory Measurements of Shear Mode Viscoelasticity in Crustal Rocks II: Thermally Stressed Quartzite and Granite

—Forced torsional oscillation techniques have been used to explore the seismic-frequency shear mode viscoelasticity of specimens of two crustal rocks (Cape Sorell quartzite and Delegate aplite), cycled between room temperature and 700°C under conditions of moderate confining pressure. The anisotropy and intergranular inhomogeneity of thermal expansivity in these materials give rise to large deviatoric stresses, resulting in thermal cracking at temperatures above a pressure-dependent threshold temperature, associated with the onset of very pronounced temperature sensitivity of the shear modulus, in general accord with the predictions of fracture mechanics models. For Delegate aplite in particular, the shear modulus behaves reproducibly during multiple thermal cycles at different confining pressures, consistent with the notion that the thermal cracks are of low aspect ratio (minimum/maximum dimension), and are therefore readily closed by the prevailing confining pressure once the thermal stresses are removed. Marked frequency-dependent dissipation of shear strain energy is observed on heating each rock to temperatures ≥ 500°C, although the attenuation varies significantly with prior thermal history, probably as a result of progressive dehydration and relaxation of deviatoric stresses. Temperature and pressure dependent crack densities for Delegate aplite have been estimated by comparison of the observed shear moduli with those expected for a crack-free aggregate. In parallel with the forced oscillation tests, measurements have been made of the rate at which (argon) pore pressure equilibrium is re-established following a perturbation. Combination of these results, which provide a proxy for permeability, with the inferred crack densities indicates that the variation of permeability with crack density is well described by a percolation model with a threshold crack density of ～0.2.     

Climatic influences on Holocene variations in soil erosion rates on a small hill in the Mojave Desert

A detailed study of a small hill in NE Mojave Desert in eastern California was conducted to elucidate the effect of climate on the variations in soil erosion rates through Holocene. Field surveys and sampling were carried out to obtain information on topography, geomorphology, soil and vegetation conditions, seismic refraction, sediment deposition, and hillslope processes. Integration of this information allowed reconstruction of the hill topography at the end of the Pleistocene, deduction of the evolution of the hill from the end of the Pleistocene to the present, and estimation of total soil losses resulting from various hillslope processes. The estimates are consistent with the premise that early Holocene climate change resulted in vegetation change, soil destabilization, and topographic roughening. Current, very slow, hillslope transport rates (e.g., 5 mm ky⁻¹ by rodent burrowing, a presently important transport form) appear inconsistent with the inferred total soil loss rate (31 mm ky⁻¹). Packrat midden studies imply that the NE Mojave Desert experienced enhanced monsoonal precipitation in the early Holocene, presumably accentuating soil loss. Water erosion on one slope of the hill was simulated using Water Erosion Prediction Project (WEPP), a process-based erosion model, using 4 and 6 ky of precipitation input compatible with an appropriate monsoonal climate and the present climate, respectively. The WEPP-predicted soil losses for the chosen slope were compatible with inferred soil losses. Identification of two time periods within the Holocene with distinct erosion characteristics may provide new insight into the current state of Mojave Desert landform evolution.     

Morphological and geological aspects related to large slope failures on oceanic islands: The huge La Orotava landslides on Tenerife, Canary Islands

Huge volcanic landslides are one of the most hazardous geomorphological processes that can occur during the evolution of volcanic ocean islands. The causes of these phenomena, however, are very complex and combine non-volcanic and volcanic factors. In the Canary Islands, more than 20 events have been detected during the last decades. A detailed analysis was carried out for La Orotava amphitheatre on Tenerife in order to understand the relationship between geomorphological and geological aspects and huge volcanic landslides. The results indicated four major features that play a significant role in such mass movements: deep erosive canyons, high coastal cliffs, widespread residual soils and structural axes. High coastal cliffs and deep erosive canyons locally reduce the stability conditions and control both the seaward and the lateral boundary of the landslide. Weak residual soils formed above phonolitic pyroclastic deposits occur repeatedly in the stratigraphic column of La Orotava and are characterised by their large extent. Thus, one of these soils may have evolved into the slip surface of the failure. Part of the head scarp of the amphitheatre is defined by a volcanic rift zone, as indicated by the measurement of dike orientation and a density map of eruptive vents. The four features are not able to trigger a failure, but to destabilise the volcano flank and determine the boundary of the slide. Therefore, information on depth and orientation of canyons; location and height of coastal cliffs; stratigraphic repetition, extension and thickness of residual soils and orientation and density of dikes and eruptive vents along structural axes should be incorporated into a hazard assessment on large landslides on volcanic islands.     

Remote sensing of soil moisture: implications for groundwater recharge

Remote sensing provides information on the land surface. Therefore, linkages must be established if these data are to be used in groundwater and recharge analyses. Keys to this process are the use of remote sensing techniques that provide information on soil moisture and water-balance models that tie these observations to the recharge. Microwave remote sensing techniques are used to map the spatial domain of surface soil moisture and to monitor its temporal dynamics, information that cannot be measured using other techniques. The physical basis of this approach is presented with examples of how microwave remote sensing is utilized in groundwater recharge and related studies. Electronic Publication     

Palaeomagnetism of some rocks from Peninsular India and Kashmir

A palaeomagnetic study of seven sites in redbeds of the Late Precambrian Bhander and Rewa Series of the Upper Vindhyan System confirms that their original magnetization was extensively overprinted during the Early Tertiary, possibly related to the extrusion of the Deccan Traps about 65 Ma ago. Careful thermal demagnetization at temperatures close to the Curie Temperature of hematite revealed the primary magnetization in 100 of 121 specimens investigated. The resulting palaeomagnetic pole for the Upper Vindhyan System lies at 51.0S 37.8E. A combination with all previous results gives an overall palaeomagnetic pole at 47.3S 32.7E (N = 18, K = 35.5, A₉₅ = 5.8°). Twelve samples from the Gwalior Traps (1830 Ma) give a palaeomagnetic pole at 16N 160.5E after magnetic cleaning.Twelve flows collected from the Permo-Carboniferous Panjal Traps of Kashmir give mean direction D = 156.5, I = + 32.5 (κ = 19.8, α₉₅ = 9.9°) with a positive fold test. The palaeomagnetic pole (32N 282E), however, lies close to that observed for Deccan Trap times in India. It appears that the magnetization of the Panjal Traps was acquired during the Early Tertiary Himalayan uplift following which they were tilted to their present attitudes.