The effect of seawater magnesium on natural fluorescence during estuarine mixing,and implications for tracer applications

Natural fluorescence, which is thought to result from low molecular weight humic and fulvic compounds, can be used as a tracer to distinguish between individual river waters. Natural fluorescence exhibits conservative mixing with seawater, except for a slight fluorescence increase which is sometimes observed in the low salinity range (0–5‰). This increase is not due to the inner filter effect (internal quenching). Laboratory experiments can reproduce this low-salinity natural fluorescence increase. Of the major seawater ions, only magnesium can cause a similar natural fluorescence increase. Variation in sample pH, ionic strength, or particle content cannot explain the natural fluorescence increase, nor does it appear to be related to the estuarine flocculation of humic material. Addition of seawater magnesium to the fluorescent material with subsequent loss of hydrogen ions could enhance fluorescence by adding crosslinking to the structure. Replacement of a fluorescence-depressing metal like copper or iron by magnesium could also enhance fluorescence, essentially by removing the quenching effect of the metal. Experimental data in this study are consistent with both of these possible mechanisms. Calcium also enhances fluorescence, however the effect of seawater calcium during estuarine mixing is not as apparent as the magnesium effect. The implications of this low-salinity natural fluorescence increase with respect to estuarine and coastal tracer applications depend on whether individual rivers mix in the high or low salinity region of an estuary or coastal area.     

Injection and arrest of dykes: implications for volcanic hazards

Dykes are the principal channels through which magma reaches the surface in volcanic eruptions. For this reason dykes observed in the field are commonly assumed to be feeders to lava flows. The actual proportion of dykes reaching the surface is, however, poorly known. In order to develop models for the purpose of estimating volcanic hazard, this proportion must be known. This follows because such models should not only consider the probability of dykes being injected from magma chambers during periods of unrest in the associated volcanoes, but also the probability of the injected dykes being arrested. This paper presents field data on several thousand dykes from Iceland and Tenerife (Canary Islands) indicating that many, and probably most, dykes become arrested at various crustal levels and never reach the surface to feed eruptions. Using the results of analytical and numerical models, it is shown that, for common loading conditions, the stress field in the vicinity of a magma chamber may favour the injection and propagation of dykes while the stress field at a certain distance from the chamber favours dyke arrest. This means that many dykes that are injected from the chamber propagate only for a very limited distance from the chamber to the point where they become arrested. The implication is that during periods of unrest in volcanoes, the probability of volcanic eruption is only a small fraction of the probability of dyke injection from the source magma chamber.     

Is there any detachment in the Lower Dolpo (western Nepal)?Y a-t-il un détachement dans le bas Dolpo (Népal occidental) ?

A structural transect in the Lower Dolpo highlights that the deformation and metamorphism of the Tibetan Zone (TZ) increase toward the bottom of the sequence. The contact with the underlying HHC is marked by a metamorphic jump from amphibolite facies in the carbonatic rocks of the upper part of the HHC to greenschist facies marbles in the TZ. Moreover, the HHC and the TZ show different metamorphic histories. The contact zone shows a strain increase accompanied by asymmetric folds with a top-to-the-northeast vergence, connected to a down-to-the-northeast tectonic transport. The contact is interpreted as an extensional shear zone, connected to the South Tibetan Detachment System. To cite this article: R. Carosi et al., C. R. Geoscience 334 (2002) 933–940.     

Impacts of topography and land degradation on the sea breeze over eastern Spain

Summary A three-dimensional non-hydrostatic atmospheric model RAMS, version3b, is used to examine the impact of complex topography on the sea breeze under heterogeneous and degradation land use characteristics. In the study, it is shown that topography plays an important role in the sea-breeze circulation by aligning the sea breeze front to the coastline and locating the convergence zones close to the mountain range. When the sea breeze is coupled with the upslope wind, the sea-breeze circulation is strengthened by the topography.Sensitivity analyses are carried out to determine the influence of vegetation and soil moisture, i.e., land surface modifications, to this thermally driven flow. Land degradation results in an enhanced sea-breeze circulation which is characterized by a stronger onshore flow, a stronger return current, a larger updraft velocity associated with the sea-breeze front and further inland penetration. Other important features are a deeper sea-breeze depth, a larger downdraft velocity behind the sea-breeze front, and a longer offshore extent. The results also show how land changes modify the sea breeze temporal evolution resulting in an earlier onset and later end. The study stresses the convenience of using three-dimensional models with detailed land surface information to model the sea breeze in complex terrain where land use is rapidly modified.Received February 25, 2002; accepted October 7, 2002 Published online April 10, 2003     

Reconstruction of annual winter rainfall since A.D.1579 in central-eastern Spain based on calcite laminated sediment from Lake La Cruz

We present the first winter (December to March) rainfall reconstruction based in a novel proxy, the thickness of annual calcite laminations preserved in Lake La Cruz (central–eastern Spain). A previous calibration analysis between laminae thickness and the instrumental data series (1950 to present) indicated a highly significant correlation with winter rainfall. Therefore this study attempts the winter rainfall reconstruction since the onset of laminations (1579 a.d.) by means of the calibration function previously developed. The verification analysis between inferred annual values and earlier instrumental data (1859–1949) confirms the suitability of this novel proxy and the reliability of the series reconstructed. The reconstructed series show the fluctuating character of winter rainfall in the western Mediterranean area; interdecadal dry periods alternated with wetter periods following, in a board sense, the pattern recorded by documentary sources in other regions of the Iberian Peninsula. At present times regional winter rainfall anomalies are highly correlated with the phase of the North Atlantic Oscillation (NAO). However the time series analysis showed the dominance of nonstationary components at high frequencies of the climate signal over the last four centuries suggesting that the connection between winter rainfall and the NAO has not been stable over time and also other modes of variability, not only NAO, may have conditioned winter rainfall variability.     

A comparison of sediment microbial communities associated with<Emphasis Type="Italic">Phragmites australis</Emphasis> and<Emphasis Type="Italic">Spartina alterniflora</Emphasis> in two brackish wetlands of New Jersey

The extensive spread ofPhragmites australis throughout brackish marshes on the East Coast of the United States is a major factor governing management and restoration decisions because it is assumed that biogeochemical functions are altered by the invasion. Microbial activity is important in providing wetland biogeochemical functions such as carbon and nitrogen cycling, but there is little known about sediment microbial communities inPhragmites marshes. Microbial populations associated with invasivePhragmites vegetation and with native salt marsh cordgrass,Spartina alterniflora, may differ in the relative abundance of microbial taxa (community structure) and in the ability of this biota to decompose organic substrates (community biogeochemical function). This study compares sediment microbial communities associated withPhragmites andSpartina vegetation in an undisturbed brackish marsh near Tuckerton, New Jersey (MUL), and in a brackish marsh in the anthropogenically affected Hackensack meadowlands (SMC). We use phospholipid fatty acid (PLFA) analysis and enzymataic activity to profile sediment microbial communities associated with both plants in each site. Sediment analyses include bulk density, total organic matter, and root biomass. PLFA profiles indicate that the microbial communities differ between sites with the undisturbed site exhibiting greater fatty acid richness (62 PLFA recovered from MUL versus 38 from SMC). Activity of the 5 enzymes analyzed (β-glucosidase, acid phosphatase, chitobiase, and 2 oxidases) was higher in the undisturbed site. Differences between vegetation species as measured by Principal Components Analysis were significantly greater at the undisturbed MUL site than at SMC, and patterns of enzyme activity and PLFAs did not correspond to patterns of root biomass. We suggest that in natural wetland sediments, macrophyte rhizosphere effects influence the community composition of sediment microbial populations. Physical and chemical site disturbances may impose limits on these rhizosphere effects, decreasing sediment microbial diversity and potentially, microbial biogeochemical functions.     

Progressive failure leading to the 3 December 2013 rockfall at Puigcercós scarp (Catalonia,Spain)

A detailed analysis of the pre-failure behavior of the 3 December 2013 rockfall (1,012 m³) occurred on Puigcercós pilot study area (Catalonia, Spain) is presented. The exact date of failure was obtained based on a photographic monitoring performed every 4 h. The long-term monitoring (2,217 days) of the rock slope carried out by a Terrestrial LiDAR allowed the early detection of both pre-failure deformation and precursory rockfalls preceding the final failure. By means of the analysis of the pre-failure deformation, four different deformed areas were detected and the tertiary creep phase was observed in three of them. An attempt to predict the time to failure was performed using the Fukuzono’s (1985) method. Furthermore, the temporal evolution of the precursory rockfalls occurred in those four areas during the progressive failure showed a close resemblance with the exponential pattern of the cumulated displacements at tertiary creep stage. Finally, the study of the meteorological conditions did not show any single triggering factor associated with the final failure. Reversely, the increase in the occurrence of precursory rockfalls on several areas of the slope together with the observed acceleration on the deformation pattern reinforce the role of a progressive degradation of the stability conditions, which ultimately leaded to the 3 December rockfall event.     

Effect of discharge on the chlorophylla distribution in the tidally-influenced Potomac River

In the tidal Potomac River, high river discharges during the spring are associated with high chlorophylla concentrations in the following in the following summer, assuming that summertime light and temperature conditions are favorable. Spring floods deliver large loads of particulate N and P to the tidal river. This particulate N and P could be mineralized by bacteria to inorganic N and P and released to the water column where it is available for phytoplankton use during summertime. However, during the study period relatively low concentrations of chlorophylla (less than 50 μg l^?1 occurred in the tidal river if average monthly discharge during July or August exceeded 200 m³s^?1. Discharge and other conditions combined to produce conditions favorable for nuisance levels of chlorophylla (greater than 100 μg l^?1 approximately one year out of four. Chlorophylla maxima occurred in the Potomac River transition zone and estuary during late winter (dinoflagellates) and spring (diatoms). Typical seasonal peak concentrations were achieved at discharges as high as 970 m³ s^?1, but sustained discharges greater than 1,100 m³ s^?1 retarded development. Optimum growth conditions occurred following runoff events of 10 to 15 d duration which produced transit times to the transition zone of 7 to 10 d. Wet years with numerous moderate-sized runoff events, such as 1980, tend to produce greater biomass in the transition zone and estuary than do dry years such as 1981.