Flares associated with EFR's (Emerging Flux Regions)

I examined a moderately active sunspot group, McMath 9735, and found that 15 of 16 flares observed in 1968, October 20–21 occurred near, and were preceded by, at least one of several EFR's (Emerging Flux Regions) in the area. Flares were larger and more numerous when: (1) the EFR appeared close to already existing spots, (2) a large amount of filament reorientation was occurring, and when (3) the EFR was most active, i.e., it was increasing in area and brightness and was accompanied by violent surging and great brightness fluctuations at the feet of the dark fibrils. Only two flares occurred at an inverted EFR, i.e., a leading spot with f polarity, however the largest event (2B) of the 15 quickly spread to this region after starting in a different EFR. A sunspot appeared in the inverted emerging flux region less than three hours after the flares. However this is thought to be merely an indication of the growing EFR and, therefore, a secondary effect.     

Biodegradation of petroleum hydrocarbons at low temperature in the presence of the dispersant Corexit 9500

Our study examined the effects of Corexit 9500 and sediment on microbial mineralization of specific aliphatic and aromatic hydrocarbons found in crude oil. We also measured gross mineralization of crude oil, dispersed crude oil and dispersant by a marine microbial consortium in the absence of sediment. When provided as carbon sources, our consortium mineralized Corexit 9500 the most rapidly, followed by fresh oil, and finally weathered oil or dispersed oil. However, mineralization in short term assays favored particular components of crude oil (2-methyl-naphthalene > dodecane > phenanthrene > hexadecane > pyrene) and was not affected by addition of nutrients or sediment (high sand, low organic carbon). Adding dispersant inhibited hexadecane and phenanthrene mineralization but did not affect dodecane and 2-methyl-naphthalene mineralization. Thus, the effect of dispersant on biodegradation of a specific hydrocarbon was not predictable by class. The results were consistent for both high and low oiling experiments and for both fresh and weathered oil. Overall, our results indicate that environmental use of Corexit 9500 could result in either increases or decreases in the toxicity of residual oil through selective microbial mineralization of hydrocarbons.     

Temporal Variability of Iron Speciation in Coastal Rainwater

Iron occurs in rain as particulateand dissolved Fe and includes both Fe(II) and Fe(III)species. Model calculations and correlation analysisindicate Fe(II)(aq) occurs almost exclusively as thefree ion whereas Fe(III)(aq) occurs as both ironoxalate and Fe(OH)₂ ⁺(aq) with largevariations over the pH range from 4.0 to 5.0. Complexation with humic-like compounds may also beimportant for Fe(III)(aq); however, the concentrationand structural characteristics of these compounds haveyet to be determined. 112 rain samples were collectedfor iron analysis in Wilmington, North Carolina,between 1 July 1997, and 30 June 1999. Total iron,particulate iron and Fe(III)(aq) were higher inconcentration in summer and spring rain relative towinter and autumn rain. Fe(II)(aq) concentrations, incontrast, did not vary seasonally. Particulate iron,which was approximately half the total rainwater iron,was highest between noon and 6 p.m. (EST), probably dueto more intense regional convection including land-seabreezes during that time. The ratio ofFe(II)(aq)/Fe(III)(aq) was also highest in rainreceived between noon and 6 p.m., which most likelyreflects photochemical reduction of Fe(III)(aq)complexes to form Fe(II)(aq). A conceptual modeldepicting the interplay between iron species, lightintensity and organic ligands in rainwater ispresented.     

Water isotopic variability in Mallorca: a path to understanding past changes in hydroclimate

This paper reports the first results on δ¹⁸O and δ²H analysis of precipitations, cave drip waters, and groundwaters from sites in Mallorca (Balearic Islands, western Mediterranean), a key region for paleoclimate studies. Understanding the isotopic variability and the sources of moisture in modern climate systems is required to develop speleothem isotope‐based climate reconstructions. The stable isotopic composition of precipitation was analysed in samples collected between March 2012 and March 2013. The values are in the range reported by GNIP Palma station. Based on these results, the local meteoric water line (LMWL) δ²H = 7.9 (±0.3) δ¹⁸O + 10.8 (±2.5) was derived, with slightly lower slope than Global Meteoric Water Line. The results help tracking two main sources of air masses affecting the study sites: rain events with the highest δ¹⁸O values (> ?5‰) originate over the Mediterranean Sea, whereas the more depleted samples (< ?8‰) are sourced in the North Atlantic region. The back trajectory analysis and deuterium excess values, ranging from 0.4 to 18.4‰, further support our findings. To assess the isotopic variation across the island, water samples from eight caves were collected. The δ¹⁸O values range between ?6.9 and ?1.6‰. With one exception (Artà), the isotopic composition of waters in caves located along the coast (Drac, Vallgornera, Cala Varques, Tancada, and Son Sant Martí) indicates Mediterranean‐sourced moisture masses. By contrast, the drip water δ¹⁸O values for inland caves (Campanet, ses Rates Pinyades) or developed under a thick (>50 m) limestone cap (Artà) exhibit more negative values. A well‐homogenized aquifer supplied by rainwaters of both origins is clearly indicated by groundwater δ¹⁸O values, which show to be within 2.4‰ of the unweighted arithmetic mean of ?7.4‰. Although limited, the isotopic data presented here constitute the baseline for future studies using speleothem δ¹⁸O records for western Mediterranean paleoclimate reconstructions. Copyright © 2016 John Wiley & Sons, Ltd.     

Delineating coastal groundwater discharge processes in a wetland area by means of electrical resistivity imaging, 224Ra and 222Rn

Coastal groundwater discharge (CGD) plays an important role in coastal hydrogeological systems as they are a water resource that needs to be managed, particularly in wetland areas. Despite its importance, identifying and monitoring CGD often presents physical and logistical constraints, restraining the application of more traditional submarine groundwater discharge surveying techniques. Here we investigate the capability of electrical resistivity imaging (ERI) in the Peníscola wetland (Mediterranean coast, Spain). ERI surveying made it possible to identify and delineate an ascending regional groundwater flow of thermal and Ra‐enriched groundwater converging with local flows and seawater intrusion. The continuous inputs of Ra‐rich groundwater have induced high activities of Ra isotopes and ²²²Rn into the marsh area, becoming among the highest previously reported in wetlands and coastal lagoons. Geoelectrical imaging enabled inferring focused upward discharging areas, leaking from the aquifer roof through a confining unit and culminating as spring pools nourishing the wetland system. Forward modelling over idealized subsurface configurations, borehole datasets, potentiometric records from standpipe piezometers, petrophysical analysis, and four natural and independent tracers (²²⁴Ra, ²²²Rn, temperature and salinity) permitted assessing the geoelectrical model and a derived hydrogeological pattern. The research highlights the potential of ERI to improve hydrogeological characterization of subsurface processes in complex contexts, with different converging flows. Additionally, a hydrogeological conceptual model for a groundwater‐fed coastal wetland was proposed, based on the integration of surveying datasets. Copyright © 2013 John Wiley & Sons, Ltd.     

Motion close to the Hopf Bifurcation Of the vertical family of periodic orbits of L4

The paper deals with different kinds of invariant motions (periodic orbits, 2D and 3D invariant tori and invariant manifolds of periodic orbits) in order to analyze the Hamiltonian direct Hopf bifurcation that takes place close to the Lyapunov vertical family of periodic orbits of the triangular equilibrium point L₄ in the 3D restricted three-body problem (RTBP) for the mass parameter, μ greater than (and close to) μ_R (Routh’s mass parameter). Consequences of such bifurcation, concerning the confinement of the motion close to the hyperbolic orbits and the 3D nearby tori are also described.     

Physical conditions in the corona for a bipolar magnetic region

We have used the S-056 X-ray data from Skylab to determine quantitative values for the coronal conditions characterizing a new bipolar magnetic region (BMR). In particular, we include: (a) the time variation of the total soft X-ray flux from the BMR as a function of time; (b) the temporal and spatial variation of the temperature and emission measure; (c) the variation with time of thermal energy density; (d) the (calculated) magnetic field configuration and magnetic flux density in the corona; and (e) the temporal variation of the magnetic field energy in the corona. Detailed comparisons are made between the configuration of X-ray features and the magnetic field topology.     

Latent lifestyle preferences and household location decisions

Lifestyle, indicating preferences towards a particular way of living, is a key driver of the decision of where to live. We employ latent class choice models to represent this behavior, where the latent classes are the lifestyles and the choice model is the choice of residential location. Thus, we simultaneously estimate lifestyle groups and how lifestyle impacts location decisions. Empirical results indicate three latent lifestyle segments: suburban dwellers, urban dwellers, and transit-riders. The suggested lifestyle segments have intriguing policy implications. Lifecycle characteristics are used to predict lifestyle preferences, although there remain significant aspects that cannot be explained by observable variables.

Ilmenite as a recorder of kimberlite history from mantle to surface: examples from Indian kimberlites

Five compositional-textural types of ilmenite can be distinguished in nine kimberlites from the Eastern Dharwar craton of southern India. These ilmenite generations record different processes in kimberlite history, from mantle to surface. A first generation of Mg-rich ilmenite (type 1) was produced by metasomatic processes in the mantle before the emplacement of the kimberlite. It is found as xenolithic polycrystalline ilmenite aggregates as well as megacrysts and macrocrysts. All of these ilmenite forms may disaggregate within the kimberlite. Due to the interaction with low-viscosity kimberlitic magma replacement of pre-existing type 1 ilmenite by a succeeding generation of geikielite (type 2) along grain boundaries and cracks occurs. Another generation of Mg-rich ilmenite maybe produced by exsolution processes (type 3 ilmenite). Although the identity of the host mineral is unclear due to extensive alteration and possibility includes enstatite. Type 4 Mn-rich ilmenite is produced before the crystallization of groundmass perovskite and ulvöspinel. It usually mantles ilmenite and other Ti-rich minerals. Type 5 Mn-rich ilmenite is produced after the crystallization of the groundmass minerals and replaces them. The contents of Cr and Nb in type 2, 4 and 5 ilmenites are highly dependent on the composition of the replaced minerals, they may not be a good argument in exploration. The highest Mg contents are recorded in metasomatic ilmenite that is produced during kimberlite emplacement, and cannot be associated with diamond formation. The higher Mn contents are linked to magmatic processes and also late processes clearly produced after the crystallization of the kimberlite groundmass, and therefore ilmenite with high Mn contents cannot be considered as a reliable diamond indicator mineral (DIM) and kimberlite indicator mineral (KIM).