A crystal-chemical classification of borate structures with emphasis on hydrated borates

The rules governing formation of hydrated borate polyanions that were proposed by C.L. Christ in 1960 are critically reviewed and new rules added on the basis of recent crystal structure determinations. Principles and classifications previously published by others are also critically reviewed briefly. The fundamental building blocks from which borate polyanions can be constructed are defined on the basis of the number n of boron atoms, and the fully hydrated polyanions are illustrated. Known structures are grouped accordingly, and a shorthand notation using n and symbols Δ = triangle, T = tetrahedron is introduced so that the polyanions can be easily characterized. For example, 3:Δ+2T describes [B₃O₃(OH)₅]^2?. Correct structural formulas are assigned borates with known structures whereas borates of unknown structure are grouped separately.     

Postglacial climates inferred from a lake at treeline,southwest Yukon Territory,Canada

Pollen, chironomid, and ostracode records from a lake located at alpine treeline provide regional paleoclimate reconstructions from the southwest Yukon Territory, Canada. The pollen spectra indicate herbaceous tundra existed on the landscape from 13.6–11 ka followed by birch shrub tundra until 10 ka. Although Picea pollen dominated the assemblages after 10 ka, low pollen accumulation rates and Picea percentages indicate minimal treeline movement through the Holocene. Chironomid accumulation rates provide evidence of millennial-scale climate variability, and the chironomid community responded to rapid climate changes. Ostracodes were found in the late glacial and early Holocene, but disappeared due to chemical changes of the lake associated with changes in vegetation on the landscape. Inferred mean July air temperature, total annual precipitation, and water depth indicate a long-term cooling with increasing moisture from the late glacial through the Holocene. During the Younger Dryas (12.9–11.2 ka), cold and dry conditions prevailed. The early and mid-Holocene were warm and dry, with cool, wet conditions after 4 ka, and warm, dry conditions since the end of the Little Ice Age.     

Spatial variability of snowmelt timing from AMSR‐E and SSM/I passive microwave sensors,Pelly River,Yukon Territory,Canada

Spring snow melt run‐off in high latitude and snow‐dominated drainage basins is generally the most significant annual hydrological event. Melt timing, duration, and flow magnitude are highly variable and influence regional climate, geomorphology, and hydrology. Arctic and sub‐arctic regions have sparse long‐term ground observations and these snow‐dominated hydrologic regimes are sensitive to the rapidly warming climate trends that characterize much of the northern latitudes. Passive microwave brightness temperatures are sensitive to changes in the liquid water content of the snow pack and make it possible to detect incipient melt, diurnal melt‐refreeze cycles, and the approximate end of snow cover on the ground over large regions. Special Sensor Microwave Imager (SSM/I) and Advanced Microwave Scanning Radiometer for EOS (AMSR‐E) passive microwave brightness temperatures (T_b) and diurnal amplitude variations (DAV) are used to investigate the spatial variability of snowmelt onset timing (in two stages, ‘DAV onset’ and ‘melt onset’) and duration for a complex sub‐arctic landscape during 2005. The satellites are sensitive to small percentages of liquid water, and therefore represent ‘incipient melt’, a condition somewhat earlier than a traditional definition of a melting snowpack. Incipient melt dates and duration are compared to topography, land cover, and hydrology to investigate the strength and significance of melt timing in heterogeneous landscapes in the Pelly River, a major tributary to the Yukon River. Microwave‐derived melt onset in this region in 2005 occurred from late February to late April. Upland areas melt 1–2 weeks later than lowland areas and have shorter transition periods. Melt timing and duration appear to be influenced by pixel elevation, aspect, and uniformity as well as other factors such as weather and snow mass distribution. The end of the transition season is uniform across sensors and across the basin in spite of a wide variety of pixel characteristics. Copyright © 2007 John Wiley & Sons, Ltd.     

Modelling river water temperature using deterministic,empirical, and hybrid formulations in a Mediterranean stream

River water temperature is a common target of water quality models at the watershed scale, owing to its principal role in shaping biogeochemical processes and in stream ecology. Usually, models include physically‐based, deterministic formulations to calculate water temperatures from detailed meteorological information, which usually comes from meteorological stations located far from the river reaches. However, alternative empirical approaches have been proposed, that usually depend on air temperature as master variable. This study explored the performance of a semidistributed water quality application modelling river water temperature in a Mediterranean watershed, using three different approaches. First, a deterministic approach was used accounting for the different heat exchange components usually considered in water temperature models. Second, an empirical approximation was applied using the equilibrium temperature concept, assuming a linear relationship with air temperature. And third, a hybrid approach was constructed, in which the temperature equilibrium concept and the deterministic approach were combined. Results showed that the hybrid approach gave the best results, followed by the empirical approximation. The deterministic formulation gave the worst results. The hybrid approach not only fitted daily river water temperatures, but also adequately modelled the daily temperature range (maximum–minimum daily temperature). Other river water features directly dependent on water temperature, such as river intrusion depth in lentic systems (i.e. the depth at which the river inflow plunges to equilibrate density differences with lake water), were also correctly modelled even at hourly time steps. However, results for the different heat fluxes between river and atmosphere were very unrealistic. Although direct evidence of discrepancies between meteorological drivers measured at the meteorological stations and the actual river microclimate was not found, the use of models including empirical or hybrid formulations depending mainly on air temperature is recommended if only meteorological data from locations far from the river reaches are available. Copyright © 2008 John Wiley & Sons, Ltd.     

Long-term persistence of solar activity

The solar irradiante has been found to change by 0.1% over the recent solar cycle. A change of irradiante of about 0.5% is required to effect the Earth's climate. How frequently can a variation of this size be expected? We examine the question of the persistence of non-periodic variations in solar activity. The Hürst exponent, which characterizes the persistence of a time series (Mandelbrot and Wallis, 1969), is evaluated for the series of¹⁴ C data for the time interval from about 6000 BC to 1950 AD (Stuiver and Pearson, 1986). We find a constant Hürst exponent, suggesting that solar activity in the frequency range of from 100 to 3000 years includes an important continuum component in addition to the well-known periodic variations. The value we calculate,H ≈ 0.8, is significantly larger than the value of 0.5 that would correspond to variations produced by a white-noise process. This value is in good agreement with the results for the monthly sunspot data reported elsewhere, indicating that the physics that produces the continuum is a correlated random process (Ruzmaikin et al., 1992), and that it is the same type of process over a wide range of time interval lengths. We conclude that the time period over which an irradiance change of 0.5% can be expected to occur is significantly shorter than that which would be expected for variations produced by a white-noise process. The full paper has been submitted to Solar Physics. Part of the research decribed here was carried out by JPL, Caltech under a contract with NASA.     

On the electrical conductivity of air inside buildings

Summary Simultaneous measurements of the electrical conductivity of air inside and outside of buildings have been performed with continuously recording electronic instruments of high sensitivity and short time constant. It appears that the electrical conductivity, a measure of the natural ionization of air, is one atmospheric-electric parameter that can manifest itself inside occupied buildings without appreciable difference in physical character from outside values.The probable importance of these experimental results for the field of bioclimatology is pointed out and the possibility is discussed that the electrical conductivity of air might be one of the searched—for parameters in associating physiological phenomena with weather changes.

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Zusammenfassung Gleichzeitige Messungen der luftelektrischen Leitfähigkeit im Freien und innerhalb von Gebäuden wurden mit kontinuierlich registrierenden Röhreninstrumenten von großer Empfindlichkeit und kurzer Zeitkonstante durchgeführt. Es wurde gefunden, daß die Leitfähigkeit als Maß der natürlichen Luftionisierung eine luftelektrische Größe darstellt, die ohne wesentliche physikalische Beeinflussung in bewohnte Gebäude einzudringen vermag.Die mögliche Bedeutung dieser experimentellen Ergebnisse für das Gebiet der Bioklimatologie wird angedeutet und die Wahrscheinlichkeit diskutiert, daß die luftelektrische Leitfähigkeit einen der noch unbestimmten Faktoren des Zusammenhanges physiologischer Erscheinungen mit Wetterveränderungen darstellen könnte.

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Résumé Des instruments électroniques à enregistrement continu de haute fidelité et ayant une constante de courte durée ont permis de prendre des mesures simultanées de la conductivité électrique de l'air à l'intérieur et à l'extérieur de bâtiments. Il semble que la conductivité électrique, mesure de l'ionisation naturelle de l'air, soit un paramètre de l'électricité atmosphérique qui peut se manifester à l'intérieur de bâtiments habités sans différence appréciable de caractéristiques physiques avec celles des valeurs extérieures.L'importance probable de ces résultats expérimentaux dans le champ de la bioclimatologie est indiquée, et la possibilité que la conductivité atmosphérique puisse être un des paramètres recherchés dans l'association des phénomènes physiologiques avec des changements du temps est étudiée.

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With 1 Figure.

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Publication No. 25 of the Institute of Geophysics, University of California at Los Angeles. The research reported in this paper has been sponsored in part by the Geophysics Research Directorate of the Air Force Cambridge Research Center, Air Research and Development Command, under Contract No. AF 19(122)-254.     

The effect of seawater magnesium on natural fluorescence during estuarine mixing,and implications for tracer applications

Natural fluorescence, which is thought to result from low molecular weight humic and fulvic compounds, can be used as a tracer to distinguish between individual river waters. Natural fluorescence exhibits conservative mixing with seawater, except for a slight fluorescence increase which is sometimes observed in the low salinity range (0–5‰). This increase is not due to the inner filter effect (internal quenching). Laboratory experiments can reproduce this low-salinity natural fluorescence increase. Of the major seawater ions, only magnesium can cause a similar natural fluorescence increase. Variation in sample pH, ionic strength, or particle content cannot explain the natural fluorescence increase, nor does it appear to be related to the estuarine flocculation of humic material. Addition of seawater magnesium to the fluorescent material with subsequent loss of hydrogen ions could enhance fluorescence by adding crosslinking to the structure. Replacement of a fluorescence-depressing metal like copper or iron by magnesium could also enhance fluorescence, essentially by removing the quenching effect of the metal. Experimental data in this study are consistent with both of these possible mechanisms. Calcium also enhances fluorescence, however the effect of seawater calcium during estuarine mixing is not as apparent as the magnesium effect. The implications of this low-salinity natural fluorescence increase with respect to estuarine and coastal tracer applications depend on whether individual rivers mix in the high or low salinity region of an estuary or coastal area.     

Conduit-vent structures and related proximal deposits in the Las Cañadas caldera, Tenerife, Canary Islands

The Las Cañadas caldera wall and the outer slopes of the caldera provide three-dimensional exposures of numerous proximal-welded fallout deposits and have been mapped in detail. As a result, some parts of the Ucanca and Guajara Formations of the stratigraphy of Martí et al. (1994) have been divided into members that correspond to individual eruptions. Mapping has also revealed the occurrence of conduit-vent structures associated with proximal-welded fallout deposits. Conduit-vent structures consist of an upper flaring area and a lower narrow conduit. Conduit-vent geometry and dimensions include cylindrical plugs and eruptive fissures steeply dipping towards the caldera depression and elongated vents. The flaring area can be rather asymmetric and is usually filled by down-vent rheomorphic flow of the proximal fallout deposit. The lower conduits are filled by lava plug, agglutination of juveniles onto conduit walls and dyke intrusion with eventual dome extrusion. The eruption dynamics of welded fallout deposits and magma fragmentation within the conduit are consistent with an evolution from explosive to effusive. In this context conduit flow regimes evolve from turbulent to annular flow in which the conduit is progressively choked, and laminar flow leading to the final conduit closure.