Optimal pumping from Palmela water supply wells (Portugal) using simulated annealing

Aquifer systems are an important part of an integrated water resources management plan as foreseen in the European Union’s Water Framework Directive (2000). The sustainable development of these systems demands the use of all available techniques capable of handling the multidisciplinary features of the problems involved. The formulation and resolution of an optimization model is described for a planning and management problem based on the Palmela aquifer (Portugal), developed to supply a given number of demand centres. This problem is solved using one of the latest optimization techniques, the simulated annealing heuristic method, designed to find the optimal solutions while avoiding falling into local optimums. The solution obtained, providing the wells location and the corresponding pumped flows to supply each centre, are analysed taking into account the objective function components and the constraints. It was found that the operation cost is the biggest share of the final cost, and the choice of wells is greatly affected by this fact. Another conclusion is that the solution takes advantage of the economies of scale, that is, it points toward drilling a large capacity well even if this increases the investment cost, rather than drilling several wells, which together will increase the operation costs.     

Chemistry of the Ferraria thermal water, S. Miguel Island, Azores: mixing and precipitation processes

The Ferraria thermal water emerges at the sea level in the Ferraria lava delta (western edge of S. Miguel Island, Azores) with temperature of ca. 60°C and pH varying between 5.4 and 6.2. It is of sodium chloride type, resulting from ca. 50% seawater mixing with an acid brackish, at ≈100°C, denoting the presence of significant CO₂(g) and the progress of water–rock interactions in open system conditions. The thermal Na–Cl water is strongly enriched with Sr and Mn and, comparatively, has low concentrations in Al, Fe and As. These elements are removed from the solution as critical conditions for the formation of several neo-formed mineral phases are gradually attained. Thermodynamic equilibrium calculations are consistent with this interpretation, showing that the thermal fluid can precipitate Fe³⁺-(hydr-)oxides, kaolinite and non-crystalline silica. Wells logging show fracture planes and pores fully/partly filled up with polyphase botryoidal aggregates mostly composed of goethite + ferrihydrite and displaying variable adsorbed contents of Si, P and As. These neo-formed phases result from the pristine fluid oxidation due to seawater mixing; its precipitation is easily affected by pH and redox variations of the brackish, due to volcanic gases pressure alterations, and fluid pressure or flow-velocity oscillation in the fractured aquifer.     

Impacts of macroalgal spores on the dynamics of adult macroalgae in a eutrophic estuary: high versus low hydrodynamic seasons and long-term simulations for global warming scenarios

A model describing macroalgal early life stages and adult dynamics was used to quantify the effects of non-adult forms on the productivity of adult macroalgae in a eutrophic estuary. Predictions indicate that during years with mild winters and low rainfall, spring blooms will occur at the expense of the growth and reproduction of overwintering adults and without the contribution of the spore bank. In these circumstances, there is a positive correlation between the intensity of the blooms and the biomass of overwintering adults until a maximum threshold value. On the contrary, in years with high rainfall and low or inexistent biomass of overwintering adults, the onset of adult’s growth depends on the biomass of viable dormant spores, the growing season occurs later and adult productivity is very limited. Long-term predictions for climate change scenarios suggest that, in general, global warming will have adverse affects on Ulva intestinalis productivity, with the adults being more affected than the early life stages.     

A critical review of approaches to aquatic environmental assessment

As demands on aquatic resources increase, there is a growing need to monitor and assess their condition. This paper reviews a variety of aquatic environmental assessments, at local, national, international and global scales and finds confusion in the terminology used to describe assessments. In particular the terms 'ecosystem' and 'integrated' are often misused resulting in lack of clarity. Therefore, definitions of some assessment terminology are suggested, consolidating existing proposals and simplifying future applications. A conclusion from the review is that a new classification system is required. The categorisation system proposed builds on preliminary work of the International Council for the Exploration of the Sea (ICES). Assessment classification is based on the environmental components considered, methodologies and nature of the linkages between components, and the inclusion or exclusion of socio-economic factors. The assessment terminology and categorisation system provided could in future simplify the way that assessments are defined and used to inform development of management strategies.     

Fe,Mn, P and S Speciation in Sediments from the Capivara Hydroelectric Dam Lake (Brazil) as an Indicator of Anthropogenic Influences

The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments.     

Estimating free parameters in 2D inversion: example of gravity inversion in a rifted basement

We advance a principle directed to assigning numerical values to free parameters usually present in inversion methods. It may be formulated as: ‘Optimum estimates of free parameters in an inversion procedure must lead, in tests using synthetic data, to solutions whose geometrical expression reflects the main qualitative or semiquantitative geological characteristic of the study area.’ To this end, the interpreter should (i) specify a typical anomalous source geometry which incorporates the most relevant geological information for the study area, (ii) compute the corresponding gravity anomaly and (iii) invert the anomaly for the source geometry finding the numerical values of the free parameters that lead to a solution closest to the typical source. Application of the above methodology to synthetic and real data from the basement relief of a rift basin has asserted its efficacy.     

A Note on Extension Variances in IR2

Matheron (1971) proposed an approximation of the extension variance in IR. We propose in this note an extension of this formula in IR ² , based on a MacLaurin formula. Its application is shown in an example, the estimation of the maximum depressional storage of a soil surface.     

Pathogenic fungi: an unacknowledged risk at coastal resorts? New insights on microbiological sand quality in Portugal

Whilst the potential impact on beach users from microorganisms in water has received considerable attention, there has been relatively little investigation into microbial contaminants in sand. Thirty three beaches across Portugal were analyzed during a five year period (2006-2010) to determine the presence of yeasts, pathogenic fungi, dermatophytes, total coliforms, Escherichia coli and intestinal enterococci in sand.Our results showed that 60.4% of the samples were positive for fungi and that 25.2% were positive for the bacterial parameters. The most frequent fungal species found were Candida sp. and Aspergillus sp., whereas intestinal enterococci were the most frequently isolated bacteria. Positive associations were detected among analyzed parameters and country-regions but none among those parameters and sampling period.Regarding threshold values, we propose 15 cfu/g for yeasts, 17 cfu/g for potential pathogenic fungi, 8 cfu/g for dermatophytes. Eighty four cfu/g for coliforms, 250 cfu/g for E. coli, and 100 cfu/g for intestinal enterococci.     

Climatic signals in lacustrine deposits of the Upper Yacoraite Formation,Western Argentina: Evidence from clay minerals,analcime, dolomite and fibrous calcite

Authigenic clays are an important control on reservoir quality in lacustrine carbonates but remain challenging to predict. Lacustrine depositional systems respond to climatic variations in rainfall, surface runoff and groundwater input, and evaporation, and result in rapid and frequent changes in lake volume; this is expressed through changing water depth and shoreline position. In the upper portion of the Early Palaeocene Yacoraite Formation of the Salta Basin in Argentina, extensive lacustrine deposits were deposited during the sag phase of rifting. Prior high-resolution stratigraphic studies have suggested that climatic factors control microbial carbonate sequences within a ‘balanced fill’ lake, with variation in the lake level having a major influence on facies association changes. This study characterizes the evolution of facies and mineralogy within the Yacoraite Formation, focusing on the distribution of clay minerals, making a link between the high, medium and low-frequency sequence stratigraphic cycles. The low-frequency transgressive hemicycle of the upper portion of the Yacoraite Formation is comprised of abundant siliciclastic facies, suggesting a wetter period. Microbialites occurring in this interval are coarse-grained and agglutinated. Detrital clay minerals such as illite and chlorite and associated siliciclastic sediments were input to the lake during high-frequency transgressive periods. During high-frequency regressive hemicycles, sedimentation was dominated by carbonate facies with Ca-rich dolomite and the authigenic clays are comprised of chlorite/smectite mixed-layers. By contrast, the low frequency regressive hemicycle records fine-grained agglutinated microbialite with horizons of fibrous calcite, more stoichiometric dolomite, barite and authigenic magnesian smectite. This indicates elevated ion concentrations in the lake under intense evaporation during an arid period. Understanding the conditions that are favourable for formation and preservation of authigenic clays within the lacustrine environment can improve understanding of reservoir quality in comparable economically important deposits.