Geochronology of granulites from the south Itabuna-Salvador-Curaçá Block,São Francisco Craton (Brazil): Nd isotopes and U–Pb zircon ages

This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event.     

Numerical predictions of the behaviour of soft clay with two anisotropic elastoplastic models

The numerical predictions obtained with the Melanie and MIT-E3 models are compared. Firstly, the performance of the constitutive models is checked against undrained triaxial tests. The models are then used to replicate the behaviour of an embankment built on soft clay. The numerical results are compared with the field data in terms of settlements, lateral displacements and excess pore pressures. Additionally, the numerical predictions are also analysed in terms of yield area, contours of vertical effective stresses, horizontal effective stresses and shear stresses and in terms of effective stress paths.     

K–Ar and Ar/Ar ages of dikes emplaced in the onshore basement of the Santos Basin, Resende area, SE Brazil: implications for the south Atlantic opening and Tertiary reactivation

New K–Ar and ⁴⁰Ar/³⁹Ar data of tholeiitic and alkaline dike swarms from the onshore basement of the Santos Basin (SE Brazil) reveal Mesozoic and Tertiary magmatic pulses. The tholeiitic rocks (basalt, dolerite, and microgabbro) display high TiO₂ contents (average 3.65 wt%) and comprise two magmatic groups. The NW-oriented samples of Group A have (La/Yb)_N ratios between 15 and 32.3 and range in age from 192.9±2.2 to 160.9±1.9 Ma. The NNW-NNE Group B samples, with (La/Yb)_N ratios between 7 and 16, range from 148.3±3 to 133.9±0.5 Ma. The alkaline rocks (syenite, trachyte, phonolite, alkaline basalts, and lamprophyre) display intermediate–K contents and comprise dikes, plugs, and stocks. Ages of approximately 82 Ma were obtained for the lamprophyre dikes, 70 Ma for the syenite plutons, and 64–59 Ma for felsic dikes. Because Jurassic–Early Cretaceous basic dikes have not been reported in SE Brazil, we might speculate that, during the emplacement of Group A dikes, extensional stresses were active in the region before the opening of the south Atlantic Ocean and coeval with the Karoo magmatism described in South Africa. Group B dikes yield ages compatible with those obtained for Serra Geral and Ponta Grossa magmatism in the Paraná Basin and are directly related to the breakup of western Gondwana. Alkaline magmatism is associated with several tectonic episodes that postdate the opening of the Atlantic Ocean and related to the upwelling of the Trindade plume and the generation of Tertiary basins southeast of Brazil. In the studied region, alkaline magmatism can be subdivided in two episodes: the first one represented by lamprophyre dykes of approximately 82 Ma and the second comprised of felsic alkaline stocks of approximately 70 Ma and associated dikes ranging from 64 to 59 Ma.

Resumo

Novos dados K–Ar e ⁴⁰Ar/³⁹Ar de enxames de diques toleíticos e alcalinos localizados no embasamento onshore da Bacia de Santos (SE Brasil) apontam para diferentes pulsos magmáticos ocorridos entre o Jurássico e o Terciário. Os diques de rochas toleíticas (basalto, diabásio e microgabro), são mais velhos, exibem altos teores de TiO₂ (3,65% peso na média) e podem ser subdivididos em dois grupos magmáticos. O Grupo A aflora a norte da Bacia de Resende, compreende diques orientados na direção NW, com razões (La/Yb)_N entre 15 e 32,3, e idades entre 192.9±2.2 e 160.9±1.9 Ma. O Grupo B aflora a sul e a leste da Bacia de Resende, engloba diques orientados na direção NNW e NNE, com razões (La/Yb)_N entre 7 e 16, e idades obtidas entre 148.3±3 e 133.9±0.5 Ma. As rochas alcalinas (sienito, traquito, fonolito, basalto alcalino e lamprófiro) possuem teores médios de K, e afloram como diques, plugs e stocks.. As idades obtidas são de ca. 82 Ma para os diques lamprofíricos, de ca. 70 Ma para os plugs sieníticos, e entre 64 e 59 Ma para os diques félsicos. Como estas idades Jurássicas para diques toleíticos ainda não foram descritas para a região sudeste do Brasil, pode-se especular que durante o emplacement dos diques do GrupoA o cenário tectônico indicaria esforços extensionais anteriores à abertura do Oceano atlântico Sul, e contemporânea ao derrame basáltico do Karoo na África do Sul. Já os diques do Grupo B são contemporâneos ao magmatismo Serra Geral e ao enxame de diques de Ponta Grossa, e portanto este episódio está diretamente relacionado à separação entre o Brasil e África no Cretáceo. O magmatismo alcalino está associado a diversos episódios tectônicos que sucedem à abertura do Oceano Atlântico Sul e que resultaram no desenvolvimento das Bacias terciárias do sudeste brasileiro. Está provavelmente relacionado à chegada da Pluma de Trindade e as idades obtidas para a região em estudo indicam que o magmatismo lamprofírico é mais antigo (ca. 82 Ma), seguido pelos plútons sieníticos (ca. 70 Ma) e diques associados (64 a 59 Ma.)     

Building a 3D geomodel for water resources management: case study in the Regional Park of the lower courses of Manzanares and Jarama Rivers (Madrid, Spain)

Water resources management of protected sites requires a powerful tool to analyze the process and changes that are occurring in the environment. This paper describes a 3D geomodel design of the Jarama River Detrital Aquifer located in Madrid (Spain). That hydrogeological unit is included in the “Parque Regional de los Cursos Bajos de los Ríos Manzanares y Jarama” (Regional Park of the Lower Courses of Manzanares and Jarama Rivers). The goal of this work is to define a method by which a three-dimensional (3D) model can be created with hydrogeologic geometry real of main aquifer, to accomplish an adequate management of the groundwater resources. All data used in this study were integrated in a geographic database: geological and hydrogeological information, geological map (1:25,000), eleven cross-sections, piezometric maps and a digital elevation model. The constructed 3D model of the Jarama Aquifer shows geometric features and spatial distribution and variations of geologic units. Thus, the 3D model allows the assessment of volumes of each unit, the depth and thickness variations of the main aquifer, and the spatial and temporal variations of water tables. From the 3D model, the most suitable areas (in terms of groundwater protection) for managed recharge and mining works have been identified.     

Density-Stratified Flow Events in Great Salt Lake,Utah, USA: Implications for Mercury and Salinity Cycling

Density stratification in saline and hypersaline water bodies from throughout the world can have large impacts on the internal cycling and loading of salinity, nutrients, and trace elements. High temporal resolution hydroacoustic and physical/chemical data were collected at two sites in Great Salt Lake (GSL), a saline lake in the western USA, to understand how density stratification may influence salinity and mercury (Hg) distributions. The first study site was in a causeway breach where saline water from GSL exchanges with less saline water from a flow restricted bay. Near-surface-specific conductance values measured in water at the breach displayed a good relationship with both flow and wind direction. No diurnal variations in the concentration of dissolved (<0.45 μm) methylmercury (MeHg) were observed during the 24-h sampling period; however, the highest proportion of particulate Hg_total and MeHg loadings was observed during periods of elevated salinity. The second study site was located on the bottom of GSL where movement of a high-salinity water layer, referred to as the deep brine layer (DBL), is restricted to a naturally occurring 1.5-km-wide “spillway” structure. During selected time periods in April/May, 2012, wind-induced flow reversals in a railroad causeway breach, separating Gunnison and Gilbert Bays, were coupled with high-velocity flow pulses (up to 55 cm/s) in the DBL at the spillway site. These flow pulses were likely driven by a pressure response of highly saline water from Gunnison Bay flowing into the north basin of Gilbert Bay. Short-term flow reversal events measured at the railroad causeway breach have the ability to move measurable amounts of salt and Hg from Gunnison Bay into the DBL. Future disturbance to the steady state conditions currently imposed by the railroad causeway infrastructure could result in changes to the existing chemical balance between Gunnison and Gilbert Bays. Monitoring instruments were installed at six additional sites in the DBL during October 2012 to assess impacts from any future modifications to the railroad causeway.     

First U–Pb SHRIMP age of the Hauterivian stage, Neuquén Basin, Argentina

A high-resolution ion-microprobe (SHRIMP) U–Pb zircon age from a tuff layer intercalated in the ammonoid bearing sedimentary succession of the Neuquén Basin in Argentina provides a robust geochronologic date to add to the absolute ages and to improve the relative chronology of the Early Cretaceous Hauterivian stage. The tuff layer appears interbedded between shales of the upper member (Agua de la Mula) of the Agrio Formation within the Spitidiscus riccardii ammonoid zone (base of the Late Hauterivian) yielding a date of 132.5 ± 1.3 Ma. This date confirms and supports an accurate correlation between the ammonoid biostratigraphy of the Neuquén Basin with the Western Mediterranean Province of the Tethys during the Early Cretaceous and matches with the most recently published time scale. It also casts doubts on the validity of K–Ar ages on glauconite-grains recently reported from the Lower Cretaceous of the Vocontian Basin of France.     

An orthotropic interface damage model for simulating drying processes in soils

The study of drying process in soils has received an increased attention in the last few years. This is very complex phenomenon that generally leads to the formation and propagation of desiccation cracks in the soil mass. In recent engineering applications, high aspect ratio elements have proved to be well suited to tackle this type of problem using finite elements. However, the modeling of interfaces between materials with orthotropic properties that generally exist in this type of problem using standard (isotropic) constitutive model is very complex and challenging in terms of the mesh generation, leading to very fine meshes that are intensive CPU demanding. A novel orthotropic interface mechanical model based on damage mechanics and capable of dealing with interfaces between materials in which the strength depends on the direction of analysis is proposed in this paper. The complete mathematical formulation is presented together with the algorithm suggested for its numerical implementation. Some simple yet challenging synthetic benchmarks are analyzed to explore the model capabilities. Laboratory tests using different textures at the contact surface between materials were conducted to evaluate the strengths of the interface in different directions. These experiments were then used to validate the proposed model. Finally, the approach is applied to simulate an actual desiccation test involving an orthotropic contact surface. In all the application cases the performance of the model was very satisfactory.     

U-Pb dating of an early paleozoic bimodal magmatism in the french Massif Central and of its further metamorphic evolution

In the Marvejols area (Southern french Massif Central), the gneissic Marvejols supergroup is overthrust on the metasedimentary “Série du Lot”, deposited in part prior to 540 Ma. The allochtonous terranes are characterized by the occurrence of a leptyno-amphibolitic group, a complex association of mafic and felsic rocks of igneous and sedimentary derivation. A 480±10 Ma age has been obtained by U-Pb dating of zircons, for the crystallization of both mafic and felsic meta-igneous rocks. These rocks were emplaced during an important extensional tectonics. Relics of eclogites, pyrigarnites, coronite gabbros and HP-trondhjemites are clear evidence for a further HP-HT event dated at 415±6 Ma on zircons from a HP trondhjemite. Subsequently, the Marvejols supergroup underwent an amphibolite facies metamorphism with incipient mobilization dated at 345±10 Ma. Rifting and thinning of the continental crust in Cambro-Ordovician times appears to be a major geodynamic feature which could account for the thermal events often referred to the “Caledonian” orogeny. The Silurian (415 Ma) age of the HP episode is clearly older than the main Variscan tectonometamorphic event; it is in agreement with Rb-Sr dating of the Moldanubian granulites and with some radiometric data from Southern Brittany (France). These results point to a compressive phase, probably in a subduction context, in view of the high pressures reached (15–20 Kb), after the Cambro-Ordovician distensive phase. The main final tectono-metamorphic paroxysm (blocking of subduction process and continental collison ?) is not prior to the end of Devonian (340–350 Ma) and is related to the Variscan orogeny s.s     

Water contamination and remedial measures at the Troya abandoned Pb-Zn mine (The Basque Country, Northern Spain)

 This article describes a case of contamination of a karstic aquifer by abandoning an underground mine exploiting sulphide ore body. To exploit the ore, the aquifer was drained and the water level declined about 230 m, drying up the spring that had drained the aquifer up to that moment. When the mining activity ceased, the piezometric level recovered and contaminated water began to flow out from a mine adit. The water is high in sulphates and dissolved Fe, although the pH is neutral. When this water reached the nearby creek, the fish population was eliminated, principally due to the presence of toxic metals and the precipitation of Fe hydroxides. The contamination originated in an area of the partially flooded mine rooms where the ore is in contact with both air and water. The acidity generated by pyrite oxidation is neutralized by calcite dissolution. Presently, the mine water is diverted to the old tailings pond which functions as an aerobic wetland. This action has allowed the fish population in the creek to be restored. Received: 20 January 1999 · Accepted: 15 March 1999