滇中禄丰地区中元古代早期球颗玄武岩的锆石U-Pb年龄、地球化学特征及其大地构造意义

在1∶5万区域地质调查的基础上,在禄丰地区东川群黑山组新发现了球颗玄武岩及凝灰岩夹层。采用LA-ICP-MS技术测得球颗玄武岩和凝灰质板岩中锆石U-Pb加权平均年龄分别为1678±10 Ma和1572±19 Ma,表明黑山组沉积时代为中元古代早期;其中球颗玄武岩SiO_2含量介于40.83%～52.56%,δEu正异常,大离子亲石元素Rb、Ba和高场强元素Nb、Ta、Th等强不相容元素相对富集,全岩地球化学显示为大陆板内低钛拉斑海相玄武岩,形成于伸展的构造环境,可能为Columbia超大陆裂解的产物。本次的发现,为准确地标定东川群时代、层序及大地构造属性提供新的参考依据,也为重塑整个滇中前寒武纪地层格架提供时代约束。     

湖南川口岩体型钨矿赋矿花岗岩地球化学特征及LA-ICP-MS锆石U-Pb定年

川口矿田钨矿床产于湖南衡阳川口岩体的外接触带及岩体内部,矿床类型主要有岩浆热液石英细脉带型和石英大脉型。近年川口矿田取得了重大找矿突破,并发现了新类型的岩体型钨矿。本文对川口岩体型钨矿床的黑云母二长花岗岩及赋矿的白云母二长花岗岩分别进行了 LA-ICP-MS锆石U-Pb定年和岩石地球化学特征研究,获得川口岩体的成岩年龄为(223.1 ± 0.78)Ma,MSWD=0.98,n=24,岩体型钨矿成矿年龄为(224.6±1.31)Ma,MSWD=0.33,n=9,为印支期成岩成矿。川口花岗岩具有高SiO_2,富K_2O+Na_2O,低CaO、MgO的特点,属于过铝质高钾钙碱性系列S型花岗岩,形成于碰撞环境下弱挤压构造体制。川口岩体稀土总量(∑REE)整体较低,轻稀土相对较富集,具有强烈的负Eu异常,富集大离子亲石元素Ba、K和高场强元素Ta,而亏损大离子亲石元素Sr和相容元素P、Ti等,表明该岩体各阶段花岗岩来自同一岩浆源,且经历了高度演化。赋矿花岗岩更低的δEu值及(La/Yb)_N值,表明其结晶分异程度更高。     

The wavelets and hierarchies of the climate system

Summary Wavelet analysis of global mean temperature data, the drought-flood data of the past 500 years in China, and the temperature time series of Shanghai, highlights the following: (1) the climatic wavelets depend on the hierarchies of a climate system; (2) for different time scales or hierarchies, a climate system may have different catastrophic points and periods; (3) for different time scales or hierarchies, variation of the Southern Hemisphere temperature has an obvious phase-lag compared with that of the Northern Hemisphere and the catastrophe points also lag behind; (4) in a cold-warm period, the cold semi-period of the Northern Hemisphere is obviously longer than the warm one; (5) for different hierarchies or time scales, there exists a phase-lag for the droughtflood variation in China moving gradually with latitude from north to south. Finally, a new technique of climate diagnosis, the phase curve of wavelets, is put forward in this paper.With 6 FiguresSupported by Chinese NKPFR.     

试论湖南衡阳盆地与地幔柱的关系及其对关键矿产深部探测的意义

衡阳盆地是华南地区独具特色的中—新生代陆相沉积盆地,其形成机制与丰富的矿产资源都十分引人注目。衡阳盆地近等轴形态,地形上表现为典型的“盆山体系”,重力资料显示出地幔隆起的特征,构造形式上发育“棋盘状”和“环形(弧形)”格局,火成岩与成矿元素组合以及同位素特征均具有幔源特征,这表明衡阳盆地的形成与华南地区中生代地幔柱活动之间具有密切的成因联系。盆地及其周缘矿产资源具有长时期、多矿种、强富集的特征。不同时代和不同矿种组合的成矿作用与区域岩浆作用和盆地沉积作用具有明显的专属性。衡阳盆地及周边不但出现了丰富的有色金属和非金属矿产,也出现了钨锡铌钽铋碲铀等关键矿产,但后者的工作程度最低。因此,在深部矿产探测过程中应做到“四注意四加强”。     

中国煤系高岭岩(土)资源成矿机理与开发利用

中国含煤地层中高岭岩（土）分布广泛，成矿时代多，成因复杂，储量丰富，质地优良，是一种重要的自然资源和非金属矿产，具有极高的开发利用价值，在全世界独具特色。本文研究了中国煤系高岭岩（土）资源概况、研究简史；根据成分、结构、地质产状等特征，提出了中国煤系高岭岩（土）的成因类型；对生物和有机质在其形成中的作用进行了分析和探讨，并结合有机酸溶解矿物模拟实验对其成矿作用做了初步探索；最后对煤系高岭岩的某些关键性加工技术进行了简述。     

Ecological effects analysis of land use change in coal mining area based on ecosystem service valuing: a case study in Jiawang

Land use change is one of the uppermost driving forces of regional ecosystem change, and has a huge impact on the environmental balance. Mining areas with intensive resources exploitation and utilization have undergone different kinds of environmental influences, such as water pollution and land use cover change. The extensive coal mining in China has led to significant regional land use change resulting in major ecological damage. The objective of this study was to form a clearer picture of the regional ecological environmental situation for promoting ecological protection and improvement by ecosystem service valuing. The case study area was selected at Jiawang town, which has undergone extensive coal mine exploitation for many decades. The study investigated the relationship between land use change and ecological environment, and described the ecosystem service value variations in Jiawang, based on remote sensing and GIS technology. After modification of regional ecosystem service value coefficients, the method was used to evaluate the conditions in the study area from 1990 to 2005 based on the land use/cover information interpreted from TM/ETM+ images. The characters and changes of ecosystem service values were then analyzed both quantitatively and spatially.     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

川西北早志留世陆源碎屑──碳酸盐混积缓坡

研究区位于扬子地块西北缘，由一套巨厚的页岩、泥岩层夹生物礁及透镜状和不规则层状风暴生屑灰岩、瘤状灰岩组成。根据区内特征的岩石类型及其组合、分布和相应的化石生态，作者认为本区兰多维列期至早温洛克期时为一典型的陆源碎屑－－碳酸盐混积均斜缓坡，并且从浅到深划分为滨岸、浅缓坡、深缓坡及盆地等亚环境。滨岸区位于潮间带，以潮坪碳酸盐岩为代表；浅缓坡位于浪基面至风暴浪基面之间，岩性组合为Ａ、Ｂ类风暴岩，Ａ、Ｂ类瘤状灰岩、生物礁灰岩及粘结岩；深缓坡位于风暴浪基面至最大风暴浪基面之间，岩性以Ｄ、Ｅ类风暴岩、Ｃ类瘤状灰岩及泥页岩组合为特征；盆地处于最大风暴浪基面之下，为黑色泥页岩沉积。结合早志留世时全球冰川作用，文中讨论了海平面变化的原因及对环境的影响。     

甘肃省近50 a夏季极端强降水量的气候特征

利用甘肃省1960—2006年59个台站逐日降水资料,根据百分位值法定义了不同台站的极端强降水阈值,统计出了夏季（6～8月）逐年逐站极端强降水量,并进行了时空特征诊断。结果表明：一致性异常分布是甘肃省夏季极端强降水量的最主要空间模态;夏季极端强降水量的异常空间分布可分为陇南型、陇中型、河西西部型、河西东部型及陇东型5个关键区;在5个关键区中,陇南区、陇中区近47a来夏季极端强降水量表现出减少趋势,河西东部区与陇东区表现出增加趋势,而河西西部区却经历了少-多-少的抛物线型变化;另外从周期分析来看,甘肃省夏季极端强降水量近47a来在大多数分区存在11～13a和6～8a的振荡周期。     

东南亚中南半岛锡矿带成矿特征

东南亚中南半岛位于特提斯成矿域和西环太平洋成矿域的相交地带,在印支—喜山期发生了多期次俯冲、碰撞造山成矿作用,发育多个与中酸性岩浆活动密切相关的锡(钨)岩浆热液成矿系统,形成了世界著名的东南亚中南半岛锡矿带。研究区自西向东依次可划分为抹谷—毛淡棉—德林达依—普吉锡矿带、景栋—清莱—清迈锡矿带和越北—长山—昆嵩—大叻锡矿带三大锡矿带及7个锡矿亚带,锡矿化花岗岩多为高度分异演化的重熔型铝过饱和花岗岩类,具有多硅、富碱、多挥发分、高钾、87Sr/86Sr初始比值高、Rb/Sr值高、相对明显富集Be、Bi、Cu、Mo、Pb、Sn、Y、Zn等元素的特点。锡矿体主要分布于S型花岗岩与围岩的内、外接触带。锡矿床成矿类型主要有热液脉型、矽卡岩型、锡石—硫化物型、云英岩型、伟晶岩—细晶岩型等。从海西晚期到喜山早期都有锡的成矿事件发生,以燕山期锡成矿作用为主,成矿构造环境主要为岛弧环境和大陆边缘碰撞造山环境。