Raman Micro-Spectroscopic Study of Sulfate Ion in the System Na2SO4 – H2O

This work aims to quantify sulfate ion concentrations in the system Na₂SO₄-H₂O using Raman micro-spectroscopy.Raman spectra of sodium sulfate solutions with known concentrations were collected at ambient temperature（293 K） and in the 500 cm^₁-4000 cm^-1 spectral region.The results indicate that the intensity of the SO₄^2- band increases with increasing concentrations of sulfate ion.A linear correlation was found between the concentration of SO₄^2-（c） and parameter I₁,which represents the ratio of the area of the SO₄^2- band to that of the O-H stretching band of water（A_s/A_w）:I₁=-0.00102+0.01538 c.Furthermore,we deconvoluted the O-H stretching band of water(2800 cm^-1-3800 cm^-1) at 3232 and 3430 cm^-1 into two sub-Gaussian bands,and then defined Raman intensity of the two sub-bands as A_Bi(3232 cm^-1) and A_B2(3430 cm^-1),defined the full width of half maximum（FWHM） of the two sub-bands as W_B1(3232 cm^-1) and W_B2(3430 cm^-1).A linear correlation between the concentration of SO₄^2-（c） and parameter I₂,which represents the ratio of Raman intensity of SO₄^2-（A_s）(in 981 cm^-1) to(A_B1+A_B2),was also established:I₂=-0.0111+0.3653 c.However,no correlations were found between concentration of SO₄^2-（c） and FWHM ratios,which includes the ratio of FWHM of SO₄^2-（W_s） to W_B1 W_B2 and W_B1+B2(the sum of W_B1 and W_B2),suggesting that FWHM is not suitable for quantitative studies of sulfate solutions with Raman spectroscopy.A comparison of Raman spectroscopic studies of mixed Na₂SO₄ and NaCI solutions with a constant SO₄^2- concentration and variable CI^- concentrations suggest that the I\ parameter is affected by CI^-,whereas the I₂ parameter was not.Therefore,even if the solution is not purely Na₂SO₄-H₂O,SO₄^2- concentrations can still be calculated from the Raman spectra if the H₂O band is deconvoluted into two sub-bands,making this method potentially applicable to analysis of natural fluid inclusions.     

An Review of International Climate Change Conference and Analysis on Recent Hot Issues

The international climate change negotiation has been carried out over 20 years. The issue of climate change has shifted from a scientific question into a complex political matter which is related to the sustainable development of mankind. Based on the overview of major processes and stages of international climate conferences, this paper analyzed the key measures that major countries have taken to address climate change, as well as the primary tasks of Paris climate conference and recent international actions. The recent international climate policy issues were also analyzed in order to provide suggestions for China’s activel participation in the development of a new round of international climate change system.     

南北构造带北部石炭纪东西沉积边界分合演变及其地质意义

南北构造带是中国大陆地质构造及深部过程和地表系统的重要分界线,也是地震活动的多发地带,对其在前中生代是否存在、不同时期各区带的构造属性和联系研究薄弱。文中以南北构造带北部为研究对象,重点讨论其中南段,探讨研究区石炭纪地质构造特征及其与具分区意义的南北构造带形成演化的联系。研究表明,在石炭纪,今南北构造带北部所在地区处于伸展裂陷环境,断裂活动强烈,总体控制着河西走廊—北祁连沉积域的东界和隆拗格局及沉积厚度等变化。南北构造带北部及其西沉积区的断裂活动和沉积演化,经历了前黑山期初始裂陷、臭牛沟期进一步(向北)扩张、土坡期沉积-沉降鼎盛及太原期衰减4个阶段。其中于晚石炭世土坡晚期(本溪期)和太原期,东(华北)、西沉积域的沉积范围均向南北构造带北部扩展,先后经历了北部连通到全部相通的演变过程。石炭纪各期诸断裂与中、新生代断裂在位置和方向上具有明显的相关性,反映二者成生和演化联系密切。南北构造带北部及邻区,在石炭纪主要时期分隔华北和河西走廊—北祁连两大沉积域,东、西沉积域的沉积边界在该区带的分合演变和建造特征及断裂的主控因素,显示该区带在石炭纪已属具明显分区作用的重要地质构造单元,为此后南北构造带北部的进一步发展演化和重要的构造地位奠定了基础。     

点云滤除临时动地物构建表面模型方法探讨

针对获取高精度数字表面模型(DSM)效率不高的现状,文章研究了基于机载激光雷达点云滤除临时动地物的方法:通过对TIN迭代滤波与聚类进行改进,提出了两种滤除临时动地物构建DSM的方法,第一种是基于数据流TIN迭代与临时动地物的特征,直接滤除临时动地物构建DSM;第二种是基于数字高程模型(DEM),逆向添加滤除临时动地物点的非地面点构建DSM。最后通过实验证明这两种方法均可较好地滤除临时动地物构建DSM。     

“天地图·榆林”市级节点电子地图建设研究

结合"天地图·榆林"市级节点项目中的电子地图建设,探讨天地图市级节点18级至20级矢量电子地图和影像电子地图、专题电子地图的数据选取、数据处理和电子地图制作等内容,对市级电子地图建设有一定的参考。     

基于ROACH的微波全息法相关机设计

基于ROACH开发平台设计了一套适用于微波全息法测量的高性能实时数字相关机,采用了带通采样技术,无需在相关机之前进行基带转换,使全息测量硬件系统更加简洁;采样速率为10 Mbps~1 000 Mbps可调,采用数字混频、数字滤波,信号带宽和频率分辨率都易于调整,具有很大的灵活性和可扩展性。测试结果表明该相关机测量精度高、稳定性好、准确可靠。     

Global distribution of the intensity and frequency of hourly precipitation and their responses to ENSO

Climate Dynamics - We investigate the global distribution of hourly precipitation and its connections with the El Niño–Southern Oscillation (ENSO) using both satellite precipitation...     

油菜花期物候主要限制因子分析及预报模型的构建

以油菜开花开始时间(即始花期)为研究对象,利用1980—2016年江苏省油菜发育期观测资料和同步气象数据,分析油菜始花期的时空变化趋势。结合油菜生理特性,筛选与油菜始花期显著相关的气象因子。以高淳站为例,采用通径分析明确各气象因子对油菜始花期的作用并评估因子敏感性,最后构建油菜始花期的回归预报模型。结果表明:在气候变化背景下江苏地区油菜始花期呈逐年提前趋势,淮河以南地区平均提前3 d以上;上年日平均气温稳定通过0℃终日(X_1)、当年日平均气温稳定通过5℃初日(X_2)、现蕾至开花前时段内分别大于0℃、5℃和10℃的有效积温(X_1、X_4和X_5)、最低气温分别小于0和5℃的日数(X_6和X_7)及平均最低气温(X_8)等8个因子与油菜始花期相关性达极显著水平;其中2月上旬至3月上旬的平均最低气温(X_8)、日最低气温小于5℃日数(X_7)、大于5℃有效积温(X_4)对油菜始花期的直接影响位列8个因子的前三位,且这3个因子两两共同对油菜始花期的相对影响程度也排在各因子对回归方程R~2总贡献率的前三位;其余5个因子直接效应普遍小于间接效应,且它们主要通过X_4、X_7、X_8对油菜始花期产生影响,而X_4、X_7、X_8也通过这5个因子产生一定影响;去掉任何一个因子,都会引起其他某些因子对油菜始花期的直接、间接作用发生变化;基于这8个因子构建的回归模型可解释68.48%的油菜始花期变化,并具有区域适用性。因此,就江苏地区而言,光照和降水对油菜开花早晚影响较小,热量条件才是江苏油菜开花早晚的主要限制因子,所构建的始花期预报模型可较好反映油菜开花时间早晚与相关热量因子变化的规律。     

An Empirical Tropical Instability Wave-induced Wind Stress Model in the Equatorial Pacific and its Incorporation into the Ocean Model

Abstract

Satellite observations revealed that there is a close relationship between perturbations of sea surface temperature (SST) and wind stress (τ) induced by tropical instability waves (TIWs; SST_TIW and τ _TIW). Using the empirical relationship observed between TIW-induced wind stress divergence (curl) and downwind (crosswind) SST gradients, this study establishes a TIW-induced wind stress field perturbation model τ _TIW?=?F(SST). This empirical model solves τ _TIW from the TIW-induced wind stress divergence and curl, which are estimated from the downwind and crosswind SST gradients. This empirical τ _TIW?=?F(SST) model can be incorporated into the ocean model to take into account the effect of τ _TIW. By comparing two experiments with and without the τ _TIW effect, this study demonstrates that τ _TIW has a substantial effect on the equatorial Pacific heat budget and induces the long-term mean SST to exhibit a 0.2°C difference, which is consistent with previous studies.