西昆仑落石沟一带铅锌矿成矿规律与找矿前景

西昆仑落石沟矿带是新疆西南部重要的成矿区带,落石沟矿带已发现铁、铜、铅锌矿(床)点13处,成矿潜力巨大。文章在综合前人工作成果的基础上,就区域内铅锌矿的分布规律、成矿地质背景、矿床地质特征、区域物化探异常特征、成矿模式、控矿因素等方面进行了介绍,重点以宝塔山、多宝山铅锌矿作为典型矿床对其成矿特征进行了分析和对比,指出西昆仑落石沟一带为寻找MVT型(碳酸盐岩容矿型)铅锌矿的有利地区,初步总结了该成矿带铅锌矿的控矿规律,确定了区域预测要素,提出了找矿有利地区。     

利用膨润土与工业废渣制轻质保温材料

本文介绍了利用膨润土、钙质造纸废渣制备轻质保温材料的研究,分析了膨润土在轻质保温材料制备中的作用,优选出制备轻质保温材料的配方和工艺。该材料的导热系数为０ ．１７１ Ｗ／ｍ·Ｋ,抗压强度约为９ ．３７ ｋｇ／ｃｍ２ ,容重为０ ．４９ ｇ／ｃｍ３ 。     

白钨矿的原位高压X射线衍射研究

使用金刚石对顶砧高压装置(DAC)和同步辐射光源,对天然白钨矿进行了原位高压能量色散X射线衍射(EDXD)研究,实验最高压力为16.0 GPa.在实验压力范围内观察到了一次白钨矿结构→钨锰铁矿结构的可逆相变:压力小于5.3 GPa时为白钨矿结构(I4_1/a),在5.3～12.3 GPa压力区间内为白钨矿结构与钨锰铁矿结构(P2/c)并存,大于12.3 GPa时完全相变为钨锰铁矿结构.从键长、配位数和配位多面体角度对白钨矿→钨锰铁矿结构的相变机制进行了解释.     

对矿物包裹体溶液性质的新认识——兼论含矿溶液是酸性溶液的地质证据

对金属矿床成矿溶液的性质 ,特别是 pH值 (酸碱度 )的确定 ,是认识含矿溶液的成因、成矿条件和成矿机理的关键。目前对成矿溶液性质的研究主要局限在对围岩蚀变矿物包裹体的测定方面 ,并得出近中性热卤水成矿的结论。作者认为 ,多数围岩蚀变矿物的包裹体溶液不能代表原成矿溶液的性质 ,“近中性的热卤水成矿”的认识有误 ,应是酸性水形成的含矿溶液成矿 ,并从矿物包裹体溶液的特征、Roedder的高金属含量的矿物包裹体溶液的发现、氢氧同位素资料、矿物包裹体中高卤水溶液的起源以及成矿溶液的演化机理等方面论述了酸性金属含矿溶液的成因及成矿演化过程。     

新疆锰矿成矿规律研究

最近新疆西昆仑地区锰矿勘查实现重大突破,伴随大型优质锰矿的发现和勘查,锰已成为新疆区域优势金属矿种之一。通过系统收集资料,总结新疆锰矿成矿类型及区域时空规律。指出寒武纪、二叠纪、石炭纪是新疆锰矿成矿的3个重要时代,西昆仑-昆盖山裂谷带、塔里木陆块北部边缘活动带是新疆锰矿成矿的重要构造单元,以海相沉积型锰矿为主要成矿类型。同时,对比中国南方重要锰矿成矿特征,指出新疆奥尔托喀讷什、穆呼锰矿与广西下雷超大型锰矿在地质构造背景、成矿时代、含矿建造、矿石类型等方面均有相似之处,在成矿空间上具某种“亲缘性”。新疆西昆仑穆呼-玛尔坎苏锰矿带具超大型锰矿成矿潜力。     

Sr,Nd,Pb Isotope Geochemistry and Magma Evolution of the Potassic Volcanic Rocks,Wudalianchi,Northeast China

Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition.     

山东开元洞发现典型"北方型"石笋微生长层

石笋中微层的形成一般认为与地表气候环境具有明显的季节变化有关~([1,2]).石笋微层的发育不仅具有明确的年代学意义~([2]),还具有重要的气候环境变化指示意义~([2,3]).     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

关于间接测定碘的分析方法研究

用硝基苯萃取[Cd（Phen）3]^2＋I2^-离子对,再用盐酸反萃取,利用氢化物发生-原子荧光光谱法测定镉的含量,从而间接测定碘。实验在pH=5．2的NaAc-HAc缓冲体系下进行,优化了还原剂KBH;中邻菲罗啉的浓度,镉溶液用量,萃取剂硝基苯的用量,反萃取盐酸的酸度,并制备碘的标准曲线,其线性相关系数R2≥0．9942,线性范围0～10ng／mL,精密度为8．5％,检出限0．80ng／mL,利用标准曲线测出水样中碘的浓度为17．78ng／mL,结果令人满意。实验表明,开发原子荧光光谱间接分析方法,使其能够准确测量更多种类的元素,有着十分积极的意义,同时也能够促进该方法得到更广范的应用。     

黔北务-正-道地区铝土矿镓含量特征与赋存状态初探

黔北务(务川)-正(正安)-道(道真)地区铝土矿是贵州铝土矿重要组成部分,对该区瓦厂坪、通塘底和高梁窝3个代表性铝土矿床的镓(Ga)及其一些主要和微量元素进行了分析,结合电子探针研究,初步探讨了ca在本区铝土矿中的赋存状态.结果表明:本区铝土矿及含矿岩系中的铝土质页岩中的Ga含量高,分别为56.1×10-6～131×10-6(平均91.0×10-6)和25.1×10-6～47.6×10-6(平均36.8×10-6),均达到铝土矿中Ga的综合利用指标(20×10-6),具有很高的综合利用价值;铝土矿中的Ga除可能以Al类质同象形式相对富集于Al矿物(主要为-水铝石)外,还有可能在金红石和锆石等重矿物中富集.