海洋表层沉积物中金属镉的来源解析

利用2015年8月份对长江口及其邻近海域表层沉积物的监测数据,基于主成分分析/绝对主成分分数(PCA/APCS)受体模型定量解析了重金属元素镉(Cd)的可能来源,并结合地统计学插值了Cd的源贡献量的空间分布状况,结果表明沉积物中镉污染主要存在3个可能来源,源头及贡献率分别为工业污染(18.8%)、陆地径流输入(66.0%)、生物活动等自然因素(13.6%),并且各个源头贡献量具有不同的空间分布状况,其中工业污染的高值区主要集中在靠近陆地区域,陆地径流输入的分布呈现由近岸向外海逐减降低的特征,生物活动等自然因素的高值区主要集中在远离陆地的外海区域。     

目标触底瞬态地震波信号的检测

目标触底过程中通常会产生强烈的瞬态地震波信号,通过对此类地震波信号的监测、处理和分析,能够帮助判断该信号的产生是否是由异常活动产生的,并且能够根据信号分析相关信息,实现早期预警, 从而做出快速响应。 由于双谱检测具有很好的抗高斯干扰能力,对高斯平稳随机过程和试验模拟目标触底瞬态地震波信号的双谱特性进行了分析,并在高斯背景中对试验采集的瞬态信号进行了检测仿真,仿真试验结果表明:在高斯背景的干扰下,双谱检测能够有效实现对瞬态信号的检测^[1] 。     

江苏海岸中部近岸冬季潮汐和潮流特征

南黄海西侧的江苏海岸近岸区域,素以地形复杂、潮流强劲、悬沙输运剧烈著称,但是较长期的同步潮位和潮流观测数据仍然缺乏,尤其是在近岸(20 km)浅水(20 m)区域。2014年1月在大丰港附近开展了连续潮位和潮流观测,获得的数据揭示了一系列特征。此地潮汐潮流为正规半日潮,浅水分潮显著。平均潮差为3.05 m,最显著的两个分潮为M2和S2分潮,振幅分别为1.45 m和0.52 m。潮流最显著的半日分潮M2分潮和最显著的浅水分潮M4分潮在沿岸方向上振幅分别为0.84m/s和0.12m/s,在跨岸方向上振幅分别为0.24 m/s和0.01 m/s,沿岸方向占绝对优势。潮波的沿岸传播介于前进波和驻波之间,驻波的特征稍强。M2分潮潮流椭圆最大流(长轴)方向为南偏东7.4°。存在冬季沿岸向北的余流,垂向平均值的大小为2.2 cm/s。以上潮汐潮流特征为该区域海洋物质输运研究提供了基础资料。     

冷泉系统甲烷气体渗漏的声学特征及潜在环境效应

The amount of methane leaked from deep sea cold seeps is enormous and potentially affects the global warming,ocean acidification and global carbon cycle. It is of great significance to study the methane bubble movement and dissolution process in the water column and its output to the atmosphere. Methane bubbles produce strong acoustic impedance in water bodies, and bubble strings released from deep sea cold seeps are called "gas flares"which expressed as flame-like strong backscatter in the water column. We characterized the morphology and movement of methane bubbles released into the water using multibeam water column data at two cold seeps. The result shows that methane at site I reached 920 m water depth without passing through the top of the gas hydrate stability zone(GHSZ, 850 m), while methane bubbles at site II passed through the top of the GHSZ(597 m) and entered the non-GHSZ(above 550 m). By applying two methods on the multibeam data, the bubble rising velocity in the water column at sites I and II were estimated to be 9.6 cm/s and 24 cm/s, respectively. Bubble velocity is positively associated with water depth which is inferred to be resulted from decrease of bubble size during methane ascending in the water. Combined with numerical simulation, we concluded that formation of gas hydrate shells plays an important role in helping methane bubbles entering the upper water bodies, while other factors, including water depth, bubble velocity, initial kinetic energy and bubble size, also influence the bubble residence time in the water and the possibility of methane entering the atmosphere. We estimate that methane gas flux at these two sites is 0.4×10~6–87.6×10~6 mol/a which is extremely small compared to the total amount of methane in the ocean body, however, methane leakage might exert significant impact on the ocean acidification considering the widespread distributed cold seeps. In addition, although methane entering the atmosphere is not observed, further research is still needed to understand its potential impact on increasing methane concentration in the surface seawater and gas-water interface methane exchange rate, which consequently increase the greenhouse effect.     

中尺度暖涡对热带气旋强度变化的影响及作用机制

基于两组理想化数值试验,对比研究了分布于热带气旋不同位置处的海洋中尺度暖涡所引发的热带气旋强度变化的时空特征。研究发现,热带气旋中心附近的暖涡对热带气旋强度有增强作用,而位于热带气旋外围的暖涡则会抑制热带气旋的发展。本研究将暖涡增强（减弱）热带气旋强度的区域称为内（外）区。随着时间的推移,内（外）区暖涡对热带气旋强度的增强（减弱）幅度逐渐减小（增大）,区域范围同步减小（增大）。内区暖涡增强了热带气旋的次级环流和结构对称性、增加了海气界面热通量,同时减弱了外围螺旋雨带,进而导致热带气旋强度增强;若暖涡在外区,其对热带气旋的作用相反,导致热带气旋强度减弱。由于理想化试验中热带气旋静止不动,因此研究结果可能只适用于传播速度较慢的热带气旋。本研究结果有助于更好地理解热带气旋和海洋中尺度暖涡之间的相互作用,并通过引入热带气旋外区暖涡的影响助力提高热带气旋强度预报工作。     

基于SPE与SPATT的水体中麻痹性贝类毒素检测方法构建与应用

为实现麻痹性贝类毒素(paralytic shellfish poisoning,PSP)的实时监控与提前预警,本研究构建了基于固相萃取技术(solid phase extraction,SPE)与固相吸附毒素跟踪技术(solid phase adsorption toxin tracking,SPATT)的水体中PSP检测方法,重点优化了吸附材料及前处理方法,评价了回收率、检出限等指标,并将方法应用于2019年春季秦皇岛山海关海域PSP消长过程的监测中,比较评估了两种方法的监控预警效果。结果表明:SPE方法选用ENVI-Carb 500mg/6mL固相萃取柱,过样体积为50mL,13种PSP组分的平均回收率为82.2%±10.0%、检出限为4.0-20.0ng/L;SPATT方法选用SP207大孔吸附树脂,洗脱时间为静置Id最佳,整体回收率约为9.2%;在实际应用中,结合产毒藻密度及贻贝富集毒素含量的变化,发现SPE方法的检测结果可实时表征海域PSP风险状况,对于贻贝中PSP的预警效果也显著优于SAPTT方法,后者不仅因监控方式相对滞后一个监测周期,且灵敏度及准确性均较差。对于秦皇岛海域,当SPE方法检测结果达到100ng STX eq/L时,该海域贻贝中PSP残留将具有潜在的食用安全风险,跟踪过程表明这一阈值可提前两周预警贻贝富集毒素含量超出我国限量标准(800μg STX eq/kg),这对于强化风险警示并制定防范措施具有积极作用。     

钦州湾海洋环境的富营养化水平评价及其对浮游植物叶绿素a的影响

文章通过钦州湾现场调查资料,分别利用单因子污染指数法和富营养化指数法对湾内水质的污染状况和富营养化水平进行评价,并分析讨论不同的富营养化水平条件下浮游植物叶绿素a的响应。结果显示,钦州湾的污染状况和富营养化程度从湾顶至湾外呈现由重至轻的梯度变化,并出现两个“极端区域”：茅尾海化学需氧量（COD）和营养盐的污染指数劣于三类海水水质标准并重度富营养化;外湾污染指数符合一类海水水质标准并贫营养化。分析表明,茅尾海的重度富营养化是由河流输入、相对封闭的地形以及过度的牡蛎养殖造成,而外湾的贫营养化则主要归因于较少的水产养殖和陆源污水排放以及大量的浮游植物对磷酸盐的消耗。叶绿素a在这两个区域均呈现低值,茅尾海内主要是由于贝类滤食大粒径浮游植物和真光层深度下降引起,而外湾则是氮磷比（N/P）失衡,浮游植物生长受磷限制导致。另外,核电站温排水有可能是导致叶绿素a较高的原因。减少茅尾海内的养殖规模,种植红树林,集中污水于外湾排放,加强温排水口的水质监控是保证钦州湾海洋生态环境可持续发展的手段。     

Automatic Sounding Generalization in Nautical Chart Considering Bathymetry Complexity Variations

Sounding acts as the main feature in a digital nautical chart as it describes the concerned marine topography for the safety of navigation. Unlike the geometry-oriented selection of point feature, the generalization of soundings for chart compiling is expected to be context-oriented, which means bathymetry complexity variations across the study region should be preserved in the sounding selection process. However, such variations are not explicitly accessible to automated systems. This paper proposes an approach that effectively analyzes and measures bathymetry complexity from sounding data, with a focus on topography variations among different regions. The presented approach first divides the exploring region into several subregions, by adopting techniques of computational geometry and graph theory. Then, the approach quantitatively measures the bathymetry complexity of the subregions from grid-based digital terrain model. Finally, a composite bathymetry complexity index integrating aspects of steepness and depth variation is developed to guide the operation of sounding selection in different subregions. Generally, when seafloor is rugged with steep slopes, the number of soundings is high. While in flatter areas, a smaller amount of soundings is retained. The potential of our approach is demonstrated by an application to a real data set.     

底栖有孔虫(Florilus decors)壳体微量元素/钙比值的LA-ICP-MS原位微区分析方法及应用——以长江口外海域为例

深海沉积物中有孔虫壳体的微量元素、同位素测试技术已较为成熟,而河口近海沉积物中有孔虫壳体元素微区测试却鲜有报道。本文报道了一种利用激光剥蚀电感耦合等离子体质谱（LA-ICP-MS）分析法测试取自长江口外沉积物中的有孔虫壳体元素/钙比值的技术,研究了氦气载气流量、能量密度、束斑大小、激光剥蚀频率等参数对测试结果的影响,优化了活体有孔虫原位分析方法。应用确定的测试条件对2016年7月取自长江口外的底栖有孔虫优美花朵虫样品（Florilus decors）进行测试,发现Mg、Sr等元素/钙比值在壳体不同位置上无显著差异,而Mn的数据较为离散,可能与有孔虫生长过程中经历的水环境及其变化有关。