On the precision and accuracy of IGS orbits

In order to explore the precision and accuracy of International GNSS Service (IGS) orbits, we difference geocentric satellite positions midway between successive daily Final orbits for the period starting 5 November 2006, when the IGS switched its method of antenna calibration, through 31 December 2007. This yields a time series of orbit repeatabilities analogous to the classical geodetic test for position determinations. If we compare our average positional discontinuities to the official IGS accuracy codes, root-sum-squared (RSS) for each pair of days, we find the discontinuities are not well correlated with the predicted performance values. If instead the IGS weighted root-mean-square (WRMS) values from the Final combination long-arc analyses are taken as the measure of IGS accuracy, we find the position differences and long-arc values are correlated, but the long-arc values are exaggerated, particularly around eclipses, despite the fact that our day-boundary position differences apply to a single epoch each day and the long-arc analyses consider variations over a week. Our method is not well suited to probe the extent to which systematic effects dominate over random orbit errors, as indicated by satellite laser ranging residuals, but eclipsing satellites often display the most problematic behavior. A better metric than the current IGS orbit accuracy codes would probably be one based on the orbit discontinuities between successive days.     

Adsorption of cobalt by using inorganic components of sediment samples from water bodies

The adsorption of cobalt ions was evaluated using sediment samples from water bodies to investigate the adsorption properties of sediment and the behavior of these natural materials in the presence of nuclear and industrial waste.The two sediments(S1 and S2)were treated to eliminate humic and fulvic acids and then they were characterized by several techniques.The minerals found in both the sediments(X-ray diffraction)were quartz and albite;plus,goethite and muscovite in S1,and kaolinite and montmorillonite in S2.Point of zero charge(PZC)of S1 and S2 was 6.00 and 5.22,respectively.The specific area of S1(63.3 m²/g)is higher than S2(1.5 m²/g).Adsorption kinetics data for S1 and S2 were best fitted to the pseudo second-order model.The removal efficiency of S1 for cobalt was 96%with an adsorption capacity(qe)of 0.93 mg/g,and for S2 was 45%with a qeof 0.40 mg/g.The experimental data of the adsorption isotherms were adjusted to Langmuir and Freundlich models for S1 and S2,respectively.The thermodynamic parameters(enthalpy,entropy,and Gibb’s free energy)indicated that the adsorption processes were endothermic,spontaneous,and chemisorption mechanism.The results show that the adsorption capacities of the sediments depend on their composition.These water sediments have important adsorption properties for cobalt,and they can be used in the treatment of nuclear and industrial aqueous wastes.     

Groundwater-level response to land-use change and the implications for salinity management in the West Moorabool River catchment, Victoria, Australia

The connection between the removal of native vegetation, rising water tables and increasing stream salinity has been established for many catchments across Australia. However, the West Moorabool River in south west Victoria is an example of a catchment where there has been little discernable effect on groundwater levels following land clearing. Over the past 150 years, a significant portion of the catchment has been cleared of dense forest for agricultural development. Historic standing water-level records from 1870–1871 and 1881 are compared with contemporary measurements (1970s to 2007) recorded in the government bore databases. The data show that the earliest recorded groundwater levels are well within the seasonal range of values observed today. By integrating geology and hydrogeology with historical observations of groundwater levels, climate data and land use, the contemporary field observations of stream salinity are linked to the changed water use and shift in rainfall. In contrast to the normally accepted axiom, reafforestation as a management strategy to mitigate the rising salinity in the West Moorabool River catchment would seem inappropriate.     

Silurian and Devonian systems

The Ediacara mineral field is situated 30 km W of Beltana on the western margins of the Flinders Ranges, South Australia, and consists of silver‐lead and copper deposits in lower Cambrian carbonate rocks that contain anomalous base‐metal contents throughout the Adelaide Geosyncline. The lower Cambrian rocks, which consist of the basal Parachilna Formation and overlying Ajax Limestone, rest disconformably on the Precambrian, and at Ediacara occupy a shallow N‐S elongate syncline near the hinge zone of the Adelaide Geosyncline. The main primary ore minerals of the silver‐lead mineralization are galena and pyrite, with very minor chalcopyrite and sphalerite, and rare tetrahedrite and pearceite. The gangue consists mainly of silica (both chalcedony and quartz), with minor dolomite and rare barite. The mineralization is stratabound and occurs in conformable zones, the lowest of which commences about 30–50 m above the base of the Cambrian sequence. The host to the silver‐lead mineralization, the Ajax Limestone, can be subdivided into three units which represent a set of lithologies, structures and organic traces indicative of a shallow near‐shore carbonate environment. The silver‐lead mineralization is mainly present in sandy and laminated dolomites which were deposited in an environment ranging from sub‐tidal to bar and channel and tidal flat, respectively. Four types of mineralization have been recognized; disseminated sulphides of syngenetic and/or diagenetic origin and epigenetic concentrations along stylolites, in veins and as breccia fillings. Post‐depositional solution activity has affected a large proportion of the carbonate sequence. The effects of this activity range from stylolites through stylobreccias to solution collapse breccias. The epigenetic concentrations of mineralizations have apparently been formed by the remobilization of the disseminated sulphides during solution activity. The ore and gangue minerals of the epigenetic mineralization display both euhedral forms and distinct colloform banding, and framboidal textures have also been observed in both pyrite and galena. There is evidence of repeated episodic precipitation and no simple paragenetic sequence can be recognized. Fluid inclusions in silica and dolomite associated with the epigenetic mineralization have homogenization temperatures of 159 to 199°C and freezing temperatures that indicate the fluids to be saline brines containing NaCl with CaCl₂ and/or MgCl₂. Sulphur isotope analyses show a range of 8³⁴S values from ‐12.5 to +8.6 per mil, with no evidence of significant differences between the four types of mineralization. The data suggest deposition of the disseminated sulphides as a result of biological reduction of seawater sulphate in a system partially open with respect to sulphate supply. Subsequent remobilization of sulphides apparently involved little or no sulphur isotope fractionation. The Ediacara silver‐lead deposits have many features in common with Mississippi Valley‐type lead‐zinc deposits and appear to have similarities in terms of genesis, in that the epigenetic mineralization has been formed as a result of post‐depositional solution activity during diagenesis in a sedimentary basin. The scale of transport of the metals deposited as the epigenetic mineralization at Ediacara appears, however, to have been very much less than that of the metals in other Mississippi Valley‐type deposits.     

The last deglaciation in the Picos de Europa National Park (Cantabrian Mountains,northern Spain)

A sedimentological and geochemical study of the Lago Enol sequence (Cantabrian Mountains, northern Spain), together with detailed geomorphological mapping, provides a first record of glacier evolution and climate change over the last 40 ka in the Picos de Europa National Park. The Enol glacier retreated from its maximum extent prior to 40 ka BP as demonstrated by the onset of proglacial lacustrine sedimentation in two glaciated depressions: the Comella hollow to the north (before 40 ka BP) and the Lago Enol (before 38 ka BP). These results support previous evidence that the maximum extent of southern European glaciers occurred earlier than in northern Europe. Alternation of homogeneous and laminated proglacial sediments during the glacier retreat illustrate a dynamic glacial evolution during the Marine Isotope Stage (MIS) 3 (40–26 ka BP). A slight warming is detected at 26 ka ago with the change from proglacial sediments (in a lake located in contact to the glacier) to glaciolacustrine sedimentation (in a non‐contact or distal lake). Finally, the onset of organic‐rich sediments took place at 18 ka ago. This last transition occurred in two phases, similarly to the North Atlantic Last Termination, suggesting a link between North Atlantic Deep Water formation oscillations and palaeohydrological variability in the Cantabrian Mountains. Copyright © 2009 John Wiley & Sons, Ltd.     

Seismic activity related to the 1991 eruption of Colima Volcano,Mexico

Ten years after the last effusive eruption and at least 15 years of seismic quiescence, volcanic seismic activity started at Colima volcano on 14 February 1991, with a seismic crisis which reached counts of more than 100 per day and showed a diversity of earthquake types. Four other distinct seismic crises followed, before a mild effusive eruption in April 1991. The second crisis preceded the extrusion of an andesitic scoriaceous lava lobe, first reported on 1 March; during this crisis an interesting temporary concentration of seismic foci below the crater was observed shortly before the extrusion was detected. The third crisis was constituted by shallow seismicity, featuring possible mild degassing explosion-induced activity in the form of hiccups (episodes of simple wavelets that repeat with diminishing amplitude), and accompanied by increased fumarolic activity. The growth of the new lava dome was accompanied by changing seismicity. On 16 April during the fifth crisis which consisted of some relatively large, shallow, volcanic earthquakes and numerous avalanches of older dome material, part of the newly extruded dome, which had grown towards the edge of the old dome, collapsed, producing the largest avalanches and ash flows. Afterwards, block lava began to flow slowly along the SW flank of the volcano, generating frequent small incandescent avalanches. The seismicity associated with the stages of this eruptive activity shows some interesting features: most earthquake foci were located north of the summit, some of them relatively deep (7–11 km below the summit level), underneath the saddle between the Colima and the older Nevado volcanoes. An apparently seismic quiet region appears between 4 and 7 km below the summit level. In June, harmonic tremors were detected for the first time, but no changes in the eruptive activity could be correlated with them. After June, the seismicity decreasing trend was established, and the effusive activity stopped on September 1991.     

A cautionary note on humanitarian intervention

In the Post-Cold War environment, the role of the military has been extended to include intra-state peace enforcement on humanitarian grounds. This raises issues of legality. In this paper, four arguments are advanced that a right of states to intervene in humanitarian emergencies now exists. Problems contingent upon such intervention are then examined.     

Thermal radiation from cloudless skies in Granada

Summary Data on thermal radiation from clear skies obtained at Granada from May to November 1983 were utilized to carry out a detailed comparison between measured and calculated values of longwave radiation with several analytical and empirical equations. The goal of this work is to check the aplicability of these equations to Granada conditions. The results obtained for all the equations are quite satisfactory. Nevertheless, Idso's formula significantly overestimates our experimental results, probably as a consequence of the differences in atmospheric dust conditions between our test area and the location for which that equation was originally derived. A reduction in the independent coefficient, in accordance with previous results of other authors, provides a better fit to our data set and clearly shows the climatological dependence of the constants in the estimation equations.

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Zusammenfassung Die von Mai bis November 1983 in Granada gesammelten Daten über Wärmestrahlung bei klarem Himmel wurden dazu verwendet, um einen detaillierten Vergleich zwischen gemessenen und errechneten Werten der langwelligen Strahlung aus verschiedenen analytischen und empirischen Gleichungen durchzuführen. Das Ziel dieser Arbeit ist es, die Anwendbarkeit dieser Gleichungen auf die Verhältnisse in Granada zu überprüfen. Die gewonnenen Ergebnisse sind für alle diese Gleichungen ganz zufriedenstellend. Idsos Formel überschätzt jedoch deutlich unsere experimentellen Ergebnisse, möglicherweise als Folge der unterschiedlichen atmosphärischen Staubbedingungen in unserem Testgebiet und dem Standort, für den die Gleichung ursprünglich abgeleitet wurde. Eine Reduktion des unabhängigen Koeffizienten, in Übereinstimmung mit früheren Ergebnissen anderer Autoren, bietet eine bessere Anpassung an unseren Datensatz und zeigt deutlich die klimatologische Abhängigkeit der Konstanten in Schätzungsgleichungen.

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With 3 Figures