Distribution, characterization, and geochemical controls of elements of concern in uranium mine tailings, Key Lake, Saskatchewan, Canada

The distribution of As, Mo, Ni and Se in the aqueous and solid phases of U mine tailings in the Deilmann Tailings Management Facility (DTMF), located at the Key Lake mine in northern Saskatchewan, Canada, was defined using as-discharged tailings samples collected monthly starting in 1996 and core samples collected from the DTMF from 3 locations on 3 occasions between 2004 and 2009. These data indicated that the DTMF can be divided into two geochemical zones; tailings generated from the Deilmann ore body between 1996 and 2000 and tailings from the McArthur River ore body, mined after July 2000. The Deilmann tailings solids are generally characterized by greater elemental concentrations than those in the McArthur River tailings, particularly for As, Co and Ni. These elevated concentrations are attributed to the abundance of Ni–Co–As–S minerals in this ore. The mean aqueous concentrations of As, Mo, Ni, and Se are 3.7, 23.2, 0.14, and 0.02 mg L⁻¹, respectively, in the Deilmann porewaters and 0.20, 4.16, 0.06, and 0.03 mg L⁻¹, respectively, in the McArthur River porewaters. Similarly, the mean As, Mo, Ni, and Se solid phase concentrations are 5.89 × 10³, 69.9, 3.20 × 10³, and 17.4 μg g⁻¹, respectively, for the Deilmann tailings and 440, 13.6, 551, and 3.03 μg g⁻¹ in the McArthur River tailings. Statistically, pH remained unchanged from the time of discharge while Eh values have remained oxic with no significant change between the two tailings types over 15 a of residence time. Results from sequential extractions, thermodynamic modeling, and results of complimentary research indicated that ferrihydrite solubility is the dominant control on aqueous As concentrations and also plays a role in controlling dissolved Mo, Ni and Se.     

A geologic study of the Juan del Grijalva landslide,the most important mass movement during the last century in Mexico

On November 4th 2007, along the Grijalva River in the state of Chiapas, Mexico, has occurred one of the largest landslides ever known. This landslide, known as Juan del Grijalva, destroyed the town of the same name, killing 20 people, and moved 55 million cubic meters of rock and debris down slope to completely block the Grijalva River. In order to understand the characteristics and factors that triggered the Juan del Grijalva landslide, geologic studies were conducted at the site. The results indicate that the landslide was composed of a lithologic sequence of thin-bedded shales and thin to medium-thick-bedded sandstones. This was faulted into several blocks dipping in the same sense as the mass movement. The main triggering factor was the increment of the pore pressure into the lithologic unit due to water saturation after 5 days of heavy rain before the incident. According to records from the last century, the Juan del Grijalva mass movement represents one of the largest mass movements recorded all over the world. The risk conditions of the area after the landslide lead to the rapid construction of an artificial channel to drain the accumulating mass of water upstream and therefore prevent a future catastrophic inundation down stream.     

Geochemical processes in a Mediterranean Lake: a high-resolution study of the last 4,000 years in Zoñar Lake,southern Spain

High-resolution geochemical analysis of a 6-m-long sediment core from Zoñar Lake, southern Spain, provides a detailed characterization of major changes in lake and watershed processes during the last 4,000 years. Geochemical variables were used as paleolimnological indicators and complement Zoñar Lakes’s paleoenvironmental reconstruction based on sedimentological and biological proxies, which define periods of increasing allochthonous input to the lake and periods of dominant autochthonous sedimentation. Chemical ratios identify periods of endogenic carbonate formation (higher Ca/Al, Sr/Al and Ba/Al ratios), evaporite precipitation (higher S/Al, Sr/Al ratios), and anoxic conditions (higher Mo/Al, U/Th ratios and Eu anomaly). Higher productivity is marked by elevated organic carbon content and carbonate precipitation (Mg/Ca). Hydrological reconstruction for Zoñar Lake was based on sedimentological, mineralogical and biological proxies, and shows that lower lake levels are characterized by Sr-rich sediments (a brackish lake with aragonite) and S-rich sediments (a saline lake with gypsum), while higher lake levels are characterized by sediments enriched in elements associated with alumino-silicates (Al, K, Ti, Fe, trace and rare earth elements), reflecting fresher conditions. Geochemical indicators also mark periods of higher detrital input to the lake related to human activity in the watershed: (1) during the Iberian Roman Humid Period (650 BC–AD 300), around the onset of the Little Ice Age (AD 1400), during the relatively drier Post-Roman and Middle Ages (AD 800–1400), and over the last 50 years, due to mechanized farming practices. Heavy metal enrichment in the sediments (Cu and Ni) suggests intensification of human activities during the Iberian Roman Period, and the use of fertilizers during the last 50 years.     

Three‐dimensional gravity‐current flow within a subaqueous bend: Spatial evolution and force balance variations

The nature of three‐dimensional flow in submarine channel bends is poorly understood, largely due to the absence of detailed data from natural channels. Herein, data from density‐driven flows in a large reservoir on the Huanghe (Yellow) River are presented showing the spatio‐temporal variation of flow around a subaqueous bend. The data demonstrate for the first time that reversed helical flow, relative to that found in river channel bends, can occur from the centrifugal forcing of flow, even when the Coriolis force acts in the opposite direction. The data also suggest that reversed helical flow fields in submarine channels may be more frequent than currently estimated, notably for bends where Coriolis and centrifugal forces combine in the same direction. In addition, this study provides the first field evidence suggesting that sinuous submarine channels can exhibit an asymmetry in helical flow orientation between left and right‐turning bends, which will have major implications for the morphodynamics of submarine channels, their resultant patterns of sedimentation and, ultimately, the distribution of depositional units across submarine fan systems.     

Book reviews

APPLIED GEOGRAPHY: Issues, Questions and Concerns (Geo Journal Library Vol. 15) edited by M. S. Kenzer. 16 × 24 cm, x and 210 pages. Kluwer: Dordrecht 1989 (ISBN 0 7923 04381).

WINE AND THE VINE: An Historical Geography of Viticulture and the Wine Trade by T. Unwin. 16 × 24 cm, xvi and 409 pages. Routledge: London 1991 (ISBN 0 415 13120 6) $A155.00 (hard); distributed by The Law Book Co.

WATERFRONT SYDNEY 1860–1920 by G. Aplin and J. Storey. 26 × 18 cm. 144 pages. Allen & Unwin: Sydney 1991 (first published 1984) (ISBN 1 86373 098 2) $A24.95 (soft).

Australian Geographer 23 (2), November 1992

INDUSTRIAL LOCATION: Principles and Policies (Second Edition) by K. Chapman and D. F. Walker. 15 × 23 cm, xiii and 322 pages. Basil Black‐well: Oxford 1991 (ISBN 0 631 16789 7) $A39.95 (soft).

INTERNATIONALISATION OF AUSTRALIA'S SERVICE INDUSTRIES by J. V. Langdale. 17 × 25 cm, iv and 373 pages. Australian Government Publishing Service, for Department of Industry, Technology and Commerce: Canberra 1991 (ISBN 0 644 13841 6).

TOURISM AND GOLD IN KAKADU: The Impact of Current and Potential Natural Resource Use on the Northern Territory Economy by B. Knapman, O. Stanley and J. Lea. 21 × 29 cm, vi and 49 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1179 4).

ABORIGINAL AUSTRALIA AND THE ‘NEW FEDERALISM’ INITIATIVE (Discussion Paper No. 2) by G. J. Crough. 14 × 21 cm, 42 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1325 8).

AUSTRALIAN NATIONHOOD AND OUTBACK INDIGENOUS PEOPLES (Discussion Paper No. 1) by P. Jull. 14 × 21 cm, 38 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1309 6).

MIGRATION AND DEVELOPMENT IN THE SOUTH PACIFIC (Pacific Research Monograph No. 24) edited by J. Connell. 17 × 25 cm, xii and 199 pages. National Centre for Development Studies, Australian National University: Canberra 1990 (ISBN 0 07315 0668 5) $A25.00 (soft).

POPIULESIN BLONG HONIARA: Olketa Popiulesin Map Blong 1986 Sensis. HONIARA: 1986 Census Atlas (Statistics Office Occasional Paper No. 4 / Board of Development Studies Monograph No. 1) by A.C. Walsh. 21 × 29 cm, vii and 95 pages. Department of Statistics: Honiara and Board of Development Studies, Massey University: Palmerston North 1990 (ISSN 0114 8834) $NZ34.00 in New Zealand, $NZ38.00 elsewhere (soft).

DOI MOI: Vietnam's Renovation Policy and Performance (Political and Social Change Monograph No. 14) edited by D. K. Forbes, T. H. Hull, D. G. Marr and B. Brogan. 15 × 22 cm, xiv and 263 pages. Department of Political and Social Change, Australian National University: Canberra 1991 (ISBN 0 7315 1303 7).     

An empirical model of event scale cohesive bank profile evolution

The highly stochastic nature of riverbank erosion has driven the need for spatially explicit empirical models. Detailed bank profile surveys along a meander bend of the Brandywine Creek in Pennsylvania, USA, before and after 28 high flow events over a 2·5 year period are used to develop an empirical model of cohesive bank profile erosion. Two hundred and thirty‐six bank erosion observations are classified as hydraulic erosion or subaerial erosion. Threshold conditions required to initiate bank erosion cannot be defined based on field measurements. Using the near‐bank velocity and the number of freeze–thaw cycles as predictors, regression equations are derived for hydraulic erosion that specify the length, thickness, and location on the bank face of eroded blocks. An empirical discriminant function defines the critical geometry of overhang failures, and the volumes removed by overhang failures are computed using another regression equation. All the regression equations are significant, but have low correlation coefficients, suggesting that cohesive bank erosion has a strong stochastic component. Individual events typically remove small masses of soil (average volume 0·084 m³/m) a few centimeters thick (median = 0·057 m) and a few decimeters in length (median = 0·50 m) from the lower third of the bank. Hydraulic erosion is responsible for 87% of all erosion. When applied to three survey sites not used in its development, the profile model predicts the total volume of erosion with errors of 23%, 5% and 1%. Twenty‐four percent of computed erosion volumes for single events are within 50% of observed volumes at these three sites. Extending the approach to decadal timescales and to entire bends will require three‐dimensional observations of bank failure, and spatially and temporally explicit methods to account for the influence of individual large trees on bank failures and near‐bank hydraulic processes. Copyright © 2009 John Wiley & Sons, Ltd.     

Analysis of tracer tomography using temporal moments of tracer breakthrough curves

Hydraulic/partitioning tracer tomography (HPTT) was recently developed by Yeh and Zhu [Yeh T-CJ, Zhu J. Hydraulic/partitioning tracer tomography for characterization of dense nonaqueous phase liquid source zones, Water Resour Res 2007;43:W06435. doi:10.1029/2006WR004877.] for estimating spatial distribution of dense nonaqueous phase liquids (DNAPLs) in the subsurface. Since discrete tracer concentration data are directly utilized for the estimation of DNAPLs, this approach solves the hyperbolic convection–dispersion equation. Solution to the convection–dispersion equation however demands fine temporal and spatial discretization, resulting in high computational cost for an HPTT analysis. In this work, we use temporal moments of tracer breakthrough curves instead of discrete concentration data to estimate DNAPL distribution. This approach solves time independent partial differential equations of the temporal moments, and therefore avoids solving the convection–dispersion equation using a time marching scheme, resulting in a dramatic reduction of computational cost. To reduce numerical oscillations associated with convection dominated transport problems such as in inter-well tracer tests, the approach uses a finite element solver adopting the streamline upwind Petrov–Galerkin method to calculate moments and sensitivities. We test the temporal moment approach through numerical simulations. Comparing the computational costs between utilizing moments and discrete concentrations, we find that temporal moments significantly reduce the computation time. We also find that tracer moment data collected through a tomographic survey alone are able to yield reasonable estimates of hydraulic conductivity, as indicated by a correlation of 0.588 between estimated and true hydraulic conductivity fields in the synthetic case study.     

The Afragola settlement near Vesuvius,Italy: The destruction and abandonment of a Bronze Age village revealed by archaeology,volcanology and rock-magnetism

Public works in progress in the Campanian plain north of Somma-Vesuvius recently encountered the remains of a prehistoric settlement close to the town of Afragola. Rescue excavations brought to light a Bronze Age village partially destroyed and buried by pyroclastic density currents (PDCs) of the Vesuvian Pomici di Avellino eruption (3.8 ¹⁴C ka BP) and subsequently sealed by alluvial deposits. Volcanological and rock-magnetic investigations supplemented the excavations.Careful comparison between volcanological and archaeological stratigraphies led to an understanding of the timing of the damage the buildings suffered when they were struck by a series of PDCs. The first engulfed the village, located some 14 km to the north of the inferred vent, and penetrated into the dwellings without causing major damage. The buildings were able to withstand the weak dynamic pressure of the currents and deviate their path, as shown by the magnetic fabric analyses. Some later collapsed under the load of the deposits piled up by successive currents. Stepwise demagnetization of the thermal remanent magnetization (TRM) carried by potsherds embedded in the deposits yields deposition temperatures in the order of 260–320 °C, fully consistent with those derived from pottery and lithic fragments from other distal and proximal sites. The fairly uniform temperature of the deposits is here ascribed to the lack of pervasive air entrainment into the currents. This, in turn, resulted from the lack of major topographical obstacles along the flat plain.The coupling of structural damage and sedimentological analyses indicates that the currents were not destructive in the Afragola area, but TRM data indicate they were still hot enough to cause death or severe injury to humans and animals. The successful escape of the entire population is apparent from the lack of human remains and from thousands of human footprints on the surface of the deposits left by the first PDCs. People were thus able to walk barefoot across the already emplaced deposits and escape the subsequent PDCs. The rapid cooling of the deposits was probably due to both their thinness and heat dissipation due to condensation of water vapour released in the mixture by magma–water interaction.