延边地区天宝山多金属矿田的流体特征与成矿模式

天宝山铅锌铜钼多金属矿田由新兴铅-锌矿床、东风铅-锌-铜-钼矿床和立山铜-铅-锌矿床组成,它们分别产在侏罗纪黑云母花岗闪长岩、闪长岩与古生代海相火山-沉积岩的接触带和岩体内部。矿床地质特征研究表明:新兴铅-锌矿床以石英硫化物充填胶结角砾岩筒矿体为特征,具有与中温岩浆热液矿床类似的蚀变特征;东风铅-锌-铜-钼矿床以发育浸染状硫化物、石英硫化物脉和辉钼矿石英脉为特征,具有接触交代热液矿床特征;立山铜-铅-锌矿床则以磁铁矿、方铅矿和闪锌矿等多金属硫化物矿化发育为特征,具有典型的接触交代矽卡岩型矿床特征。对主成矿阶段以及成矿晚阶段的脉石矿物石英流体包裹体研究揭示:新兴铅-锌矿床的石英-黄铁矿阶段、石英-闪锌矿-方铅矿-黄铜矿多金属硫化物阶段和石英-碳酸盐阶段对应的温度分别为270～340℃、190～260℃、130～160℃;盐度(w(NaCl))和密度分别为0.62%～9.86%和0.37～1.00g/cm3;压力为37.31～87.69MPa;激光拉曼光谱分析获得流体包裹体的成分主要为CO2、H2O,含有少量的CH4和N2。东风铅-锌-铜-钼矿床的石英-辉钼矿阶段、石英-闪锌矿-方铅矿-黄铜矿多金属硫化物阶段和石英-碳酸盐阶段对应的温度分别为280～337℃、200～260℃、101～190℃;盐度和密度分别为7.16%～23.95%和0.96～1.12g/cm3;压力为28.23～56.64MPa;激光拉曼光谱分析获得流体包裹体成分为H2O。立山铜-铅-锌矿床的磁铁矿-石英脉阶段、石英-方铅矿-闪锌矿-黄铜矿等多金属硫化物和石英-碳酸盐阶段对应的温度分别为210～240℃、170～200℃、126～160℃,盐度和密度分别为2.07%～9.47%和0.89～0.92g/cm3;压力为33.88～59.72 MPa;激光拉曼光谱分析获得流体包裹体成分为CO2和CH4。基于矿床地质特征、成矿流体性质和来源等方面的讨论,建立了天宝山多金属矿田的成矿模式。     

油藏数值模拟中地质模型的建模流程与方法

围绕油藏数值模拟过程中三维地质模型的建模技术进行了分析与探讨,详细介绍了基于角点网格模型的建模方法,给出了相应的实现步骤。其主要流程是:首先根据断层数据构造断层模型,在断层模型的基础上构建骨架模型;然后在骨架模型约束下采用地层恢复技术实现含断层的地层模型;最后基于结构模型插值物性参数完成属性模型。以塔河油田缝洞型油藏为例,对建模流程和技术的可行性进行验证,结果表明,其建模结果与专业地质建模软件Petrel相符。     

蒙古国东南部巴音苏赫图晚古生代—早中生代二长花岗岩地球化学特征及其对构造环境的约束

巴音苏赫图二长花岗岩位于西伯利亚板块东南缘陆缘增生带与二连—贺根山板块对接带北缘之间。该岩体由石炭纪及三叠—侏罗纪两期花岗岩组成,均以高硅、富Al2O3、K2O、Na2O,贫MgO、CaO为特征。微量元素表现为富集LILE、亏损HFSE。弱富集LREE,Eu负异常明显。岩石学和地球化学综合研究表明:两期花岗岩早期为高钾钙碱性、准铝质-过铝质花岗岩碰撞期I型花岗岩,晚期花岗岩具有A型花岗岩特点。Sr-Nd同位素研究表明:石炭纪二长花岗岩(87Sr/86Sr)i比值较低(0.700 62～0.704 82),εNd(t)为正值(0.9～1.5),岩浆来自于增生的岛弧或年轻的幔源物质,在岩浆上升过程中遭受了少量地壳物质的混染;晚三叠世—早侏罗世花岗岩(87Sr/86Sr)i比值较高(0.709 96～0.710 19),εNd(t)较低,为-0.3～0.3,该期次花岗岩与晚石炭世花岗岩同源,受地壳混染程度相对较高。应用LA-ICP-MS法测得石炭纪花岗岩U-Pb年龄为(296±3.5)Ma,结合区域构造演化特点及所测三叠纪花岗岩的地球化学特征认为,在晚石炭世,南蒙古额尔德尼查干地区已进入碰撞期构造环境,在三叠—侏罗纪仍有同碰撞花岗岩侵入,晚石炭世以后的碰撞期持续时间较长。     

Heavy metals pollution on the sediments in lakes Dianchi, Erhai and Poyanghu and historical records

In this paper²¹⁰ Pb and ¹³⁷Cs dating methods were used to determine sedimentation rates of lakes Dianchi, Erhai and Poyanghu, and to establish the time scale of the sediments. Also based on geochemical records in the sediment column, the historical variation in heavy metal content over the past one hundred years was determined. Some element concentration increased rapidly after the 1970s, such as Cu, Zn and Mn in the sediments of northern Lake Dianchi, Cd and Mn in southern Lake Erhai and in the west central parts of Lake Poyanghu, Our investigations indicate that the increase in element concentration is caused by human activities. In order to understand the extent of the effect caused by human activities, we have calculated the flux of Zn, Cd and Mn. Results show that the flux caused by human activities is seven times greater than the natural one and the ratio is about 2 times in Lake Erhai and Lake Poyanghu.     

Mineral and fluid inclusions in zircon of UHP metamorphic rocks from the CCSD-main drill hole: A record of metamorphism and fluid activity

The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.

Abundant H₂O–CO₂, H₂O- or CO₂-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H₂O- and/or CO₂-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation.     

The Taihua group on the southern margin of the North China craton: further insights from U–Pb ages and Hf isotope compositions of zircons

The "Taihua Group" is a collective term for a series of old terranes scattered along the southern margin of the North China Craton. The timing of formation and thermal overprinting of the Taihua Group have long been contentious, and its relationship with the Qinling orogenic belt has been unclear. In this study, new data from integrated in-situ U–Pb dating and Hf isotope analysis of zircons from an amphibolite (from the Xiong’ershan terrane) and a biotite gneiss (from the Lantian-Xiaoqinling terrane) indicate that the Upper Taihua Group formed during the Paleoproterozoic (2.3–2.5 Ga) and thus was originally part of the southern edge of North China Craton, detached during the Mesozoic Qinling orogeny and displaced about 100 km north from its original location. This suggests that the Taihua Group became part of the tectonic terrane associated with the Qinling orogeny and now forms part of the overthrust basement section of the Qinling belt. Before the Qinling orogeny, the Taihua Group was metamorphosed at 2.1 Ga. The initial Hf-isotope compositions of zircons, together with positive εNd(t) values for the whole-rocks, imply that the original magmas were derived from a juvenile source with some assimilation of an Archean crustal component.     

华北晚古生代煤中有机硫的赋存状态及其成因

为揭示煤中有机硫的赋存状态及其地质成因,采用电子探针微区分析和硫同位素分析技术对华北地区山西大同、太原西山、霍州以及安徽淮南４个矿区的８个层晚古生代的煤层进行了研究,海水的作用对有机硫的聚集起着十分重要的影响。煤的不同显微组分中有机硫的质量分数存在明显差异,镜质组中有机硫的质量分数高于其在惰质组的质量分数。硫在煤中的聚集是一个逐渐累积的过程,有机硫的聚集一般滞后于黄铁矿硫的聚集。泥炭沼泽条件控制着     

吉林集安铅锌矿地球化学与分散元素

吉林集安铅锌矿床是我国最早报导的少数几个典型低温铅锌矿床之一。矿化具有多期次特点 ,富矿体都是多期次矿化叠加的产物。根据矿化先后和矿物生成顺序将矿化分为五个阶段 :①石英 黄铁矿矿化阶段 ;②重晶石 闪锌矿矿化阶段 ;③石英 方铅矿矿化阶段 ;④石英 黄铁矿矿化阶段 ;⑤碳酸盐 氧化矿物矿化阶段。用均一法和爆裂法测得石英、重晶石、闪锌矿包裹体成矿温度变化在 1 1 0℃～ 1 97℃之间。矿床中除含铅锌矿外 ,还有微量的Pt和Pd,并普遍含分散元素Cd、Ga、Tl、In、Se、Ge、Te,其中以Cd含量最高 ,闪锌矿中Cd含量最高可达 71 5 5× 1 0 6。分散元素主要呈类质同象形式赋存在各种矿物之中 ,未发现独立矿物。通过矿床地质和硫铅同位素研究表明该铅锌矿床属低温沉积 改造型层控矿床。     

柴达木盆地东台吉乃尔盐湖盐类沉积特征及成盐年代的初步研究

东台吉乃尔盐湖经过长期的成盐演化和成矿过程 ,最终形成了以氯化钠化学沉积为主的蒸发盐 ,晶间卤水富含B、Li等多种元素卤水矿床 ,根据 1998年对该湖干盐滩中部所打的CK1孔钻孔剖面( 12m)及测试的几个14 C年龄 ,初步证实该盐湖上部盐层是在约 10 0 0 0aBP形成 ,未经碳酸盐和硫酸盐成盐阶段 ,盐湖形成初期即进入氯化物成盐阶段。