The composition and concentration of dissolved free amino acid (DFAA) of seawater samples collected in May 2016 from the surface to the hadal zone of the northern region of the Yap Trench were analyzed by pre-column derivatization of o-phthalaldehyde. Results show that the average concentration of DFAA in the study area was 0.47±0.36 µmol/L. In different sampling stations, the concentrations of DFAA with water depth showed complex variation patterns. At the sediment-seawater interface, the concentrations of DFAA in the western side of the trench were obviously higher than that in its eastern side. In the study area, there were no significant correlations between the concentrations of DFAA and the environmental parameters such as concentrations of chlorophyll a (Chl a), dissolved oxygen (DO), pH, and dissolved inorganic nitrogen (DIN), indicating that the concentrations of DFAA in seawater of the trench are affected by many factors, such as photosynthesis, respiration, temperature, pressure, illumination, and circulation. The dominant DFAA are similar in different water layers of sampling stations, including aspartic acid (Asp), glutamic acid (Glu), glycine (Gly), and serine (Ser). The composition of different amino acids, and the relative abundance of acidic, basic, and neutral amino acids might be related to the sources and consumption of various amino acids. Nine pairs of amino acids in the DFAA showed significantly positive relationship by correlation matrix analysis, suggesting that they might share similar biogeochemical processes. The degradation index (DI) of the DFAA in seawater of the Yap Trench could reflect the degradation, source, and freshness of DFAA in the trench to some extents. This is a preliminary study of amino acids from sea surface to hadal zone in the ocean, more works shall be done in different trenches to reveal their biogeochemical characteristics in extreme marine environments.
Laboratory flume experiments were done to investigate bed load sediment transport by both steady and unsteady flows in a degrading channel. The bed, respectively composed of uniform sand, uniform gravel, or sand-gravel mixtures, always undergoes bulk degradation. It is found that both uniform and non-uniform bed load transport is enhanced greatly by unsteady flows as compared to their volume-equivalent steady flows. This enhancement effect is evaluated by means of an enhancement factor, which is shown to be larger with a coarser bed and lower discharges. Also, the fractional transport rates of gravel and sand in non-uniform sand-gravel mixtures are compared with their uniform counterparts under both steady and unsteady flows. The sand is found to be able to greatly promote the transport of gravel, whilst the gravel considerably hinders the transport of sand. Particularly, the promoting and hindering impacts are more pronounced at lower discharges and tend to be weakened by flow unsteadiness. 相似文献
Although thin on the order of several to tens of millimeters, sheet flows normally comprise a lower pick-up sub-layer and an upper contact-load sub-layer, separated at the bed level (z = 0). The time-averaged concentration profile in the pick-up sub-layer shows a ‘convex upward’ curvature, but ‘concave upward’ shape characterizes the time-averaged concentration profile in the contact-load sub-layer. The time-dependent concentration in the contact-load sub-layer is approximately in-phase with the free stream flow velocity, whereas it is nearly in anti-phase with the free stream flow velocity in the pick-up sub-layer. Two distinct analytical expressions of the time-averaged concentration profiles for the respective sub-layers are proposed. The expressions are validated with detailed observation datasets collected in the Groβer Wellenkanal (GWK) prototype wave flume in Hannover, Germany. The agreement between the predicted and the measured values is excellent. Interparticle collisions in the pick-up sub-layer and convective lifting processes associated with vortex shedding in the contact-load sub-layer are considered responsible for the opposite curvatures and in-phase/anti-phase concentration variations. Both transitional boundary and reference concentration are also elaborated. 相似文献
The research on diagenesis of clastic-rock reservoir is developing rapidly in recent ten years. Thus, it is of great significance in academic and scientific exploration to summarize the domestic and international research progress and the key issues of frontier research on diagenesis. The research progress, main achievement and recognition in diagenesis of clastic-rock reservoirs in recent years is discussed, and the hot issues or developing trend of diagenesis in the future is probed in this paper, on the basis of summarizing the previous research results and understanding, combined with the typical research examples at home and abroad. It is believed that great progress was obtained in provenance and parent rock constraints on sandstone types and their diagenetic evolution pathways, impact of fluid-rock interaction and its product on diagenesis, influence of thermodynamics and overpressure background on diagenesis and pore development, the timing sequence between hydrocarbon accumulation and filling process and the sandstone reservoir becoming low permeability-densification. At present, diagenetic research is developing in direction of the spatial and temporal dynamics and quantitative evolution mechanistic and diagenetic system controlled by the basin fluid dynamics, thermal dynamic processes, combining the micro-scale diagenesis research with the basin macroscopic background such as sedimentation from the source to the basin, burial history, hydrocarbon maturity and charge into reservoirs, tectonic evolution and fluid activity, and fluid and rock interaction.The aim of this paper is to induce the academic peers and experts in diagenesis and the related research fields to come forward with their valuable contributions, to cooperate and work together and joint efforts on the research exquisite, profundity and breadth of diagenesis, and application of the most advanced analytical measurement techniques and methods, as well as integration and infiltration of multidisciplinary, in order to promote the course of the clastic-rock reservoir diagenetic research in China. 相似文献
Hyperspectral sensing can provide an effective means for fast and non-destructive estimation of leaf nitrogen (N) status in crop plants. The objectives of this study were to design a new method to extract hyperspectral spectrum information, to explore sensitive spectral bands, suitable bandwidth and best vegetation indices based on precise analysis of ground-based hyperspectral information, and to develop regression models for estimating leaf N accumulation per unit soil area (LNA, g N m−2) in winter wheat (Triticum aestivum L.). Three field experiments were conducted with different N rates and cultivar types in three consecutive growing seasons, and time-course measurements were taken on canopy hyperspectral reflectance and LNA under the various treatments. Then, normalized difference spectral indices (NDSI) and ratio spectral indices (RSI) based on the original spectrum and the first derivative spectrum were constructed within the range of 350–2500 nm, and their relationships with LNA were quantified. The results showed that both LNA and canopy hyperspectral reflectance in wheat changed with varied N rates, with consistent patterns across different cultivars and seasons. The sensitive spectral bands for LNA existed mainly within visible and near infrared regions. The best spectral indices for estimating LNA in wheat were found to be NDSI (R860, R720), RSI (R990, R720), NDSI (FD736, FD526) and RSI (FD725, FD516), and the regression models based on the above four spectral indices were formulated as Y = 26.34x1.887, Y = 5.095x − 6.040, Y = 0.609 e3.008x and Y = 0.388x1.260, respectively, with R2 greater than 0.81. Furthermore, expanding the bandwidth of NDSI (R860, R720) and RSI (R990, R720) from 1 nm to 100 nm at 1 nm interval produced the LNA monitoring models with similar performance within about 33 nm and 23 nm bandwidth, respectively, over which the statistical parameters of the models became less stable. From testing of the derived equations, the model for LNA estimation on NDSI (R860, R720), RSI (R990, R720), NDSI (FD736, FD526) and RSI (FD725, FD516) gave R2 over 0.79 with more satisfactory performance than previously reported models and physical models in wheat. It can be concluded that the present hyperspectral parameters of NDSI (R860, R720), RSI (R990, R720), NDSI (FD736, FD526) and RSI (FD725, FD516) can be reliably used for estimating LNA in winter wheat. 相似文献
This study presents a thermo-hydro-mechanical (THM) model of unsaturated soils using isogeometric analysis (IGA). The framework employs Bézier extraction to connect IGA to the conventional finite element analysis (FEA), featuring the current study as one of the first attempts to develop an IGA-FEA framework for solving THM problems in unsaturated soils. IGA offers higher levels of interelement continuity making it an attractive method for solving highly nonlinear problems. The governing equations of linear momentum, mass, and energy balance are coupled based on the averaging procedure within the hybrid mixture theory. The Drucker-Prager yield surface is used to limit the modified effective stress where the model follows small strain, quasi-static loading conditions. Temperature dependency of the surface tension is implemented in the soil-water retention curve. Nonuniform rational B-splines (NURBS) basis functions are used in the standard Galerkin method and weak formulations of the balance equations. Displacement, capillary pressure, gas pressure, and temperature are four independent quantities that are approximated by NURBS in spatial discretization. The framework is used to simulate strain localization in an undrained dense sand subjected to plane strain biaxial compression under different temperatures and displacement velocities. Results show that an increase in the displacement rate leads to reduction in the equivalent plastic strain while an increase in the temperature leads to an increase in the equivalent plastic strain. The findings suggest that the proposed IGA-based framework offers a viable alternative for solving THM problems in unsaturated soils. 相似文献