青岛近海地区SO2和SO42-干沉降速率的季节变化

用小麦岛和团岛观测站提供的青岛近海气象和水温资料,以适于SO2气体和硫酸盐(SO42-)气溶胶的干沉降模型研究了模型中的输送阻尼对两种污染物质干沉降速率的贡献,并计算了2003年青岛近海地区两种污染物质干沉降速率的季节变化。结果表明:对SO2而言,粘性副层传输系数对沉降速率的贡献大于空气动力学传输系数;对于SO42-,空气动力学传输系数对沉降速率的贡献要大于表面传输系数。SO2和SO42-的干沉降速率变化范围分别为0.187~0.868cm/s和0.188~0.532cm/s。两种污染物质干沉降速率的四季变化有相似的规律,即冬季>秋季>春季>夏季。     

Summer distribution and geochemical composition of suspended-particulate matter in the east china sea

The distribution and geochemical composition of suspended-particulate matter (SPM) in the East China Sea (ECS) were investigated during the summer period of high continental runoff to elucidate SPM sources, distribution and cross-shelf transport. The spatial variability of SPM distribution (0.3–6.5 mg l⁻¹) and geochemical composition (POC, Al, Si, Fe, Mn, Ca, Mg and K) in the ECS was pronounced during summer when the continental fluxes of freshwater and terrestrial materials were highest during the year. Under the influences of Changjiang runoff, Kuroshio intrusion, surface production and bottom resuspension, the distribution generally showed strong gradients decreasing seaward for both biogenic and lithogenic materials. Particulate organic carbon was enriched in surface water (mean ∼18%) due to the influence of biological productivity, and was diluted by resuspended and/or laterally-transported materials in bottom water (mean 9.4%). The abundance of lithogenic elements (Al, Si, Fe, Mn) increased toward the bottom, and the distribution correlations were highly significant. Particulate CaCO₃ distribution provided evidence that the SPM of the bottom water in the northern part of the study area was likely mixed with sediments originally derived from Huanghe. A distinct benthic nepheloid layer (BNL) was present in all seaward transects of the ECS shelf. Sediment resuspension may be caused by tidal fluctuation and other forcing and be regarded as the principal agent in the formation of BNL. This BNL was likely responsible for the transport of biogenic and lithogenic particles across or along the ECS shelf. Total inventories of SPM, POC and PN are 46, 2.8 and 0.4 Tg, respectively, measured over the total area of 0.45 × 10⁶ km² of the ECS shelf. Their mean residence times are about 27, 13 and 11 days, respectively. The inventory of SPM in the water column was higher in the northernmost and southernmost transects and lower in the middle transects, reflecting the influences of terrestrial inputs from Changjiang and/or resuspended materials from Huanghe deposits in the north and perhaps from Minjiang and/or Taiwan’s rivers in the south. The distribution and transport patterns of SPM and geochemical elements strongly indicate that continental sources and cross-shelf transport modulate ECS particulate matter in summer.     

海底天然气水合物的地震资料处理与分析

介绍了利用多道反射地震资料，采用反射振幅随炮检距变化AVO（Ampltude versus Offset)技术和其他地震正、反演方法，通过研究地震剖面上的拟海底反射层（BSR）分布、地震弹性参数特征，来探讨BSR上、下方含天然气水合物沉积层和含游离气沉积层的内部结构和某些主要物理性质，如沉积物的空隙率、天然气水合物的饱和度等，由此来评估海底天然气水合物的资源前景并研究其成矿机制。     

东海钙质生物骨屑的矿物学特征

通过电镜、电子探针和X射线等项分析,对东海沉积物中的有孔虫、腹足类、双壳类、苔藓、珊瑚、海胆等骨屑进行了矿物学研究,确定了矿物成分与生物属种的关系,并基于有孔虫壳体化学成分将壳体分为均质壳和异质壳,生物碳酸盐中镁主要富集在方解石及镁方解石中,锶在方解石和镁方解石中的分配系数(D)相似,为0.11—0.14;在文石质骨屑中D=1.09-1.20。碳氧同位素组成与生物属种有明显关系。据一些有孔虫壳体氧同位素偏差值计算的水温来看,本次测定的有孔虫属种的骨屑不能作为理想的骨屑温度计。     

我国海水制盐工艺改革的设计研究

从技术上和工艺上的可能性、可行性和合理性，论证了海水制盐工艺改革的必要性，并且提出了实现海水制盐工艺改革的各种设计方案。它对我国的海水制盐工业的发展将具有深远意义。     

海底天然气水合物地球化学探测技术

海底天然气水合物是未来的新型能源，地球化学探测与分析技术在天然气水合物勘探、研究和开发中发挥巨大作用。简要介绍了天然气水合物地球化学探测方法及相关的分析测试技术，包括海底沉积物、海水、海面低层大气中烃类气体(主要为甲烷)、孔隙水中阴阳离子和同位素地球化学异常等。并对发展天然气水舍物地球化学探测与分析新技术提出建议。     

Co–rich Mn crusts from the Magellan Seamount cluster: the long journey through time

The Magellan seamounts began forming as large submarine shield volcanoes south of the equator during the Cretaceous. These volcanoes formed as a cluster on the small Pacific plate in a period when tectonic stress was absent. Thermal subsidence of the seafloor led to sinking of these volcanoes and the formation of guyots as the seamounts crossed the equatorial South Pacific (10–0°S) sequentially and ocean surface temperatures became too high for calcareous organisms to survive. Guyot formation was completed between about 59 and 45 Ma and the guyots became phosphatized at about 39–34 and 27–21 Ma. Ferromanganese crusts began formation as proto-crusts on the seamounts and guyots of the Magellan Seamount cluster towards the end of the Cretaceous up to 55 Ma after the formation of the seamounts themselves. The chemical composition of these crusts evolved over time in a series of steps in response to changes in global climate and ocean circulation. The great thickness of these crusts (up to 15–20 cm) reflects their very long period of growth. The high Co contents of the outer parts of the crusts are a consequence of the increasing deep circulation of the ocean and the resulting deepening of the oxygen minimum zone with time. Growth of the Co-rich Mn crusts in the Magellan Seamount cluster can be considered to be the culmination of a long journey through time.     

Estimating the geostrophic velocity obtained by HF radar observations in the upstream area of the Kuroshio

A method to extract geostrophic current in the daily mean HF radar data in the Kuroshio upstream region is established by comparison with geostrophic velocity determined from the along-track altimetry data. The estimated Ekman current in the HF velocity is 1.2% (1.5%) and 48° (38°)-clockwise rotated with respect to the daily mean wind in (outside) the Kuroshio. Furthermore, additional temporal smoothing is found necessary to remove residual ageostrophic currents such as the inertial oscillation. After removal of the ageostrophic components, the HF geostrophic velocity agrees well with that from the altimetry data with rms difference 0.14 (0.12) m/s in (outside) the Kuroshio.     

The origin and biogeochemistry of organic matter in surface sediments of Lake Shihwa and Lake Hwaong

To understand the origin and biogeochemistry of the organic matter in surface sediments of Lake Shihwa and Lake Hwaong, organic nitrogen, inorganic nitrogen, labile organic carbon, and residual organic carbon contents as well as stable isotope ratios for carbon and nitrogen were determined by KOBr-KOH treatment. Ratios of organic carbon to organic nitrogen (C_org/N_org) (mean = 24) were much higher than ratios of organic carbon to total nitrogen (C_org/N_tot) (mean=12), indicating the presence of significant amounts of inorganic nitrogen in the surface sediments of both lakes. Stable isotope ratios for organic nitrogen were, on average, 5.2‰ heavier than ratios of inorganic nitrogen in Lake Shihwa, but those same ratios were comparable in Lake Hwaong. This might be due to differences in the origin or the degree of degradation of sedimentary organic matter between the two lakes. In addition, stable isotope ratios for labile organic carbon were, on average, 1.4‰ heavier than those for residual organic carbon, reflecting the preferential oxidation of¹³C-enriched organic matter. The present study demonstrates that KOBr-KOH treatment of sedimentary organic matter can provide valuable information for understanding the origin and degradation state of organic matter in marine and brackish sediments. This also suggests that the ratio of C_org/N_org and stable isotope ratios for organic nitrogen can be used as indexes of the degree of degradation of organic matter.