Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

土体颗粒破碎研究进展

在打入桩的桩端以及大型土石坝、海洋平台等的地基中常常会出现高应力区。在这些高应力区中,作为地基的粒状土的颗粒会发生不同程度的破碎。对高应力水平下粒状土体的破碎特性进行深入研究有助于解决这一类型的岩土工程问题。因此近年来土体颗粒破碎逐渐引起人们的重视。本文对土体颗粒破碎研究现状进行了详尽的阐述,并指出研究中存在的问题及今后研究发展方向。     

Predators of juvenile blue crabs outside of refuge habitats in lower Chesapeake Bay

Blue crabsCallinectes sapidus in lower Chesapeake Bay are subject to high rates of predation during the late summer of their first year of growth as they migrate out of vegetated nursery habitats. Predators, potentially contributing to this pattern, were identified in video-recorded field observations of tethered juvenile crabs (20–25 mm carapace width). Predators were also tested in large laboratory tanks containing similarly-sized untethered crabs as prey. Seven different predators attacked tethered crabs in the field. Only two predators, larger blue crabs and northern puffers,Sphoeroides maculatus, consistently succeeded in preying on crabs in both field and laboratory settings. These results confirm the importance of cannibalism on juvenile blue crabs and identify puffers as a potentially overlooked source of predation pressure.     

Deconvolving the δO seawater component from subseasonal coral δO and Sr/Ca at Rarotonga in the southwestern subtropical Pacific for the period 1726 to 1997

To reconstruct oceanographic variations in the subtropical South Pacific, 271-year long subseasonal time series of Sr/Ca and δ¹⁸O were generated from a coral growing at Rarotonga (21.5°S, 159.5°W). In this case, coral Sr/Ca appears to be an excellent proxy for sea surface temperature (SST) and coral δ¹⁸O is a function of both SST and seawater δ¹⁸O composition (δ¹⁸O_sw). Here, we focus on extracting the δ¹⁸O_sw signal from these proxy records. A method is presented assuming that coral Sr/Ca is solely a function of SST and that coral δ¹⁸O is a function of both SST and δ¹⁸O_sw. This method separates the effects of δ¹⁸O_sw from SST by breaking the instantaneous changes of coral δ¹⁸O into separate contributions by instantaneous SST and δ¹⁸O_sw changes, respectively. The results show that on average δ¹⁸O_sw at Rarotonga explains ∼39% of the variance in δ¹⁸O and that variations in SST explains the remaining ∼61% of δ¹⁸O variance. Reconstructed δ¹⁸O_sw shows systematic increases in summer months (December-February) consistent with the regional pattern of variations in precipitation and evaporation. The δ¹⁸O_sw also shows a positive linear correlation with satellite-derived estimated salinity for the period 1980 to 1997 (r = 0.72). This linear correlation between reconstructed δ¹⁸O_sw and salinity makes it possible to use the reconstructed δ¹⁸O_sw to estimate the past interannual and decadal salinity changes in this region. Comparisons of coral δ¹⁸O and δ¹⁸O_sw at Rarotonga with the Pacific decadal oscillation index suggest that the decadal and interdecadal salinity and SST variability at Rarotonga appears to be related to basin-scale decadal variability in the Pacific.     

Change detection in Sal forest in Dehradun Forest Division using remote sensing and geographical information system

The review of study site have revealed the change in vegetation cover of Sal Dense to Sal Medium and Sal Open in 6 forest Mosaics owing to biotic and abiotic conditions prevailing in the specific areas. Analysis carried out using thematic map derived from aerial photograph of 1976 and satellite data of IRS 1C LISS III False Colour Composite (FCC) of March 1999 revealed the cause for change in forest density classes. Deforestation, encroachment and agriculture have been identified as the underlying causes, which have affected some specific locations to a marked extent. There has been a progressive and remarkable change among vegetation classes from 1976 to 1999. It is evident from forest type and density map that Sal density has significantly reduced from Sal Dense 65.61 % in 1976 to Sal Dense 11.12% in the year 1999 followed by Sal Open 11.18 % and Sal Medium 18.24 %. The overall change has been estimated to be 42.11% of the total forested area.     

Estimation of recent glacial variations in baspa basin using remote sensing technique

The Himalayas has one of the largest concentrations of glaciers outside the Polar Regions. Various reports suggest that significant number of mountain glaciers is shrinking due to climatic variations. Monitoring of these glaciers is important to assess future availability of water resources in the Himalayan region. However, Himalayan glaciers are normally difficult to monitor due to the rugged, mountainous terrain. Therefore, images of Indian Remote Sensing Satellite were used to monitor glaciers in the Baspa basin. Investigations have shown the presence of 30 glaciers in the basin, with areal extent of 167 km2. Out of these, 19 glaciers, with areal extent of 140 km² were selected to estimate retreat. Investigation suggests that almost all glaciers are retreating in the study basin and overall 19% deglaciation has been observed from 1962 to 2001. In general, altitude distribution appears to have significant influence on glacial retreat. Glaciers located around 5000 m altitude range are showing 24% loss as compared to 14% by glaciers located in altitude range higher than 5400 m. In addition, mean altitude of glacier terminus is shifted upward by 88 m, i.e. from 4482 to 4570 m in last 39 years. The glacial volumes were estimated using regression relationship between area and depth. The investigations have suggested that 19.10 km³ of glacial water stored in the 19 glaciers in 1962, has been reduced to 14.71 km³ in 2001, respectively, an overall loss of 23 percent in a period between 1962 and 2001. These investigations suggest that all glaciers in the Baspa Basin are reducing and in long term, such reducing trend can create scarcity of water in the region.     

Remote sensing and gis applications in the identification of aquaculture hotspots at village level

Interpretation of IRS LISS II and LISS III imagery has revealed the various landforms as well as land use/land cover features in a part of the Godavari delta coastal belt. A comparative analysis of geomorphological vs. land use/land cover maps suggested that the landforms exert a certain degree of control over human land use activities even in this monotonously plain area. Further, an analysis of the sequential imagery pertaining to 1992 and 2001 aimed at detecting the land use/land cover change has indicated that the aquaculture has phenomenally increased by 9,293.5 ha during the 9-year period. At the same time, the cropland which occupied about 29,104 ha in 1992 has been reduced to 19,153.9 ha by 2001 mainly due to the encroachment of aquaculture. Village level data on temporal variation in land use/land cover extracted through GIS analysis revealed that in 14 out of the total 39 villages in the area, the conversion of cropland into aquaculture ponds was more than 30% with the highest conversion rate of 89.8% in Gondi village. These fourteen villages, which are designated as ‘aquaculture hotspots’ are grouped into 4 priority classes based on the intensity of conversion.     

HUBEX强化观测期雷达测雨在水文过程模拟中的应用(英)

选择全球能量与水循环亚洲季风试验区的淮河黄泥庄水文站控制的史河流域(805 km2)为研究区域,基于数字高程模型,生成栅格水流流向,构建数字流域及空间拓扑关系;然后,将阜阳雷达观测数据经过订正校准后作为研究区内每一栅格单元上的雨量输入,并在每一栅格上应用新安江模型构建产流模型;再根据每一栅格至流域出口断面-黄泥庄水文站的距离,运用Muskingum方法进行汇流演算,从而获得黄泥庄站的流量过程。计算结果显示,从1998年5月31日-8月3日的强化观测期内模型确定性系数为92.41％,其间4场洪水的确定性系数分别为85.64％、86.62％、92.57％和83.91％,高于应用地面雨量计观测的数据计算的结果。这说明雷达测雨数据具有较高的时空分辨率,当它应用于水文过程模拟时优于地面雨量计资料,基于栅格的水文模型为充分利用雷达数据提供了良好平台。