Correlation analysis and partial least square modeling to quantify typical minerals with Chang＇E-3 visible and near-infrared imaging spectrometer＇s ground validation data

In 2013, Chang＇E-3 program will develop lunar mineral resources in-situ detection. A Visible and Near-infrared Imaging Spectrometer （VNIS） has been selected as one payload of CE-3 lunar rover to achieve this goal. It is critical and urgent to evaluate VNIS＇ spectrum data quality and validate quantification methods for mineral composition before its launch. Ground validation experiment of VNIS was carried out to complete the two goals, by simulating CE-3 lunar rover＇s detection environment on lunar surface in the laboratory. Based on the hyperspectral reflectance data derived, Correlation Analysis and Partial Least Square （CA-PLS） algorithm is applied to predict abundance of four lunar typical minerals （pyroxene, plagioclase, ilmenite and olivine） in their mixture. We firstly selected a set of VNIS＇ spectral parameters which highly correlated with minerals＇ abundance by correlation analysis （CA）, and then stepwise regression method was used to find out spectral parameters which make the largest contri- butions to the mineral contents. At last, functions were derived to link minerals＇ abundance and spectral parameters by partial least square （PLS） algorithm. Not considering the effect of maturity, agglutinate and Fe~, we found that there are wonderful correlations between these four minerals and VNIS＇ spectral parameters, e.g. the abundance of pyroxene correlates positively with the mixture＇s absorption depth, the value of absorption depth added as the in- creasing of pyroxene＇s abundance. But the abundance of plagioclase correlates negatively with the spectral parame- ters of band ratio, the value of band ratio would decrease when the abundance of plagioclase increased. Similar to plagioclase, the abundance of ilmenite and olivine has a negative correlation with the mixture＇s reflectance data, if the abundance of ilmenite or olivine increase, the reflectance values of the mixture will decrease. Through model validation, better estimates of pyroxene, plagioclase and ilmenite＇s abundances are given. It is concluded that VNIS has the capability to be applied on lunar minerals＇ identification, and CA-PLS algorithm has the potential to be used on lunar surface＇s in-situ detection for minerals＇ abundance prediction.     

川北地区寒武系筇竹寺组钙质结核裂缝充填物特征及指示意义

川北地区寒武系筇竹寺组钙质结核泥页岩中早成岩期钙质结核较发育,结核裂缝中见多期次矿物充填。为揭示钙质结核裂缝形成机理,本次结合岩石学特征及地球化学特征等开展系统研究。川北筇竹寺组钙质结核裂缝中见三~四期矿物充填。第一期微晶方解石表面较脏,阴极发光暗淡,δ13C_(PDB)、δ18O_(PDB)平均值分别为-4.26‰及-7.69‰;第二期为细—中晶粒状方解石充填,阴极发光为橘黄色,流体包裹体均一温度为平均值为86.4℃,δ13C_(PDB)、δ18O_(PDB)平均值分别为-3.15‰及-7.41‰;第三期为粗晶方解石充填阴极发光暗淡,流体包裹体均一温度平均值为96.6℃,δ~(13)C_(_(PDB))、δ~(18)O_(_(PDB))平均值分别为-1.73‰及-10.28‰;第四期为重晶石充填。结合区域构造史—热演化史分析表明,钙质结核裂缝中四期充填物分别指示早期脱水、烃源岩早成熟期生烃、加里东构造运动抬升释压及深埋藏期硫酸盐热还原作用事件。     

Vertical variations and composition of dissolved free amino acid in the seawater of the Yap Trench in the western Pacific Ocean

The composition and concentration of dissolved free amino acid (DFAA) of seawater samples collected in May 2016 from the surface to the hadal zone of the northern region of the Yap Trench were analyzed by pre-column derivatization of o-phthalaldehyde. Results show that the average concentration of DFAA in the study area was 0.47±0.36 µmol/L. In different sampling stations, the concentrations of DFAA with water depth showed complex variation patterns. At the sediment-seawater interface, the concentrations of DFAA in the western side of the trench were obviously higher than that in its eastern side. In the study area, there were no significant correlations between the concentrations of DFAA and the environmental parameters such as concentrations of chlorophyll a (Chl a), dissolved oxygen (DO), pH, and dissolved inorganic nitrogen (DIN), indicating that the concentrations of DFAA in seawater of the trench are affected by many factors, such as photosynthesis, respiration, temperature, pressure, illumination, and circulation. The dominant DFAA are similar in different water layers of sampling stations, including aspartic acid (Asp), glutamic acid (Glu), glycine (Gly), and serine (Ser). The composition of different amino acids, and the relative abundance of acidic, basic, and neutral amino acids might be related to the sources and consumption of various amino acids. Nine pairs of amino acids in the DFAA showed significantly positive relationship by correlation matrix analysis, suggesting that they might share similar biogeochemical processes. The degradation index (DI) of the DFAA in seawater of the Yap Trench could reflect the degradation, source, and freshness of DFAA in the trench to some extents. This is a preliminary study of amino acids from sea surface to hadal zone in the ocean, more works shall be done in different trenches to reveal their biogeochemical characteristics in extreme marine environments.

     

昌宁—孟连结合带北端癞痢头山岩体地球化学特征及其对成岩成矿作用的启示

位于昌宁—孟连结合带北端的癞痢头山岩体,主要由中粗晶花岗闪长岩(MGG)和细晶花岗闪长岩(FG)组成,形成于中三叠世(232 Ma).MGG和FG岩相学特征相似,无明显空间分带关系,呈过渡渐变关系.它们具高硅(w(SiO2) =66.2％～68.2％,平均67.0％),富钾(K2O/Na2O=1.04～2.59,平均1.64),贫碱(w(Na2O+K2O)=5.45％～7.31％,平均5.99％)、低钠(w(Na2O)=1.54％～3.58％,平均2.38％),高镁值(Mg#=47.3～58.7,平均51.5)和过铝质(A/CNK=1.41～2.17,平均1.65)特征,属过铝质高钾钙碱性系列.二者轻、重稀土元素含量比值介于6.91～12.1,表现为轻稀土元素相对富集、重稀土元素相对亏损.岩石富集w(Rb) (54.7～176×10-6),w(U)(1.10～4.77×10-6),w(Th) (9.33～35.30×10-6)等大离子亲石元素,亏损w(Ta) (1.22～1.51×10-6),w(Nb)(14.9～18.5×10-6),w(Zr)(78.4～171.0×10-6)等高场强元素,以及δEu(0.35～0.57)和"TNT"负异常特征,表明初始岩浆以陆壳成分为主并有幔源组分的加入.癞痢头山岩体样品具有较高的A/CNK值(1.41～2.17)和刚玉分子含量(1.87％～8.67％),以及Nb/Ta比值(11.03～13.76)和Zr/Hf比值(23.13～47.85)分别与平均地壳和壳源岩石相应比值一致,显S型花岗岩特征.综合分析,认为癞痢头山岩体属于S型花岗岩,起源于古老地壳物质(贫黏土的古老杂砂岩)部分熔融岩浆和底侵作用带入的幔源岩浆的混合岩浆,是保山—思茅地块陆陆后碰撞阶段力学性质由挤压向伸展转化动力学背景下的产物,具备成矿作用发生的物质基础,有一定的找矿潜力.     

垂直应变的研究意义及模型分析

近20多年来国内垂直应变领域一直无人涉及.垂直应变量的获取可将应变固体潮从平面应变观测提升到三维空间应变观测.本文说明了垂直应变观测的必要性,建立了垂直应变观测系统的原始模型,并提出了研制的难点和理论上的解决方法.     

Gravity variation before Kunlun mountain pass western Ms=8.1 earthquake

The relation between the gravity variation features and Ms=8.1 earthquake in Qinghai-Xizang monitoring area is analyzed preliminarily,by using spatial dynamic variation results of regional gravity field from absolute gravity and relative gravity observation in 1998 and 2000.The results show that:1)Ms\8.1 earthquake in Kulun mountain pass westem occurred in the gravity variation high gradient near gravity‘s high negative variation;2)The Main tectonic deformation and emnergy accumulation before MS=8.1 earthquake are distributed at south side of the epicenter;3)The range of gravity‘s high negative variation at east of the MS=8.1 earthquake epicenter relatively coincides with that rupture region according to field geology investigation;4)Gravity variation distribution in high negative value region is just consistent with the second shear strain‘s high value region of strain field obtained from GPS observation.     

聚能爆破在大直径硬岩钻进中的应用及影响因素

通过对大直径硬岩钻进中常用钻进方法优缺点的分析,结合对聚能爆破原理和影响因素的探讨,提出在大直径硬岩钻进中采用聚能爆破和普通钻进方法相结合的复合钻进工艺,指出了聚能爆破在大直径硬岩钻进中具有广阔的应用前景     

达陕高速金竹山隧道涌水塌方的综合处治研究

在调查隧道K64 +664～ K64+ 674段涌水塌方特征的基础上,从地质结构和地层岩性分析其成因.相应地,建立综合工作程序,采用”超前双排长管棚+小导管+注浆+三台阶法施工+瓦斯监测”的综合方案.对灾害进行处治,效果明显.     

拱形波纹钢屋盖动力特性测试及分析

拱形波纹钢屋盖是一种新颖的金属拱形薄壳结构，在我国已经得到了广泛的应用。由于结构的复杂性，目前有关的理论研究尚不够深入，动力研究还很少有人涉及。以18m和30m两种跨度的W666型拱形波纹钢屋盖为研究对象，测试了拱在竖向平面内振动时的频率、振型及阻尼。在所提简化计算模型的基础上，采用有限元方法计算了结构的动力特性，其结果与试验数据符合较好。测试和分析结果为该结构的动力反应研究提供了方便。     

玛尼7.9级地震对昆仑山口西8.1级地震的触发作用及动力背景初探

根据库仑静应力变化的概念，对青藏块体中部地区1997年11月8日玛尼7．9级地震及2001年11月14日昆仑山口西8．1级地震的应力触发作用进行了初步研究。不同震源机制解计算结果表明，玛尼地震造成了昆仑地震断层面上10^-3MPa量级的库仑应力增量，该变化仅使得昆仑地震的发生提前了最长10年左右，表明当前地壳应变能水平可能并不很低。对照20世纪初以来全球7级以上强震频度和强度演化特征与地球自转变化的关系，认为地球自转幅度衰减、变化频率升高是近期强震活动的重要控制因素。昆仑山口西8．1级地震的发生，可能是地球自转持续加速阶段后期，青藏块体内部区域应力场逐渐强化，及玛尼地震应力触发的结果。