下扬子PTB界线深水相区粘土岩的火山成因研究及其对LPME的指示意义

全球,尤其是特提斯域二叠—三叠纪之交(PTB)剖面中普遍发育火山成因的粘土岩,对理解晚二叠世末生物大灭绝(LPME)的触发机制及相关基础地质问题具有重要意义。本文报道了在华南下扬子区新发现两条深水PTB剖面(皖南牛山和蔡村)的粘土岩工作,包括岩石学、矿物学和全岩地球化学等,填补了区域研究空白。研究结果发现,粘土岩主要由伊利石等粘土矿物,以及石英、岩浆锆石、长石等斑晶矿物组成。在地球化学上具有高K_2O、低Na_2O、相对富集大离子亲石元素(LILE)、相对亏损高场强元素(HFSE)等特征。据此,认为这些粘土岩为火山成因的钾质斑脱岩,其原岩可能为中酸性流纹英安岩,具有弧岩浆作用的源区背景。对比华南其他地区已发现的PTB界线粘土岩,发现它们成因类似,可能来源于古特提斯洋周缘陆陆碰撞,抑或是泛大洋俯冲潘吉亚大陆东缘(包括华南板块)所导致的长英质火山岩浆喷发,且具有多期多源性特点。PTB时期全球活跃的火山岩浆活动(包括镁铁质火山作用和华南地区火山灰所指征的长英质火山作用)可能是导致LPME的主要原因。     

长江中下游庐枞火山岩盆地南侧钾质侵入岩带的成因

庐枞火山岩盆地南侧的钾质侵入岩带由正长岩-石英正长岩-正长花岗岩组成,以石英正长岩为主。它们的形成时间介于123"130 Ma之间,峰值约为126 Ma,其中正长岩和石英正长岩的形成时间稍早,而正长花岗岩的形成时间略晚。整个钾质侵入岩带的侵位时间晚于庐枞盆地内的橄榄玄粗质火山作用约4"7 Ma,也是长江中下游地区除最东段的宁镇地区外中生代最晚的岩浆活动产物之一。地球化学上,该钾质侵入岩带以高钾、富碱、富集Rb、Th、U、K等强不相容元素和轻稀土元素、亏损高场强元素Nb、Ta和Ti为特征。它们的母岩浆主要是由富集型上地幔部分熔融形成的,从正长岩经石英正长岩到正长花岗岩的演化主要受矿物的分离结晶作用控制,地壳物质同化所起的影响不大。但与同样来自富集型上地幔部分熔融的庐枞盆地内火山杂岩的母岩浆相比,前者的母岩浆来源深度可能更大些或其中包含了更多来自软流圈地幔的组分。两者的演化路径也完全不同,钾质侵入岩带的母岩浆除经历过高压下的分离结晶作用外,晚期在低压下还经历过长石为主,可能还有黑云母的分离结晶,甚至上地壳物质一定程度的混染作用;而盆地内火山杂岩的母岩浆低压下矿物的分离结晶作用及上地壳物质的混染都不明显。庐枞盆地南缘的富钾侵入岩与盆地内的火山杂岩一样,地球化学上都具有明显的大陆弧的特征,暗示它们的岩浆源区可能形成于俯冲带环境,意味着扬子地块北缘先前(推测为古元古代晚期)曾发生过俯冲作用,上地幔的交代富集可能就与这次的俯冲作用有关。     

青藏高原拉萨地块西部念青唐古拉岩群的地球化学特征及构造意义

拉萨地块西部呈断块状沿狮泉河-申扎-嘉黎蛇绿混杂岩带附近分布的念青唐古拉岩群被认为是前寒武纪变质基底。本文对念青唐古拉岩群进行了系统的岩石学、地球化学、同位素年代学及构造地质学研究。研究结果表明片岩-片麻岩-变粒岩含十字石、石榴子石等特征变质矿物,遵循粒度分异规律,其原岩可能为来自冈瓦纳古陆核北缘中新元古代弧盆体系的活动大陆边缘浊积岩。斜长角闪岩具低硅、高铁镁、富钙的基性岩特征,其原岩为岛弧型基性火山岩。念青唐古拉岩群中的花岗伟晶岩锆石LA-ICPMS U-Pb年龄为1150±13Ma,具过铝质S型花岗岩地球化学特征,可能为中元古代(1150±13 Ma)以前就开始沉积的念青唐古拉岩群基底岩石通过部分熔融形成。与花岗伟晶岩渐变过渡接触的二云斜长片麻岩第一组变质重结晶锆石U-Pb年龄为701±15 Ma,结合十字石特征变质矿物,暗示了该地区中温高压变质作用的峰期变质,变质程度达角闪岩相;第二组热液流体锆石UPb年龄为301±8.4 Ma,可能与冈瓦纳大陆北缘古特提斯洋演化过程中的岩浆热液作用有关。     

利用多光谱卫星遥感和深度学习方法进行青藏高原积雪判识

青藏高原积雪对全球气候变化十分重要,针对已有积雪遥感判识方法中普遍采用的可见光与红外光谱数据易受复杂地形与高海拔影响,导致青藏高原地区积雪判识精度较低的问题,提出了一种基于多光谱遥感与地理信息数据特征级融合的积雪遥感判识方法:以风云三号卫星可见光与红外多光谱遥感资料与多要素地理信息作为数据源,由地面实测雪深数据与现有积雪产品交叉筛选出样本标签,构建并训练基于层叠去噪自编码器(SDAE)的特征融合与分类网络,从而有效辨识青藏高原遥感图像中的云、积雪以及无雪地表。经地面实测雪深数据验证,该方法分类精度显著高于使用相同数据源的FY-3A/MULSS积雪产品,略高于国际主流积雪产品MOD10A1与MYD10A1,并且年均云覆盖率最低。试验结果表明该方法可有效地减少云层对积雪判识的干扰,提升分类精度。     

一种优化的公共主影像选取方法

针对PS-DINSAR技术中公共主影像的选取问题,提出了基于测量平差理论的归化权值和的方法。该方法在综合相关系数方法的基础上,综合考虑了时间基线、有效空间基线和多普勒质心频率差的影响,利用平差的思想进行定权,来选择公共主影像。归化权值和的方法主影像的选择更加合理、可靠。基于ERS-1/2的影像数据进行实验的实验说明:该算法在主影像的选取上更加稳定,数据的统计特性也更优化,对PS公共主影像的优化选择有重要参考价值。     

一种基于灰度块匹配的视野监测算法

针对视野移动方向的判断问题,该文介绍了运动补偿的常用方法及应用,提出了基于灰度块匹配的视野移动监测算法。通过对比各种算法计算复杂度和计算时间,发现灰度投影算法准确率低、计算量较小;块匹配搜索算法中的穷尽搜索算法准确率高,但是计算量较大。为了发挥以上两者算法的优势,将两者结合形成了灰度块匹配算法,并通过实验证实了灰度块匹配算法在实时监测系统中的可行性。     

The Electrical Conductivity Structure of the Lanping–Simao Basin and its Implications for Mineralization

正Objective The Lanping–Simao Basin in western Yunnan,located in the southeastern margin of the Tibetan Plateau,is tectonically in the transition zone between the Gondwana and Eurasia tectonic domains.It is also the frontier zone of northeastern extrusion of the Indochina Plate towards the     

Fractionation characteristics of rare earth elements (REEs) linked with secondary Fe,Mn, and Al minerals in soils

Soil secondary minerals are important scavengers of rare earth elements (REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs (La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs (LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs (HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs. The substantial fractions of REEs in soils extracted by oxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile (10 %–30 %), which were similar to the mass fraction of Fe (10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation.     

Development and Utilization of the World’s and China’s Bulk Mineral Resources and their Supply and Demand Situation in the Next Twenty Years

Bulk mineral resources of iron ores, copper ores, bauxite, lead ores, zinc ores and potassium salt play a pivotal role on the world’s and China’s economic development. This study analyzed and predicted their resources base and potential, development and utilization and their world’s and China’s supply and demand situation in the future 20 years. The supply and demand of these six bulk mineral products are generally balanced, with a slight surplus, which will guarantee the stability of the international mineral commodity market supply. The six mineral resources(especially iron ores and copper ores) are abundant and have a great potential, and their development and utilization scale will gradually increase. Till the end of 2014, the reserveproduction ratio of iron, copper, bauxite, lead, zinc ores and potassium salt was 95 years, 42 years, 100 years, 17 years, 37 years and 170 years, respectively. Except lead ores, the other five types all have reserve-production ratio exceeding 20 years, indicative of a high resources guarantee degree. If the utilization of recycled metals is counted in, the supply of the world’s six mineral products will exceed the demand in the future twenty years. In 2015–2035, the supply of iron ores, refined copper, primary aluminum, refined lead, zinc and potassium salt will exceed their demand by 0.4–0.7 billion tons(Gt), 5.0–6.0 million tons(Mt), 1.1–8.9 Mt, 1.0–2.0 Mt, 1.2–2.0 Mt and 4.8–5.6 Mt, respectively. It is predicted that there is no problem with the supply side of bulk mineral products such as iron ores, but local or structural shortage may occur because of geopolitics, monopoly control, resources nationalism and trade friction. Affected by China’s compressed industrialized development model, the demand of iron ores(crude steel), potassium salt, refined lead, refined copper, bauxite(primary aluminum) and zinc will gradually reach their peak in advance. The demand peak of iron ores(crude steel) will reach around 2015, 2016 for potassium salt, 2020 for refined lead, 2021 for bauxite(primary aluminum), 2022 for refined copper and 2023 for zinc. China’s demand for iron ores(crude steel), bauxite(primary aluminum) and zinc in the future 20 years will decline among the world’s demand, while that for refined copper, refined lead and potassium salt will slightly increase. The demand for bulk mineral products still remains high. In 2015–2035, China’s accumulative demand for iron ores(crude steel) will be 20.313 Gt(13.429 Gt), 0.304 Gt for refined copper, 2.466 Gt(0.616 Gt) of bauxite(primary aluminum), 0.102 Gt of refined lead, 0.138 Gt of zinc and 0.157 Gt of potassium salt, and they account for the world’s YOY(YOY) accumulative demand of 35.17%, 51.09%, 48.47%, 46.62%, 43.95% and 21.84%, respectively. This proportion is 49.40%, 102.52%, 87.44%, 105.65%, 93.62% and 106.49% of that in 2014, respectively. From the supply side of China’s bulk mineral resources, it is forecasted that the accumulative supply of primary(mine) mineral products in 2015–2035 is 4.046 Gt of iron ores, 0.591 Gt of copper,1.129 Gt of bauxite, 63.661 Mt of(mine) lead, 0.109 Gt of(mine) zinc and 0.128 Gt of potassium salt, which accounts for 8.82%, 13.92%, 26.67%, 47.09%, 33.04% and 15.56% of the world’s predicted YOY production, respectively. With the rapid increase in the smelting capacity of iron and steel and alumina, the rate of capacity utilization for crude steel, refined copper, alumina, primary aluminum and refined lead in 2014 was 72.13%, 83.63%, 74.45%, 70.76% and 72.22%, respectively. During 2000–2014, the rate of capacity utilization for China’s crude steel and refined copper showed a generally fluctuating decrease, which leads to an insufficient supply of primary mineral products. It is forecasted that the supply insufficiency of iron ores in 2015–2035 is 17.44 Gt, 0.245 Gt of copper in copper concentrates, 1.337 Gt of bauxite, 38.44 Mt of lead in lead concentrates and 29.19 Mt of zinc in zinc concentrates. China has gradually raised the utilization of recycled metals, which has mitigated the insufficient supply of primary metal products to some extent. It is forecasted that in 2015–2035 the accumulative utilization amount of steel scrap(iron ores) is 3.27 Gt(5.08 Gt), 70.312 Mt of recycled copper, 0.2 Gt of recycled aluminum, 48 Mt of recycled lead and 7.7 Mt of recycled zinc. The analysis on the supply and demand situation of China’s bulk mineral resources in 2015–2035 suggests that the supply-demand contradiction for these six types of mineral products will decrease, indicative of a generally declining external dependency. If the use of recycled metal amount is counted in, the external dependency of China’s iron, copper, bauxite, lead, zinc and potassium salt will be 79%, 65%, 26%, 8%, 16% and 18% in 2014, respectively. It is predicted that this external dependency will decrease to 62%, 64%, 20%,-0.93%, 16% and 14% in 2020, respectively, showing an overall decreasing trend. We propose the following suggestions correspondingly.(1) The demand peak of China’s crude steel and potassium salt will reach during 2015–2023 in succession. Mining transformation should be planned and deployed in advance to deal with the arrival of this demand peak.(2) The supply-demand contradiction of China’s bulk mineral resources will mitigate in the future 20 years, and the external dependency will decrease accordingly. It is suggested to adjust the mineral resources management policies according to different minerals and regions, and regulate the exploration and development activities.(3) China should further establish and improve the forced mechanism of resolving the smelting overcapacity of steel, refined copper, primary aluminum, lead and zinc to really achieve the goal of "reducing excess production capacity".(4) In accordance with the national strategic deployment of "One Belt One Road", China should encourage the excess capacity of steel, copper, alumina and primary aluminum enterprises to transfer to those countries or areas with abundant resources, high energy matching degree and relatively excellent infrastructure. Based on the national conditions, mining condition and geopolitics of the resources countries, we will gradually build steel, copper, aluminum and lead-zinc smelting bases, and potash processing and production bases, which will promote the excess capacity to transfer to the overseas orderly.(5) It is proposed to strengthen the planning and management of renewable resources recycling and to construct industrial base of renewable metal recycling.(6) China should promote the comprehensive development and utilization of paragenetic and associated mineral species to further improve the comprehensive utilization of bulk mineral resources.     

Study on the Global Carbon Assimilation System Based on Multisource Remote Sensing Data

The Paris agreement signed in April, 2016 aims to balance global anthropogenic carbon emissions and terrestrial carbon sinks by the middle of the 21^st century. To fulfill this goal, it is necessary to calculate carbon fluxes of different regions reliably. The global carbon assimilation system is an effective technique for achieving this goal. The Ministry of Science and Technology of China supports the project entitled as study on the global carbon assimilation system based on multisource remote sensing data through the national key research and development programs for global change and adaptation during the thirteen-five period. This project will develop synergic inversion techniques for retrieving key parameters of biological and atmospheric cycles and for assimilating multisource remote sensing and ground based data. Then, the high resolution global carbon assimilation system coupled with an ecological model will be constructed. This system is able to assimilate jointly multisource observation data and to optimize key model parameters, photosynthesis and respiration carbon fluxes of global terrestrial ecosystems, and anthropogenic carbon emission fluxes of key regions. This system will be used to study quantitatively the spatial and temporal patterns of carbon fluxes of global terrestrial ecosystems and anthropogenic carbon emission fluxes of key regions and to identify the mechanisms driving the global terrestrial carbon sinks and sources. The outputs of this study will be helpful for the fulfillment of the key research and development programs for global change and adaptation and provide valuable data and technical support for the decision-making in China.