C18键合硅胶柱在线富集/FIA-FAAS系统测定海水中痕量重金属

基于8-羟基喹啉金属螯合物在C_(18)键合硅胶上的吸附原理,在海水样品中加入少量8-羟基喹啉溶液,建立在线C_(18)键合硅胶柱富集,甲醇洗脱,洗脱液直接进入火焰的流动注射-火焰原子吸收光谱系统(FIA-FAAS)测定海水中痕量Cu,Ni,Cd和Zn的方法。富集倍数达80,进样频率为每小时30次。对Cu Ni,Cd和Zn测定的特征浓度分别为0.30,0.26,0.12和0.07μg/L;检出限(2σ)分别为0.07,0.05,0.02和0.01μg/L;相对标准偏差分别为2.7,2.1,2.8和2.5％;回收率分别为102,98,96和102％。本法快速简便,污染少,灵敏度高。     

1993年世界气候概况

１９９３年,是世界异常气候事件突出的年份。美国东部春季的“世纪暴风雪”,中西部夏季的特大洪水,日本和中国黄淮,江淮地区罕见的“低温”凉夏,巴西东北,澳大利亚东部严重的干旱,大西洋加勒比海地区猛烈的飓风以及西欧秋冬的洪水……,种种异常天气气候事件,多与热带太平洋１９９２年夏曾宣告结束,而１９９３年春再度发生,并持续至今的厄尔尼诺现象,以及中高纬地区年内多数朋份大气环流的经向型紧密相关。     

中国农业气象业务系统(CAgMSS)设计与实现

中国农业气象业务系统(CAgMSS)是基于C/S架构,研发的面向国家级和省级农业气象服务的业务工作平台,主要包括农业气象监测评价、作物产量预报、灾害监测评估、农用天气预报等子系统,是农业气象业务的基础性软件。系统融合现代信息技术和农业气象业务技术,实现了全部子系统数据管理、模型运算、产品制作等业务流程的一体化。系统采用大型关系型数据库规范了农业气象各类业务数据,基于插件技术集成各项业务功能,实现多元数据、多指标、多模型在农业气象监测、评价、预报等领域的综合应用,提高了农业气象产品的定量化、精细化、客观化水平。系统于2012年投入业务应用,基于该系统制作的农业气象情报、作物产量气象预报、农业气象灾害影响评估、关键农时农事气象保障等服务产品,在指导全国农业生产和防灾减灾中发挥了重要作用,明显提高了农业气象业务能力和业务工作效率。     

Effect of mesoscale internal structure on effective thermal conductivity of anisotropic geomaterials

Acta Geotechnica - Geomaterials tend to be stratified due to the geological process, and their properties are often anisotropic. In this study, the quartet structure generation set (QSGS) method is...     

Newly recorded bloom-forming dinoflagellate Gymnodinium impudicum in Haizhou Bay,Yellow Sea,China

Journal of Oceanology and Limnology - With the development of industrialization and aquaculture in Jiangsu and Shandong Provinces along the South Yellow Sea coast, China, eutrophication has greatly...     

安徽西湾铅锌矿床闪锌矿原位微量元素组成及成矿流体特征

安徽西湾铅锌矿床位于长江中下游成矿带庐枞矿集区北部,是近年来在该地区发现的首个赋存于三叠系周冲村组碳酸盐地层中的大型隐伏铅锌矿床,目前该矿床的成矿流体演化及矿床成因研究较为薄弱,制约了该地区铅锌矿床成矿理论与地质勘探。文章根据矿床地质特征,结合镜下鉴定,认为矿床中硫化物主要形成于石英碳酸盐硫化物阶段及碳酸盐硫化物阶段。闪锌矿原位微量元素分析和包裹体测温数据显示,石英碳酸盐硫化物阶段闪锌矿Fe、Mn含量相对较高,Ga、Ge、Cd含量相对较低,该阶段闪锌矿的均一温度为207～236℃,流体盐度w(NaCl_eq)范围为7.45%～11.81%;碳酸盐硫化物阶段的闪锌矿相对贫Fe和Mn,Cd、Ga和Ge含量相对较高,其闪锌矿均一温度为164～189℃,流体盐度w(NaCl_eq)为0.88%～5.56%。此外,西湾矿床西南部的样品以石英碳酸盐硫化物阶段的闪锌矿为主,而东北部的样品以碳酸盐硫化物阶段为主,流体包裹体均一温度结果表明矿床成矿温度从西南(183～240℃)向东北方向呈降低趋势(160～209℃),说明成矿流体由西南向东北方向移动。西湾矿床闪锌...     

北山地区古元古界北山岩群中长英质脉内锆石U- Pb年龄及其地质意义

深熔作用是大陆地壳分异、元素迁移富集的重要地质过程。位于中亚造山带南缘的北山地区,笔者等对前寒武系北山岩群进行了研究,结果表明该岩群普遍经历了角闪岩相变质及深熔作用,长英质浅色脉体分布广泛,却鲜有文献报道。绵山地区出露的古元古代北山岩群斜长角闪岩及相关的长英质浅色脉体的野外地质特征、相互关系共同指示了北山岩群变质地层经历了部分熔融,熔体在原地分凝聚积。锆石LA- ICP- MS U- Pb 测定结果表明,顺北山岩群变质地层片理产出的长英质浅色脉体锆石n(206Pb)/n(238U)加权平均年龄约为370 Ma,表明深熔作用发生时间为晚泥盆世; 一测点的n(207Pb)/n(206Pb)年龄为1623±12 Ma,与前人报道的北山岩群测年结果高度相近,虽此年龄值不足为证,但结合产出特征,可能指示长英质浅色脉体的源岩为北山岩群。此外,北山岩群中深熔作用普遍发育,露头可见大量的石榴子石、电气石、云母类矿物,指示区内部分稀有元素成矿潜力巨大。     

Analysis of water vapor characteristics in snowstorm process on the northern slope of Tianshan Mountains北大核心CSCD

Based on the daily precipitation data of 16 national meteorological observation stations on the north⁃ ern slope of Tianshan Mountains from 2000 to 2020（September to April the following year）,28 blizzard weath⁃ er processes were screened out. Then NCEP/NCAR reanalysis data and HYSPLIT model were used to simulate backward tracking of the water vapor during the snowstorm,analysis of the circulation background of the snow⁃ storm process on the northern slope of the Tianshan Mountains,as well as the main sources and transport of wa⁃ ter vapor and its contribution to the snowstorm. The research showed that the snowstorm area in the northern slope of the Tianshan Mountains was located on the right side of the axis of the southwest jet at 300 hPa high,the southwest airflow in front of the West Siberia trough at 500 hPa,the front convergence of the exit area of the southwest jet at low level at 700 hPa,and the convergence area of water vapor flux divergence and the overlap near the ground cold front area. The water vapor affecting the blizzard on the northern slope of the Tianshan Mountains mainly came from the Mediterranean Sea,the Black Sea and its vicinity,Southwest Asia,Central Asia,the Atlantic Ocean and its coasts,as well as the 850 hPa water vapor in Europe and northern Xinjiang. The water vapor from North America and other places had a relatively small contribution to the blizzard;after each water vapor source reaches the key area with the westerly airflow,under suitable circulation conditions. It mainly entered the blizzard area along the westward（southwest）and the northwest paths. But there were some differences between the layers. Based on the above characteristics,the structure of the source and transport of wa⁃ ter vapor in the snowstorm process on the northern slope of the Tianshan Mountains was established and the char⁃ acteristics of vapor transport at various heights were revealed. © 2023 The Author(s).     

塔里木盆地北缘二叠纪巴立克立克组凝灰岩年代学、地球化学及构造意义

塔里木盆地北缘广泛分布的二叠纪火山岩,对于理解天山造山带晚古生代构造演化具有重要研究意义。本文以哈拉峻地区巴立克立克组凝灰岩为研究对象,开展了地球化学、年代学和Lu-Hf同位素研究,结果显示凝灰岩富硅(SiO₂=74.59％~76.18％)、富碱(Na₂O+K₂O=7.48％~7.79％)、低铝(Al₂O₃=13.80%~14.29%),属于钾玄质过铝质流纹岩类;具轻稀土元素富集、重稀土元素相对亏损的特征,具Eu弱正异常,相对富集Rb、Th等大离子亲石元素(LILE),亏损P、Nb、Ta、Ti等高场强元素(HFSE),Nb/Ta值平均为16.60,Sr/Y值平均为2.42,Mg^#值平均为34.71;LA-ICP-MS锆石U-Pb年代学分析结果显示巴立克立克组凝灰岩的结晶年龄为280.47±2.58 Ma,εHf(t)值为-0.73~2.12,二阶段模式年龄(t_DM2)为1 318~1 145 Ma。结合塔里木盆地北缘早二叠世的构造演化、岩浆活动及沉积分布等信息,指出巴立克立克组沉积于南天山洋壳向塔里木板块俯冲的板内裂谷盆地中,具非造山板内岩浆岩特征,可能为地幔柱作用背景下,岩石圈地幔底侵导致地壳物质部分熔融的产物,继承了壳源和幔源的双重源区特征。     

Prediction of shield jamming risk for double-shield TBM tunnels based on numerical samples and random forest classifier

Acta Geotechnica - Currently, various machine learning (ML) techniques have been developed to solve geotechnical engineering problems. However, the lack of representative field samples limits the...