Acidity of Aerosols during Winter Heavy Haze Events in Beijing and Gucheng,China

We investigated the acidity and concentrations of water-soluble ions in PM_2.5 aerosol samples collected from an urban site in Beijing and a rural site in Gucheng, Hebei Province from November 2016 to January 2017 to gain an insight into the formation of secondary inorganic species. The average SO₄^2–, NO₃^–, and NH₄⁺ concentrations were 8.3, 12.5, and 14.1 μg m^–3, respectively, at the urban site and 14.0, 14.2, and 24.2 μg m^–3, respectively, at the rural site. The nitrogen and sulfur oxidation ratios in urban Beijing were correlated with relative humidity (with correlation coefficient r = 0.79 and 0.67, respectively) and the aerosol loadings. Based on a parameterization model, we found that the rate constant of the heterogeneous reactions for SO₂ on polluted days was about 10 times higher than that on clear days, suggesting that the heterogeneous reactions in the aerosol water played an essential role in haze events. The ISORROPIA II model was used to predict the aerosol pH, which had a mean (range) of 5.0 (4.9–5.2) and 5.3 (4.6–6.3) at the urban and rural site, respectively. Under the conditions with this predicted pH value, oxidation by dissolved NO₂ and the hydrolysis of N₂O₅ may be the major heterogeneous reactions forming SO₄^2– and NO₃^– in haze. We also analyzed the sensitivity of the aerosol pH to changes in the concentrations of SO₄^2–, NO₃^–, and NH₄⁺ under haze conditions. The aerosol pH was more sensitive to the SO₄^2– and NH₄⁺ concentrations with opposing trends, than to the NO₃^– concentrations. The sensitivity of the pH was relatively weak overall, which was attributed to the buffering effect of NH₃ partitioning.     

Sensitivity of carbon budget to historical climate variability and atmospheric CO2 concentration in temperate grassland ecosystems in China

Chinese temperate grasslands play an important role in the terrestrial carbon cycle. Based on the parameterization and validation of Terrestrial Ecosystem Model (TEM, Version 5.0), we analyzed the carbon budgets of Chinese temperate grasslands and their responses to historical atmospheric CO₂ concentration and climate variability during 1951–2007. The results indicated that Chinese temperate grassland acted as a slight carbon sink with annual mean value of 7.3 T?g C, ranging from -80.5 to 79.6 T?g C yr^-1. Our sensitivity experiments further revealed that precipitation variability was the primary factor for decreasing carbon storage. CO₂ fertilization may increase the carbon storage (1.4 %) but cannot offset the proportion caused by climate variability (-15.3 %). Impacts of CO₂ concentration, temperature and precipitation variability on Chinese temperate grassland cannot be simply explained by the sum of the individual effects. Interactions among them increased total carbon storage of 56.6 T?g C which 14.2 T?g C was stored in vegetation and 42.4 T?g C was stored in soil. Besides, different grassland types had different responses to climate change and CO₂ concentration. NPP and R_H of the desert and forest steppes were more sensitive to precipitation variability than temperature variability while the typical steppe responded to temperature variability more sensitively than the desert and forest steppes.     

小波分析在高边坡水平位移异常值探测中的应用研究

在测量工作中由于仪器误差等因素引起的粗差不可避免,针对粗差会导致数据中出现异常值这一问题^[1],本文以某一高边坡为研究对象,通过小波分析方法,利用MATLAB软件中的小波工具箱对某一高边坡水平位移监测成果进行异常值的探测。研究结果表明：针对某一高边坡的模拟增加粗差,进一步用小波分析方法对异常值探测,通过原始信号的差分信号可以看到剧烈波动点,有效地完成了对水平位移异常值的探测。     

基于地理探测器的合肥市热岛效应影响因素分析

地表温度是城市热岛效应的重要指标。本文利用合肥市2018年4月10日的Landsat-8 OLI影像数据,经过预处理后,采用大气校正法反演地表辐射温度,并提取研究区域的归一化差分植被指数(NDVI)、归一化差分水体指数(NDWI)。通过地理探测器模型,探测地表温度和海拔、NDVI、NDWI等因子之间的影响关系。结果表明：合肥市存在热岛效应。通过分析地理探测器模型的探测结果可知：从单一因子探测角度分析,影响合肥市地表温度的主导因子为NDVI和NDWI;从两因子交互作用影响角度分析,NDVI对因子交互作用的影响最强。研究结果有利于分析合肥市热岛效应的影响因素,为城市规划、生态环境保护提供科学依据。     

武汉东湖不同营养型子湖的水生生物与水域功能

于１９９１－１９９３年研究了武汉东湖４个营养型不同的子湖中水生生物与水域功能,表明各子湖之间各类水生生物的生态特征存在明显差异,茶港湾的ＨＢＣ和ＦＣ的数量,藻类的细胞密度和初级生产量,浮游动物和底栖动物的个体密度等均居４个子湖之首,其水质已达到了超富营养水平,将该湖区的作为污水天然净化区进行管理,可望对东湖的主体湖区起到缓冲和保护作用,郭郑湖的水质状况仅次于茶港湾湖区,处于富营养阶段,该湖区多项生     

多时相Sentinel-1A InSAR的连盐高铁沉降监测分析

多时相InSAR技术具有探测大范围毫米级地表形变的能力,已被广泛应用于地面沉降监测.近几年,应用多时相InSAR技术监测以高铁为代表的大尺度人造线状地物形变备受关注.本文将C波段SAR数据用于高铁沿线路基形变监测,应用相位稳定性分析和改进的StaMPS技术来增加相干性点的密度和形变参数解算的稳定性.采用研究区时间跨度为...     

胶辽台隆金刚石原生矿多旋回成矿作用讨论

辽东复县和鲁西蒙阴金刚石原生矿带产于中朝准地台的胶辽台隆次级凸起与凹陷的衔接带。胶辽台隆自晚前寒武纪以来,经历了扬子、晚加里东、华力西、印支、燕山等构造岩浆旋回,并在地台多旋回升降运动中,由于地壳产生减薄和水平引张作用,使富镁铁橄榄岩浆沿岩石圈断裂反复上涌,充填于基底断裂和盖层断裂中,形成了金伯利岩管和岩脉。依此,金刚石的成矿作用可划分为4个旋回;前寒武纪成矿旋回;加里东成矿旋回;华力西成矿旋回;燕山成矿旋回,其中以晚加里东—华力西成矿旋回和燕山成矿旋回最为重要。     

The discovery of iron spheres with golden Ni−Fe core in deep-sea sediments

Recently, we collected several thousand cosmic spheres in deep-sea sediments from the Northern Pacific (lat. 7°–11°N, long. 158°–178°W). They include iron sphere (83%), sillicate spheres (15%), and glassy spheres (2%). 5.7% of the iron spheres has button-shaped structures containing Ni, Co, Cu, Cr, Au, etc. This discovery is of significance for the further investigation into the origin and formation mechanism of cosmic spheres.     

Elastic properties of the incommensurate phase of akermanite,Ca2MgSi2O7

The crystal structure of akermanite, Ca₂Mg-Si₂O₇, consists of mixed tetrahedral sheets formed by [MgO₄] tetrahedra and [Si₂O₇] groups interleaved along the c axis with Ca²⁺ ions in eight-fold coordination. Above 358 K, the structure is tetragonal , and below it is incommensurate with modulations parallel to [110] and . The elastic stiffness moduli, C ^ij of the incommensurate phase at room temperature were measured from wave velocities in the 20–75 MHz carrier frequency range by the ultrasonic phase comparison method using optically clear synthetic single crystal plates (3×3×2 mm) oriented parallel to (100), (001), (110) and (101) planes. The C _ij values (GPa) are: C ₁₁ 159.40, C ₃₃ 149.43, C ₄₄ 30.26, C ₆₆ 58.10, C ₁₂ 76.58 and C ₁₃ 57.80. In (010) and (001) planes, the compressional modulus, V ²(L) from the longitudinal wave, L is considerably larger than the shear moduli, V ²(T₁, T ₂) both from the in-plane and perpendicular-to-plane shear waves, T ₁ and T ₂. The relatively small values of the shear moduli indicate the ease of tetrahedral rotations in response to in-plane and perpendicular-to-plane shears and may provide preconditions for structural changes involving shear-type atomic movements.     

多旋翼微型无人机气象探测适用性分析

本文通过多种试验对多旋翼无人机搭载微型气象探测设备进行低空温湿度探测和数据传输进行了适用性分析。结果表明,采用433 MHz无线透传的数据通讯方式数据传输稳定性较好,选用的微型气象探测设备温湿度传感器通过了实验室计量检定,与百叶箱温湿度的对比观测中二者一致性较好;无人机在单纯悬停过程中,温湿度观测与对比观测设备误差较小,相关性较好;在低空连续飞行过程中,温湿度观测结果与探空仪观测结果具有较好的一致性(温度平均绝对误差0.84℃,相对湿度平均绝对误差4%),但存在温湿度小脉动变化无法捕捉的情况,可能与设备温湿度响应时间、通风防辐射罩结果、飞行速度等有关。