广西佛子冲矿田大冲花岗闪长岩锆石SHRIMP U-Pb定年及其地质意义

本文对佛子冲铅锌矿床北部早前认为的成矿花岗岩——大冲岩体进行了年代学研究,获得花岗闪长岩锆石SHRIMP U-Pb年龄为258.2±3.2 Ma(95%置信度,MSWD=0.59),证明大冲岩体形成时代不是原来认为的燕山早期,而是属于海西期。同时结合区域上海西期岩体不成矿的认识和矿床地质特征,本文认为成矿岩体不是大冲岩体,而是燕山期花岗斑岩群,它们和铅锌矿化一起明显受到牛卫断层系统控制。     

Sequential assimilation in the wind wave model for simulations of typhoon events around Taiwan Island

We investigate the effect of data assimilation in the Wind Wave Model (WWM, Hsu et al., 2005) for wind wave simulations of typhoon events using an Optimal Interpolation (OI) method in the coastal waters of Taiwan. The main point of the present study is that the assimilation is conducted for typhoon events with short-time periods around an island. Five real typhoon events were used for numerical assimilation experiments with different combinations of the key parameters: the correlation length, the ratio of the errors between the observation and the prediction, and the number of measuring stations. The retrieved wind velocity is obtained using the wave energy growth curve computed from the WWM. The wave energy dissipation function suggested by Makin and Kudryavtsev (1999) was adopted in the data assimilation. This study shows that assimilation can improve the initial performance of the wave model, but it becomes insignificant after about 12 h. In summary, the OI approach is shown to be a reliable assimilation scheme for the WWM applied to typhoon events in the coastal waters of Taiwan Island.     

桂东北海洋山岩体锆石SHRIMP U-Pb定年和地球化学研究

桂东北海洋山岩体为岩性单一的二长花岗岩岩基。锆石SHRIMP U-Pb定年显示海洋山岩体主结晶年龄为431±7 Ma(MSWD=3.14),与赣湘桂内陆加里东期花岗闪长岩-二长花岗岩形成时代相似,为同一期成岩事件的产物。元素地球化学研究表明,绝大多数样品具有富硅(～68%),富钾(K2O/Na2O>1.5),弱过铝质(A/CNK均值1.05)和低Al2O3/TiO2值(<100)、高CaO/Na2O值(>0.3)的特征。与临区浅变质基底一致的εNd(t)值(-8.0～-8.6)和T2DM值(1.82～1.87 Ga),指示其理想源区为成熟度较低的古老变质杂砂岩。进一步的宏观地质特征和华南加里东造山带构造演化序列分析表明,海洋山岩体属于陆壳改造型花岗岩,其形成的构造环境很可能为汇聚造山向非造山转化的后造山伸张环境。     

基于等离子体增强化学气相沉积技术的光电子器件多层抗反膜的设计和制作

针对光电子器件端面抗反镀膜的要求,研究了基于等离子体增强化学气相沉积(PECVD)技术的多层抗反膜的设计和制作.首先,对影响SiN_x折射率的因素进行了实验研究,确定了具有大折射率差的SiO₂/SiN_x材料的PECVD沉积条件.根据理论计算分析,设计了四层SiO₂/SiN_x抗反膜结构,能够在70 nm的波长范围内实现低于10^-4的反射率     

Characterizing the depositional settings for sedimentary organic matter distributions in the Lower Yangtze River-East China Sea Shelf System

Grain-size distributions, total organic carbon (TOC) and total nitrogen (TN) concentrations, and TOC/TN ratios (C/N) were analysed for surface sediments from the Lower Yangtze River-East China Sea (ECS) shelf system. Hierarchical cluster analysis of grain-size parameters (mode, mean, sorting, skewness and kurtosis) has been employed to characterize grain-size compositions. The results suggest there are five grain-size compositional types (type-I–V) that fingerprint distinct depositional conditions. In areas with high sedimentation rates, hydrological sorting preferentially enriches the fraction coarser than 6.4ø (12 μm) in shallow seafloor sediments (water depth<30 m) by transporting the finer fraction to the deeper seafloor (water depth>30 m), and thus forms grain-size compositional type-I (shallow) and type-II (deep). In the open shelf, where modern sediment supply is very limited, grain-size types-III–V are identified according to different winnowing intensity. Overall TOC contents significantly correlate with mud proportions, suggesting muddy sediments are the primary control on OM accumulation. However, de-association of terrestrial OM from fine sediments in the Estuary and the occurrence of presumably relict OM in the open shelf exert additional controls on OM dispersal and carbon cycling in the ECS. By considering geography, oceanography, sediment source, and the relation between sedimentation conditions and sedimentary OM distributions, we define six depositional settings: the lower river, the estuary, the coast, the offshore upwelling area, the erosional area, and the open shelf. These settings describe the sediment dispersal and associated organic matter cycling in the Lower Yangtze River-ECS shelf system.     

南岭地区加里东期花岗岩地球化学特征、岩石成因及含矿性评价

南岭地区加里东期花岗岩从岩石学上可划分为三类岩石组合,分别是石英(或英云)闪长岩-花岗闪长岩-二长花岗岩组合,以花岗闪长岩为主;花岗闪长岩-二长花岗岩组合,以二长花岗岩为主;二长花岗岩-二云母花岗岩组合,以二长花岗岩为主,分别对应于HSS型、HS型以及S型三种成因类型。地球化学上,这三类花岗岩大体上具有过铝,适度富碱(6.26%~8.06%),K2O>Na2O(比值多在1.5左右),不同程度地富集大离子亲石元素(Rb、Cs、Th、U)的共同特点。同位素组成上,三类花岗岩都表现出高ISr值和低εNd值的特性,而且εNd值还呈现出连续过渡的特征。岩石成因上,第三类花岗岩主要起源于纯陆壳变沉积岩的部分熔融;第一类花岗岩可能是壳源岩浆与幔源岩浆近等比例混合的产物;第二类花岗岩以壳源岩浆为主,但也混合了少量幔源岩浆。在含矿性评价方面,第三类岩体,尤其是越城岭、苗儿山岩体,具有较好的成钨潜力,在第二类彭公庙岩体南部和其他加里东岩体内部及接触带附近的断裂发育区,分别有一定的钨多金属矿的找矿空间。     

广西栗木锡铌钽矿田矿化花岗岩锆石SHRIMPU—Pb定年及其意义

栗木矿田是南岭地区典型的锡铌钽多金属矿田,成矿作用与花岗岩关系十分密切。本文通过锆石SHRIMPU—Pb法定年研究,获得栗木矿田水溪庙矿区的隐伏矿化花岗岩形成年龄为212．34±1．8Ma（98％可信度,MSWD=1．5）,与前人测得的老虎头矿区的云英岩化花岗岩中白云母的Ar-Ar坪年龄（214．1Ma）、金竹源花岗岩中蚀变白云母Ar-Ar坪年龄（212．4Ma）及金竹源和三个黄牛花岗岩体锆石SHRIMPU—Pb年龄（分别为214．0Ma和218-3Ma）在误差范围内一致。结合其它资料分析,我们认为栗木地区锡铌钽矿与花岗岩为印支期同-构造-岩浆活动的产物,建议在南岭地区下一步规划部署中应注意印支期成矿岩体和印支期锡多金属矿的寻找。     

桂东北越城岭—苗儿山地区印支期成矿作用：油麻岭和界牌矿区成矿花岗岩锆石U-Pb年龄和Hf同位素制约

提要：油麻岭和界牌矿床是越城岭—苗儿山地区两个钨多金属矿床,规模均达到中型,主要矿体均产在中细粒(斑状)二长花岗岩接触带附近矽卡岩和破碎带中。本研究利用LA-MC-ICP-MS微区原位测试技术,对油麻岭矿化花岗岩和界牌内接触带花岗岩中的锆石进行了U-Th-Pb和Hf同位素分析。结果显示,油麻岭矿化花岗岩锆石U-Pb年龄为（220±1）Ma（MSWD=0.035）,界牌内接触带花岗岩锆石U-Pb年龄为（215±1）Ma（MSWD=0.055）,间接指示越城岭—苗儿山地区存在印支期成矿作用。油麻岭花岗岩样品εHf(t)值在-2.47~-6.67,界牌花岗岩样品εHf(t)值在-3.52~-6.79,表明这两个矿区花岗岩都是源于地壳物质的重熔。与南岭地区其他成钨花岗岩比较,两者源区均具有高εHf(t)值特征,可能是较多εHf(t)值＞0的新元古代新生岛弧地壳组分加入引起的。本文获得及前人发表的印支期同位素年龄表明,桂北地区经历了较强的印支期成岩成矿事件,有较好的找矿前景,今后应注意区内印支期花岗岩出露区的勘查评价工作。     

Evolution of optical spectral index and variability properties of S5 0716+714

We analyze the spectral variability and spectral evolution in the optical energy region by using multiband (BVRI) optical observations of S5 0716+714 spanning 1994 to 2005. The spectrum hardens when the source becomes brighter, which is consistent with general BL Lac objects. The spectral evolution parameter implies that the spectral variability is small in optical bands over 10 years. A simple model representing the variability of a synchrotron component can explain the spectral changes. In addition, we em...     

Polycyclic aromatic hydrocarbons in surface sediments of the East China Sea and their relationship with carbonaceous materials

This study measured concentrations of polycyclic aromatic hydrocarbons (PAHs) in surface sediments in the East China Sea (ECS) to investigate possible sources and fate of PAHs. Total concentration of PAHs in the sediments of the ECS ranged from 22 to 244 ng g(-1), with the highest levels in the coastal area and outer shelf. The observed PAH results showed elevated levels in both inner and outer shelf areas, a finding that is different from predictions by an ocean circulation model, suggesting that terrestrial sources are important for PAH contaminations in the ECS, while sediment resuspension, tidal changes and lateral transport may be important in affecting the distribution of PAHs in the outer shelf. The distribution of PAHs in the surface sediments of the ECS is similar to the distribution of carbonaceous materials (e.g., particulate organic carbon and black carbon), suggesting that carbonaceous materials may strongly affect the distribution of PAHs.