全文获取类型
收费全文 | 7799篇 |
免费 | 1566篇 |
国内免费 | 2348篇 |
专业分类
测绘学 | 1154篇 |
大气科学 | 1139篇 |
地球物理 | 1522篇 |
地质学 | 4763篇 |
海洋学 | 1323篇 |
天文学 | 272篇 |
综合类 | 666篇 |
自然地理 | 874篇 |
出版年
2024年 | 41篇 |
2023年 | 146篇 |
2022年 | 393篇 |
2021年 | 506篇 |
2020年 | 453篇 |
2019年 | 484篇 |
2018年 | 469篇 |
2017年 | 416篇 |
2016年 | 442篇 |
2015年 | 489篇 |
2014年 | 480篇 |
2013年 | 585篇 |
2012年 | 584篇 |
2011年 | 625篇 |
2010年 | 593篇 |
2009年 | 532篇 |
2008年 | 569篇 |
2007年 | 455篇 |
2006年 | 439篇 |
2005年 | 372篇 |
2004年 | 316篇 |
2003年 | 338篇 |
2002年 | 411篇 |
2001年 | 354篇 |
2000年 | 263篇 |
1999年 | 217篇 |
1998年 | 141篇 |
1997年 | 106篇 |
1996年 | 72篇 |
1995年 | 80篇 |
1994年 | 79篇 |
1993年 | 68篇 |
1992年 | 39篇 |
1991年 | 31篇 |
1990年 | 24篇 |
1989年 | 15篇 |
1988年 | 19篇 |
1987年 | 10篇 |
1986年 | 15篇 |
1985年 | 15篇 |
1984年 | 8篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1979年 | 5篇 |
1958年 | 4篇 |
1957年 | 2篇 |
1954年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 265 毫秒
301.
Jason W. Stuckey Christopher Goodwin Jian Wang Louis A. Kaplan Prian Vidal-Esquivel Thomas P. BeebeJr. Donald L. Sparks 《Geochemical transactions》2018,19(1):6
Minerals constitute a primary ecosystem control on organic C decomposition in soils, and therefore on greenhouse gas fluxes to the atmosphere. Secondary minerals, in particular, Fe and Al (oxyhydr)oxides—collectively referred to as “oxides” hereafter—are prominent protectors of organic C against microbial decomposition through sorption and complexation reactions. However, the impacts of Mn oxides on organic C retention and lability in soils are poorly understood. Here we show that hydrous Mn oxide (HMO), a poorly crystalline δ-MnO2, has a greater maximum sorption capacity for dissolved organic matter (DOM) derived from a deciduous forest composite Oi, Oe, and Oa horizon leachate (“O horizon leachate” hereafter) than does goethite under acidic (pH 5) conditions. Nonetheless, goethite has a stronger sorption capacity for DOM at low initial C:(Mn or Fe) molar ratios compared to HMO, probably due to ligand exchange with carboxylate groups as revealed by attenuated total reflectance-Fourier transform infrared spectroscopy. X-ray photoelectron spectroscopy and scanning transmission X-ray microscopy–near-edge X-ray absorption fine structure spectroscopy coupled with Mn mass balance calculations reveal that DOM sorption onto HMO induces partial Mn reductive dissolution and Mn reduction of the residual HMO. X-ray photoelectron spectroscopy further shows increasing Mn(II) concentrations are correlated with increasing oxidized C (C=O) content (r = 0.78, P < 0.0006) on the DOM–HMO complexes. We posit that DOM is the more probable reductant of HMO, as Mn(II)-induced HMO dissolution does not alter the Mn speciation of the residual HMO at pH 5. At a lower C loading (2 × 102 μg C m?2), DOM desorption—assessed by 0.1 M NaH2PO4 extraction—is lower for HMO than for goethite, whereas the extent of desorption is the same at a higher C loading (4 × 102 μg C m?2). No significant differences are observed in the impacts of HMO and goethite on the biodegradability of the DOM remaining in solution after DOM sorption reaches steady state. Overall, HMO shows a relatively strong capacity to sorb DOM and resist phosphate-induced desorption, but DOM–HMO complexes may be more vulnerable to reductive dissolution than DOM–goethite complexes. 相似文献
302.
四川盆地东部垫江凹陷三叠系嘉陵江组岩盐氯同位素特征与成钾指标研究 总被引:1,自引:0,他引:1
垫江凹陷位于四川盆地东部,是四川盆地三叠纪时期重要的成盐凹陷之一,但当时古卤水是否达到钾盐沉积阶段,是否具备形成海相钾盐的良好条件,一直存在争议。本文通过对垫江凹陷长平3井、高探1井和ZK001井嘉陵江组岩盐样品进行化学成分分析,以及对长平3井典型岩盐样品进行氯同位素分析来判断古卤水沉积阶段和成钾条件。结果发现垫江凹陷三叠系嘉陵江组岩盐δ37 Cl值均为负值,均小于-0.32‰,最低达到-1.18‰,绝大部分岩盐样品溴氯系数大于0.31,有很大一部分样品溴氯系数超过0.45,进一步表明垫江凹陷在嘉陵江期古卤水浓缩已达到钾石盐析出阶段,与岩盐包裹体成分分析结果一致。综合气候-物源-构造因素,认为垫江凹陷三叠纪嘉陵江期气候条件炎热,物质来源丰富,存在次级凹陷,古构造条件优越,具备良好的成钾潜力。 相似文献
303.
Qing-Bin Guan Bin Wang Xiong Wang Xing-An Wang Qiang Shi 《International Geology Review》2018,60(15):1883-1905
This study presents new zircon U–Pb geochronology, geochemistry, and zircon Hf isotopic data of volcanic and subvolcanic rocks that crop out in the Bayanhushuo area of the southern Great Xing’an Range (GXR) of NE China. These data provide insights into the tectonic evolution of this area during the late Mesozoic and constrain the evolution of the Mongol–Okhotsk Ocean. Combining these new ages with previously published data suggests that the late Mesozoic volcanism occurred in two distinct episodes: Early–Middle Jurassic (176–173 Ma) and Late Jurassic–Early Cretaceous (151–138 Ma). The Early–Middle Jurassic dacite porphyry belongs to high-K calc-alkaline series, showing the features of I-type igneous rock. This unit has zircon εHf(t) values from +4.06 to +11.62 that yield two-stage model ages (TDM2) from 959 to 481 Ma. The geochemistry of the dacite porphyry is indicative of formation in a volcanic arc tectonic setting, and it is derived from a primary magma generated by the partial melting of juvenile mafic crustal material. The Late Jurassic–Early Cretaceous volcanic rocks belong to high-K calc-alkaline or shoshonite series and have A2-type affinities. These volcanics have εHf(t) and TDM2 values from +5.00 to +8.93 and from 879 to 627 Ma, respectively. The geochemistry of these Late Jurassic–Early Cretaceous volcanic rocks is indicative of formation in a post-collisional extensional environment, and they formed from primary magmas generated by the partial melting of juvenile mafic lower crust. The discovery of late Mesozoic volcanic and subvolcanic rocks within the southern GXR indicates that this region was in volcanic arc and extensional tectonic settings during the Early–Middle Jurassic and the Late Jurassic–Early Cretaceous, respectively. This indicates that the Mongol–Okhotsk oceanic plate was undergoing subduction during the Early–Middle Jurassic, and this ocean adjacent to the GXR may have closed by the Late Middle Jurassic–Early Late Jurassic. 相似文献
304.
冻融循环对不同孔隙率页岩相似材料影响的试验研究 总被引:2,自引:2,他引:0
基于地质力学模型试验的相似理论,针对寒区岩体工程,分别制作了5种不同孔隙率的页岩相似材料,进行冻融循环试验,探究不同孔隙率的页岩相似材料在冻融前后,其主要物理力学参数的变化规律。试验研究表明:在冻融循环后,页岩相似材料的单轴抗压强度、三轴抗压强度、弹性模量、粘聚力、内摩擦角有不同程度的减小,孔隙率、泊松比有不同程度的增大。页岩相似材料的物理力学参数受冻融循环的影响随孔隙率的增大先增大后减小,孔隙率处于9.4%~13.6%时,受冻融循环影响最大;孔隙率处于5.8%~9.4%时,受冻融循环的影响随孔隙率的增大有增大的趋势;孔隙率处于13.9%~19.1%时,受冻融循环的影响随孔隙率的增大有减小的趋势。研究结果可以为西部寒区的岩土工程建设和减灾提供相关的科学依据。 相似文献
305.
306.
YML铁矿区位于几内亚福雷卡里亚省,富铁矿以条带状赤铁矿和铁角砾岩矿为主。矿区内共发育7条矿体,条带状赤铁矿体6条,铁角砾岩矿体1条。条带状赤铁矿体赋存部位多为向形地段,次级紧密褶皱发育,沿走向和倾向有逐渐变薄和尖灭的趋势;铁角砾岩矿体覆盖于地表,以风化壳的形式出现。矿床类型属复合类型,即海底热液喷气沉积叠加后期构造变质型+风化淋滤型。该区具备铁矿形成和保存的地质条件,且已发现具一定储量、品位较高的条带状赤铁矿和大面积的铁角砾岩分布区,区内铁矿找矿远景较好。 相似文献
307.
30~#矿权区位于菲律宾迪纳加特岛北部,区内发育有红土型镍矿床。本次勘查圈定4处矿(化)体,其中以Ⅰ、Ⅱ、Ⅲ矿(化)体的矿化范围较大,厚度变化系数为45%~50%(相对稳定),经济价值较高。红土型镍矿体平面上呈地毯状展布于地表,厚度受地形控制,富镍矿体分布于矿权区东部的5、6、11、12小区;剖面上从地表向深部矿体为铁质红土层、松散红土层及高岭土化蛇纹石化橄榄岩层。30~#矿权区红土镍矿矿床的形成经历了从普通矿到富矿两个阶段,红土镍矿石属于酸性矿石。 相似文献
308.
In the Mikengshan-Yanbei area, a special region for the tin mineralization in South China, there are some Yanshanian granites and porphyries and associated porphyry tin deposits (e.g., Yanbei). Although the tin mineralization is closely associated with the granitoids magmatism, the age and petrogenesis of the granites remain controversial. The Mikengshan pluton, which intrudes into the rhyolitic tuff and pyroclastic rocks of the Upper Jurassic Jilongzhang Formation, is the largest one in Mikengshan-Yanbei area and mainly consists of K-feldspar bearing granites. In this study, we report new age and geochemical data for the Mikengshan K-feldspar bearing granites. LA-ICP-MS zircon U-Pb age dating shows that they were generated in the Early Cretaceous (~138 Ma). They have high SiO2 (74.42% to 76.69%), low Al2O3 (12.39% to 13.49%) and Mg# (11 to 19), and negative Eu, Sr and Ba anomalies, and are rich in potassium (most K2O/Na2O=1.37 to 1.94) and high field strength elements (HFSEs), and are weakly peraluminous (A/CNK=1.03 to 1.1) with high 10000×Ga/Al ratios (3.46 to 4.96) and slightly high zircon saturation temperatures (807 ℃ to 817 ℃), showing the characteristics of the typical A-type granites. Moreover, they have high Rb contents 842×10-6 to 1295×10-6, Rb/Sr (90 to 255) ratios and show rare earth elements (REE) tetrad effect, which are similar to those of high fractionated granites. Thus, we suggested that the Mikengshan K-feldspar bearing granites are high fractionated and aluminous A-type granite. Their slightly high εNd(t) values (-3.4 to -4.6) indicate that the mantle components should have played a role during their formation. Taking into account regional igneous rocks and tectonic setting data, we suggest that the Mikengshan K-bearing granites were formed in an extensional setting, which was probably related to the roll-back of the subducted Paleo-Pacific plate. © 2018, Science Press. All right reserved. 相似文献
309.
对川西南荥经坳陷内三口页岩气井尤其是川荥页1井奥陶系开展了系统的岩心观察和分析。三口钻井在梁山组之下均发育十余米厚的灰黑色泥岩,其中川荥页1井灰黑色泥岩厚近16m。沉积相分析认为灰黑色泥岩为浅水陆棚相,泥岩之下发育的大套砂岩为滨岸近滨亚相,总体向上海水逐渐变深。砂岩中发育丰富的沉积软变形构造及波状交错层理、浪成沙纹层理、平行层理、斜层理等构造。川荥页1井上部泥岩中见大量三叶虫、笔石和腕足等化石及其碎片,鉴定表明含有代表中下奥陶统的常见生物分子,如对笔石(Didymograotus sp.)、大洪山虫(Taihungshania sp.)等。该套砂泥岩组合在沉积相及古生物化石等方面明显区别于荥经坳陷周缘奥陶系五峰组—志留系龙马溪组,与研究区及邻区中下奥陶统红石崖组、湄潭组、大湾组、大官山组中段等层位相当。 相似文献
310.