Free radical scavenging abilities of polypeptide from Chlamys farreri

1 INTRODUCTION Active oxygen free radicals can damage cell structure, even kill the cells, causing aging and cer- tain serious diseases (Bors et al., 1989). Usually, the production and scavenging of active oxygen free radicals are in balance in healthy hu…     

南极威尔克斯地SGR钻孔处雪冰转化过程中的密度变化特征

本文着重描述了SGR钻孔处冰盖上的积雪在密实化过程中的特征变化,并对该过程进行了分段的和全面的回归分析.结果表明,冰盖密度随深度增大,但增长幅度随深度减小.作者提出密度变化减小度的概念.计算得出的所研究冰芯钻取点的密度变化减小度为-0.15kg/m~3·m~2,粒雪成冰前的密实速率平均值为4.08kg/m~3·a.本文得到的冰盖密度变化“临界点”与以往报道的有所不同.分析这一现象时,作者强调当积雪还在活动层时冰盖温度的影响,并以此解释密度剖面的异常变化以及离差的回升.特别指出,积雪的密度变化具有气候学意义,它在一定程度上能够反映出积雪形成及变化过程中气候变化的某些信息.本文由密度变化确定的钻孔点雪冰转化深度为50米.     

Time scale of an early to mid-Paleozoic orogenic cycle of the long-lived Central Asian Orogenic Belt, Inner Mongolia of China: Implications for continental growth

We present a detailed, new time scale for an orogenic cycle (oceanic accretion–subduction–collision) that provides significant insights into Paleozoic continental growth processes in the southeastern segment of the long-lived Central Asian Orogenic Belt (CAOB). The most prominent tectonic feature in Inner Mongolia is the association of paired orogens. A southern orogen forms a typical arc-trench complex, in which a supra-subduction zone ophiolite records successive phases during its life cycle: birth (ca. 497–477 Ma), when the ocean floor of the ophiolite was formed; (2) youth (ca. 473–470 Ma), characterized by mantle wedge magmatism; (3) shortly after maturity (ca. 461–450 Ma), high-Mg adakite and adakite were produced by slab melting and subsequent interaction of the melt with the mantle wedge; (4) death, caused by subduction of a ridge crest (ca. 451–434 Ma) and by ridge collision with the ophiolite (ca. 428–423 Ma). The evolution of the magmatic arc exhibits three major coherent phases: arc volcanism (ca. 488–444 Ma); adakite plutonism (ca. 448–438 Ma) and collision (ca. 419–415 Ma) of the arc with a passive continental margin. The northern orogen, a product of ridge-trench interaction, evolved progressively from coeval generation of near-trench plutons (ca. 498–461 Ma) and juvenile arc crust (ca. 484–469 Ma), to ridge subduction (ca. 440–434 Ma), microcontinent accretion (ca. 430–420 Ma), and finally to forearc formation. The paired orogens followed a consistent progression from ocean floor subduction/arc formation (ca. 500–438 Ma), ridge subduction (ca. 451–434 Ma) to microcontinent accretion/collision (ca. 430–415 Ma); ridge subduction records the turning point that transformed oceanic lithosphere into continental crust. The recognition of this orogenic cycle followed by Permian–early Triassic terminal collision of the CAOB provides compelling evidence for episodic continental growth.     

纺织品中偶氮染料还原液内芳香胺的电喷雾电离质谱分析

在优化的条件下,用电喷雾电离质谱(ESI-MS)检测了多种纺织品中由偶氮染料还原获得的芳香胺。当毛细管温度为100℃、鞘气流速为25单位、进样流速为10μL/min、电压为5kV时,信号的总离子流强度高且较稳定。实验分析了19种致癌芳香胺标准溶液的二级质谱,获得了相应物质的特征碎片离子;在此基础上,建立了基于ESI-MS对毛巾、棉布等样品中芳香胺进行快速定性分析的方法,具有灵敏度高、特异性好、检测速度快等优点。     

土壤中氟的形态分析

以宁夏盐池地区高氟土壤为例,采用连续提取法对土壤样品中各形态氟进行提取,离子色谱法测定各形态氟的含量。根据研究目的及土壤特点将氟的形态划分为水溶态、离子交换态、可还原态、可氧化态及残渣态5种形态;对各种形态连续提取过程中使用的提取液进行了选择。采用建立的方法获得提取土壤中F-的检出限为0.76μg/g;方法精密度(RSD,n=7)各形态氟为水溶态氟11.3%,离子交换态氟13.5%,可还原态氟10.7%,可氧化态氟8.9%。     

柴达木盆地北缘侏罗系不同沉积环境烃源岩生物标志物特征及其应用

柴达木盆地北缘地区侏罗系(中下侏罗统)的优质烃源岩主要发育于湖相与三角洲相环境。研究了不同时代、不同沉积环境中烃源岩的生物标志物组成特征,结果发现,有3类化合物的分布与组成差异显著,包括三环萜烷(C19、C20、C21)的分布型式、重排藿烷的丰度以及规则甾烷的相对组成。其中,不同时代的差异主要体现在规则甾烷组成上;而不同沉积环境的差异主要体现为三环萜烷(C19、C20、C21)的分布型式及重排藿烷的丰度。分析认为,这些差异与烃源岩的沉积环境及其生源组成有密切关系。据此,初步将这些参数应用于两方面研究,一是为划分地层沉积环境提供“生物标志物相标志”,二是研究油源对比,取得良好效果。因此,本文研究结果具有重要实用价值与参考意义。     

He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.     

Urban consolidation and house prices: a case study of Melbourne 1990–2004

This paper explores the links between a strategic policy, urban consolidation, and house prices by examining the changes in the mix of housing and in house price for the period 1991–2004. We contend that urban consolidation could be seen as a source of additional supply, (which might be expected to be felt in lower prices and so contribute to a local policy objective) but also as a stimulus to demand (by developers who could bid up the price of lots where it was understood more housing could be built). Analyses were carried out at the metropolitan and sub-regional scales using correlation tests. The research finds very weak statistical connections, and concludes that this policy has not been associated with price changes.     

渤海湾盆地新生界生油岩系底界面温度分布

依据渤海湾盆地2000余口测温井的地温梯度数据、地层岩性描述、分层数据以及钻井资料,计算了该盆地各生油岩系底界面的温度。统计结果表明:渤海湾盆地沙河街组大部分凹陷区地层底界面温度介于90℃至150℃,目前仍具有大量生油的温度条件,而在隆起或一些凸起地区,该地层组段温度普遍小于90℃,未能达到生油的温度指标。东营组和孔店组地层也仍具有一定的生油温度条件。研究还表明:地层温度与地层界面埋深密切相关,温度随界面埋深的增大而升高,沉积厚度大的凹陷区地层界面温度大于沉积厚度小的凸起区或斜坡地带,说明地层界面埋深是决定地温高低的主要控制因素,而地温梯度对地层界面温度的影响相对较小。