用X射线荧光光谱法测定Cl、S等31个元素

采用硼酸镶边垫底的粉末样品压片制样,用ARL ADVANT′XP＋型X射线荧光光谱仪对土壤和水系沉积物样品中Na、Mg、Al、Si、P、S、Cl等31个组分进行测定。重点研究了Cl和S等元素的测定条件、痕量元素的背景选择和谱线重叠校正问题。使用经验系数法和康普敦散射作内标校正基体效应。经标准物质校验,结果与标准值吻合。方法的检出限、精密度和准确度能满足多目标地球化学调查样品的分析要求。     

探地雷达在吉林西部地区探测土壤碱化层

吉林西部盐碱地区的探地雷达调查表明,盐碱地与耕地土的雷达回波具有明显差别,根据振幅的衰减特征可以精确区分耕地与盐碱地,根据频谱中高频峰值与土壤有机质含量的相关性可定性评价土壤的盐碱化程度.在雷达瞬时振幅图上,可将盐碱地纵向剖面分为盐分积累带和过渡带.采用探地雷达方法可快速了解盐碱化程度在深度方向上的变化,适宜开展大面积地面调查.     

山东蒙山第四纪冰川、黄土、水系沉积物与MIS对比研究

为了确定山东蒙山佛塔谷一带的第四纪冰川、黄土、水系沉积物与MIS的对应关系,对该区冰川遗迹进行了详细调查,并对冰川、黄土和水系沉积物进行年代学研究。对比研究了蒙山地区各类地层沉积与深海氧同位素演化阶段的对应性,建立了冰川、黄土、水系沉积物与环境演化的内在关系;详细对比了全新世、晚更新世冰川、黄土、水系沉积物与MIS的关系,初步对比了中更新世冰川沉积物与MIS的关系,发现我国东部各类第四纪沉积物与MIS之间具有良好的对应关系,从沉积层序与环境演化的角度,确认了蒙山及我国东部地区存在第四纪冰川作用的事实。     

鸟粪石结晶法预处理垃圾渗滤液中高浓度氨氮的研究

利用鸟粪石结晶法预处理垃圾渗滤液中的高浓度氨氮,通过单因素实验和正交实验探讨了pH值、添加剂种类、添加剂比例、反应时间4个因素对氨氮去除率的影响,结合反应过程中的经济成本得出鸟粪石结晶法最佳工艺条件为:pH=9,添加剂为MgC12·6H2O和Na2HPO4·12H2O,n(Mg2+):n(NH4+):n(PO43-)=1:1:1,反应时间15min,氨氮去除率达到90.13%,剩余氨氮在300mg/L以下。通过XRD和ESEM分析,沉淀产物为鸟粪石。实验表明鸟粪石结晶法可以有效去除垃圾渗滤液中的高浓度氨氮,为后续使用生物法处理提供条件,也可以弥补矿物吸附法去除氨氮的不足。可将其与生物法、矿物吸附法等方法组合使用,综合处理垃圾渗滤液。     

The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

一种新型降水预报评分方法

在目前已有的降水评分办法的基础上，对原有办法存在的弊端进行了有效的改进，使得降水的预报评估与预报服务业务结合更紧密，也更贴近公众的感受。主要介绍了新方法的基本思路、关键技术、实现方法等。评分系统已投入业务运行，成为考核预报员业务水平的重要依据。     

尿素作为过冷云冰核的实验研究

早在1956年日本的佐野(I.Sano)等人用扩散型小云室测定尿素在-14℃能出现较多的冰晶。1966—1969年美国的诺林贝格(R.G.Knollenbeng)测定尿素的成冰阈温为-15℃,尿素溶液滴的平均冻结温度为-16.8℃,但他认为“局部冷却”效应将会提高尿素的成冰能力,即尿素高速溶于水时高度吸热冷却达低共熔点温度(-11.4℃)成冰,因而使尿素成为优良冰核。根据国外报导,自1966年开始,我国北方一些省气象局,经常用飞机播撒尿素催化过冷云降水,仅吉林省每年用于尿素的费用(不计飞机等其他花费)就可超过万元。因此,为能正确评价野外试验效果和权衡这个支出是否值得,本文下面介绍对尿素微粒成冰阈温、成冰活化比以及尿素饱和溶液滴冻结温度的实验测定,给出我国对尿素的鉴定结果,并对尿素可否作为优良的过冷云冰核提出看法。     

中国葡萄气候区划探讨

根据葡萄的生物学特性及其对气候条件的要求,在全国范围内选取８３个站点,按照９个农业气候指标,利用模糊聚类的数学方法,将全国划分为６个不同的葡萄气候区,并就各区的气候特点和品种选择作出分区评述。     

海水入侵水化学指标及侵染程度评价研究

选择Ｃｌ＾,Ｍ、Ｂｒ＾－,ｒＨＣＯ３／ｒＣｌ及ＳＡＲ５项水化学要素作为综合判断海水入侵的指标：染程度划分为４级;确定了各项指标入程度的等级范围。入侵程度的衡理采用模糊数学综合判模型。     

Characteristics of dry-wet abrupt alternation events in the middle and lower reaches of the Yangtze River Basin and the relationship with ENSO

During recent decades, more frequent flood-drought alternations have been seen in China as a result of global climate change and intensive human activities, which have significant implications on water and food security. To better identify the characteristics of flood-drought alternations, we proposed a modified dry-wet abrupt alternation index (DWAAI) and applied the new method in the middle and lower reaches of the Yangtze River Basin (YRB-ML) to analyze the long-term spatio-temporal characteristics of dry-wet abrupt alternation (DWAA) events based on the daily precipitation observations at 75 rainfall stations in summer from 1960 to 2015. We found that the DWAA events have been spreading in the study area with higher frequency and intensity since 1960. In particular, the DWAA events mainly occurred in May and June in the northwest of the YRB-ML, including Hanjiang River Basin, the middle reaches of the YRB, north of Dongting Lake and northwest of Poyang Lake. In addition, we also analyzed the impact of El Niño Southern Oscillation (ENSO) on DWAA events in the YRB-ML. The results showed that around 41.04% of DWAA events occurred during the declining stages of La Niña or within the subsequent 8 months after La Niña, which implies that La Niña events could be predictive signals of DWAA events. Besides, significant negative correlations have been found between the modified DWAAI values of all the rainfall stations and the sea surface temperature anomalies in the Nino3.4 region within the 6 months prior to the DWAA events, particularly for the Poyang Lake watershed and the middle reaches of the YRB. This study has significant implications on the flood and drought control and water resources management in the YRB-ML under the challenge of future climate change.