煤的变质程度对焦炭结构构造的影响

从宏观和微观两方面对不同变质程度煤所形成焦炭的结构、构造进行了深入研究。从气煤到肥煤阶段（Ｒｏ，ｍ：０．７７％～１．１６％），焦炭气孔壁厚度逐渐增大；进入焦煤阶段（Ｒｏ，ｍ＞１．１６％），焦炭气孔壁厚度降低。气煤、１３焦煤形成的焦炭结构以各向同性体为主，焦煤、肥煤炼出的焦炭以粒状镶嵌结构为主。由气煤和高变质程度的焦煤形成的焦炭，其气孔以微孔和大孔为主，气孔分布标准差Ｄｓ最大；肥煤炼出的焦炭，其气孔分布大小较均一；１３焦煤和低变质程度的焦煤成焦后，气孔分布状况介于上述二者之间     

Bristen granite: a highly differentiated,fluorite-bearing A-type granite from the Aar massif,Central Alps,Switzerland

Bristen granite is a body of fine-grained leucogranite occurring in the Gotthard rail base tunnel in the Central Alps. During construction of the tunnel, Bristen granite (Brgr) has been drilled along a 600 m long section. The aplite-granite belongs to the suite of Variscan granitoid intrusions of the Aar massif and contains a variety of accessory minerals typical of highly differentiated granites. Rock forming fluorite, partly enriched in yttrium (Y) and rare earth elements (REE), is intergrown with the late Y- and REE-bearing carbonate mineral synchysite. The granite contains a variety of Ti- and Y-REE-niobates, thorite, and zircon. Compared with the calc-alkaline central Aar granite (cAgr), Bristen granite is strongly depleted in Ti, P, Mg, Sr, and Ba and shows a remarkable enrichment in incompatible elements such as Rb, Th, U, Nb, Y, HREE and F. Bristen granite is the most evolved granitoid rock of the Aar massif. The composition of Brgr is typical of post-collisional reduced (ferroan) A-type granites. The Brgr melt formed in the lower crust and crystallized from a highly differentiated melt at the cotectic point in the quartz-feldspar system close to 100 MPa and 700 °C. The Brgr intruded as a small isolated stock pre-Variscan gneisses with sharply discordant contacts. The primary igneous host of Nb, Ta, Y, U, Th and REE is biotite in addition to minor amounts of allanite, and zircon. The presence of Y-REE-fluorite, synchysite, parisite and Y- and Ti-niobates and other REE-minerals can be related to reaction of igneous biotite and primary fluorite with hydrothermal fluids. The reaction is associated with alpine metamorphism, because Y-bearing fluorite and synchysite have been reported from Alpine fissures. The transformation of primary biotite to chlorite and muscovite released the heavy metal oxides under lower greenschist facies conditions that formed the Alpine diagnostic mineral stilpnomelane at about 300 °C.     

Chemical composition of rock-forming minerals and crystallization physicochemical conditions of the Middle Eocene I-type Haji Abad pluton,SW Buin-Zahra,Iran

The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe³⁺?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H₂O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent.     

Absorption properties of urban/suburban aerosols in China

The broadband diffuse radiation method is improved to retrieve the aerosol refractive index imaginary part （AIP） and broadband （400-1000 nm mean） single scattering albedo （SSA）. In this method, four sets of SSA selection criteria are proposed for quality control. The method is used to retrieve AIP, SSA and absorptive optical thickness （AbOT） from routine hourly-exposed pyrheliometer and paranometer measurements over 11 sites （meteorological observatories） in China during 1998-2003. Apart from one suburban site （Ejin Qi）, the other urban sites are all located around big or medium cities. As shown in the retrieval results, annual mean SSA during 1998-2003 changes from 0.941 （Wuhan） to 0.849 （Lanzhou）, and AIP from 0.0054 to 0.0203. The 11-site average annual mean SSA and AIP are 0.898 and 0.0119, respectively. SSA during winter is smaller for most sites. There is an evidently positive correlation between SSA and aerosol optical thickness （AOT） for all sites. There is also a positive correlation between SSA and relative humidity for most sites, but a negative correlation for a few sites, such as Kashi and ǚrǚmqi in Northwest China.     

How effective is the new generation of GPM satellite precipitation in characterizing the rainfall variability over Malaysia?

We investigated the potential of the new generation of satellite precipitation product from the Global Precipitation Mission (GPM) to characterize the rainfall in Malaysia. Most satellite precipitation products have limited ability to precisely characterize the high dynamic rainfall variation that occurred at both time and scale in this humid tropical region due to the coarse grid size to meet the physical condition of the smaller land size, sub-continent and islands. Prior to the status quo, an improved satellite precipitation was required to accurately measure the rainfall and its distribution. Subsequently, the newly released of GPM precipitation product at half-hourly and 0.1° resolution served an opportunity to anticipate the aforementioned conflict. Nevertheless, related evidence was not found and therefore, this study made an initiative to fill the gap. A total of 843 rain gauges over east (Borneo) and west Malaysia (Peninsular) were used to evaluate the rainfall the GPM rainfall data. The assessment covered all critical rainy seasons which associated with Asian Monsoon including northeast (Nov. - Feb.), southwest (May - Aug.) and their subsequent inter-monsoon period (Mar. - Apr. & Sep. - Oct.). The ability of GPM to provide quantitative rainfall estimates and qualitative spatial rainfall patterns were analysed. Our results showed that the GPM had good capacity to depict the spatial rainfall patterns in less heterogeneous rainfall patterns (Spearman’s correlation, 0.591 to 0.891) compared to the clustered one (r = 0.368 to 0.721). Rainfall intensity and spatial heterogeneity that is largely driven by seasonal monsoon has significant influence on GPM ability to resolve local rainfall patterns. In quantitative rainfall estimation, large errors can be primarily associated with the rainfall intensity increment. 77% of the error variation can be explained through rainfall intensity particularly the high intensity (> 35 mm d^-1). A strong relationship between GPM rainfall and error was found from heavy (~35 mm d^-1) to violent rain (160 mm d^-1). The output of this study provides reference regarding the performance of GPM data for respective hydrology studies in this region.     

东半球500hPa闭合低压系统的统计分析

通过分析５００ｈＰａ东半球闭合低压系统，研究其气候规律。低压活动次数有年际、月际、季际变化。低压活动于中高纬度带，主要集中于两大地区，第一区是西太平洋及大陆东岸，第二区是东欧地区。第一区中心夏季向西移到大陆上，强度增大，对中国气候有重要作用。低压中心高度值的频数分布是双峰型。低压生命期比阻塞高压还长些。强低压主要出现在大陆高纬地带和西太平洋。强发展的低压多数出现在西太平洋。亚洲低压移动路径有两条，一条从西西伯利亚北部到库页岛，一条从咸海东移到库页岛     

Climatic regime shift and decadal anomalous events in China

Climatic time series from historical documents and instrumental records from China showed temporal and regional patterns in the last two to three centuries, including two multidecadal oscillations at quasi-20-year and quasi-70-year timescales revealed by signal analysis from wavelet transform. Climatic anomalous events on the decadal timescale were identified based on the two oscillations when their positive (or negative) phases coincide with each other to amplify amplitude. The coldest event occurred in the decade of 1965–1975 in eastern China, while the periods of 1920–1930, 1940–1950, and 1988–2000 appeared to be warmer in most parts of China. For the precipitation series in northern China, the dry anomalous event was found in the late 1920s, while the wet anomalous event occurred in the 1950s. A severe drought in 1927–1929 in northern China coincided with the anomalous warm and dry decade, caused large-scale famine in nine provinces over northern China. Climatic anomalous events with a warm-dry or cold-wet association in the physical climate system would potentially cause severe negative impacts on natural ecosystem in the key vulnerable region over northern China. The spatial pattern of summer rainfall anomalies in the eastern China monsoon region showed an opposite variations in phase between the Yellow River Valley (North China) and the mid-low Yangtze River Valley as well as accompanied the shift of the northernmost monsoon boundary. Climatic regime shifts for different time points in the last 200 years were identified. In North China, transitions from dry to wet periods occurred around 1800, 1875, and 1940 while the transitions from wet to dry periods appeared around 1840, 1910, and the late 1970s. The reversal transition in these time points can also be found in the lower Yangtze River. Climatic regime shifts in China were linked to the interaction of mid- and low latitude atmospheric circulations (the westerly flow and the monsoon flow) when they cross the Tibetan Plateau in East Asia.     

气象卫星接收天线标校技术及应用

在过去的几十年中,我国气象事业的不断发展,中国风云气象卫星完成了从试验应用型向业务服务性的不断转型,因此对于卫星信号接收天线的可靠性和指向精度要求越来越高。目前用于接收风云系列极轨气象卫星下行信号的天线主要有12m和4.2m天线,其具有动态特性高、波束宽度窄等特点,因此需要在天线安装和运行期间对天线的轴系误差进行精确的标定和校准。本文在传统标校方法的基础上,提出了利用太阳进行的误差标校技术,进一步降低了标校环节的复杂程度,提高了标校精度。     

Atmospheric chemistry of hydrogen fluoride

Although a large volume of monitoring and computer simulation data exist for global coverage of HF, study of HF in the troposphere is still limited to industry whose primary interest is the safety and risk assessment of HF release because it is a toxic gas. There is very limited information on atmospheric chemistry, emission sources, and the behavior of HF in the environment. We provide a comprehensive review on the atmospheric chemistry of HF, modeling the reactions and transport of HF in the atmosphere, the removal processes in the vertical layer immediately adjacent to the surface (up to approximately 500 m) and recommend research needed to improve our understanding of atmospheric chemistry of HF in the troposphere. The atmospheric chemistry, emissions, and surface boundary layer transport of hydrogen fluoride (HF) are summarized. Although HF is known to be chemically reactive and highly soluble, both factors affect transport and removal in the atmosphere, the chemistry can be ignored when the HF concentration is at a sufficiently low level (e.g., 10 ppmv). At a low concentration, the capability for HF to react in the atmosphere is diminished and therefore the species can be mathematically treated as inert during the transport. At a sufficiently high concentration of HF (e.g., kg/s release rate and thousands of ppm), however, HF can go through a series of rigorous chemical reactions including polymerization, depolymerization, and reaction with water to form molecular complex. As such, the HF species cannot be considered as inert because the reactions could intimately influence the plume’s thermodynamic properties affecting the changes in plume temperature and density. The atmospheric residence time of HF was found to be less than four (4) days, and deposition (i.e., atmosphere to surface transport) is the dominant mechanism that controls the removal of HF and its oligomers from the atmosphere. The literature data on HF dry deposition velocity was relatively high compared to many commonly found atmospheric species such as ozone, sulfur dioxide, nitrogen oxides, etc. The global average of wet deposition velocity of HF was found to be zero based on one literature source. Uptake of HF by rain drops is limited by the acidity of the rain drops, and atmospheric particulate matter contributes negligibly to HF uptake. Finally, given that the reactivity of HF at a high release rate and elevated mole concentration cannot be ignored, it is important to incorporate the reaction chemistry in the near-field dispersion close to the proximity of the release source, and to incorporate the deposition mechanism in the far-field dispersion away from the release source. In other words, a hybrid computational scheme may be needed to address transport and atmospheric chemistry of HF in a range of applications. The model uncertainty will be limited by the precision of boundary layer parameterization and ability to accurately model the atmospheric turbulence.     

Multi-Source Emission Determination Using an Inverse-Dispersion Technique

Inverse-dispersion calculations can be used to infer atmospheric emission rates through a combination of downwind gas concentrations and dispersion model predictions. With multiple concentration sensors downwind of a compound source (whose component positions are known) it is possible to calculate the component emissions. With this in mind, a field experiment was conducted to examine the feasibility of such multi-source inferences, using four synthetic area sources and eight concentration sensors arranged in different configurations. Multi-source problems tend to be mathematically ill-conditioned, as expressed by the condition number κ. In our most successful configuration (average κ = 4.2) the total emissions from all sources were deduced to within 10% on average, while component emissions were deduced to within 50%. In our least successful configuration (average κ = 91) the total emissions were calculated to within only 50%, and component calculations were highly inaccurate. Our study indicates that the most accurate multi-source inferences will occur if each sensor is influenced by only a single source. A “progressive” layout is the next best: one sensor is positioned to “see” only one source, the next sensor is placed to see the first source and another, a third sensor is placed to see the previous two plus a third, and so on. When it is not possible to isolate any sources κ is large and the accuracy of a multi-source inference is doubtful.