辽西地区构造演化与盆地成因类型研究

辽宁省西部地区发育了一系列中生代小型含煤盆地。这些盆地内有广泛的油气显示,但勘探效果却不理想。本文分析了辽西地区地球动力学背景,结合地球物理勘探资料研究了辽西地区盆地构造几何学和运动学特征,探讨了辽西地区构造演化史、盆地形成机制和成因类型,并以阜新盆地为例,阐述了盆地的构造特征和圈闭类型。      

Geochemistry of Thermal－Mineral Waters in Siping＇an District， Shanxi Province， China

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A study of the factors influencing the occurrence of landslides in the Wushan area

Due to the complex natural geological conditions, many slope-related geological hazards occur in the Three Gorges Reservoir area in China. This study focuses on the characteristics of landslide development and their underlying mechanisms in this area. A statistical analysis is conducted to determine the characteristics of landslide development in the Wushan area, including the landslide distribution as a function of the elevation, slope, landslide material composition, scale, lithology, boundary conditions, instability mechanism, stratigraphic age, attitude, and sliding direction. The mechanisms of slope instability and the effect on the occurrence of landslides are analyzed. This study provides important reference material for landslide research in the Three Gorges Reservoir area and similar stratigraphic areas.     

吉林省新华龙钼矿床流体包裹体

新华龙钼矿床位于中国东北地区吉林省东部,是一个新发现的斑岩型钼矿床。矿床产于花岗闪长斑岩中。矿床成矿阶段包括石英-浸染状辉钼矿、石英-网脉状辉钼矿、石英-黄铁矿-黄铜矿、石英-多金属硫化物和石英-碳酸盐化5个阶段。流体包裹体实验结果表明：流体包裹体的类型主要为气液两相包裹体,其次为纯气相和纯液相包裹体,还有少量含子矿物的多相包裹体。流体包裹体的均一温度为172～385 ℃,盐度(w(NaCl))为8.51%～45.44%。从早阶段到晚阶段成矿流体温度具有规律的演化,均一温度分别为360～390 ℃、270～350 ℃、250～260 ℃、220～230 ℃、170～190 ℃。其中:含子矿物多相包裹体均一温度为272～385 ℃,盐度为35.79％～45.44％,密度为1.07～1.08 g/cm³;气液两相包裹体均一温度为172～381 ℃,盐度为8.51％～23.36％,密度为0.70～0.99 g/cm³。激光拉曼光谱分析表明,包裹体的气体成分主要为CO₂、H₂O、N₂和CH₄。包裹体岩相学及测温表明,流体由早期的高温、高盐度、含二氧化碳的含矿流体在主成矿阶段发生流体包裹体的沸腾、CO₂逸出、温度降低等过程,导致大量金属硫化物沉淀。结合氢氧同位素特征,初步确定该矿床的成矿流体主要以岩浆水为主,后期有大气水的加入。流体沸腾是新华龙钼矿床成矿的重要机制。     

Correlations between 11B NMR parameters and structural characters in borate and borosilicate minerals investigated by high-resolution MAS NMR and ab initio calculations

Borates consisting of diverse fundamental building blocks (FBB) formed from complex polymerization of planar triangular [Bϕ₃] groups and tetrahedral [Bϕ₄] groups, where ϕ = O and OH, provide an excellent opportunity for investigation of correlations between the NMR parameters and local structures. However, previous studies suggested that the ¹¹B NMR parameters in borates are insensitive to local structural environments other than the B coordination number, in contrast to those documented for ²⁹Si, ²³Na and ²⁷Al in silicates, and no correlation between ¹¹B chemical shifts and the sum of bond valences has been established for borate minerals with hydroxyl groups or molecular water in the structures. In this study, high-resolution NMR spectra have been acquired at the ultra high field of 21 T as well as at 14 T for selected borate and borosilicate minerals, and have been used to extract high-precision NMR parameters by using combined ab initio theoretical calculations and spectral simulations. These new NMR parameters reveal subtle correlations with various structural characters, especially the effects of the ¹¹B chemical shifts from the bridging oxygen atom(s), site symmetry, symmetry of FBB, the sum of bond valences, as well as the next-nearest-neighbor cations and hydrogen bonding. Also, these results provide new insights into the shielding mechanism for ¹¹B in borate and borosilicate minerals. In particular, this study demonstrates that the small variation in ¹¹B chemical shifts can still be used to probe the local structural environments and that the established correlations can be used to investigate the structural details in borates and amorphous materials.     

碳酸盐岩层序地层格架对岩溶储层的控制作用——以渤海西南海域下古生界为例

以钻井、测井、地震以及岩心、薄片资料为基础,在划分三级层序的基础上,探讨了渤海西南海域下古生界层序地层特征及其对岩溶储层的控制作用。结果表明：1）三级层序界面附近发育碳、氧同位素负异常以及自然能谱Th/K正异常,基于此特征将下古生界划分为21个三级层序;2）白云岩是研究区主要的储集岩性,层序通过控制垂向岩性的变化进而控制了优质储层的发育;3）将白云岩发育的12个三级层序定义为"优势储集层序",加里东期构造不整合与12个"优势储集层序"耦合控制了潜山型储层规模及其产能高低;寒武系内发育以溶蚀孔隙为主的内幕型岩溶储层,亦限定发育于"优势储集层序"之中。实际勘探中,优选风化界面与"优势储集层序"耦合区域优先钻探,同时兼顾内幕型储层,其是今后该区高效勘探的关键。     

Multielemental Neutron Activation Analysis of Chinese Geochemical Reference Samples

The concentrations of 36 elements in geochemical reference samples issued by the Ministry of Geology and Mineral Resources of China were determined by neutron activation analysis. Three main variants of the technique, instrumental, epithermal, and nreirradiation separation neutron activation analysis (INAA, ENAA, PNAA), were employed in a systematic study of the samples by three laboratories: the Institute of Atomic Energy of the Academia Sinica (INAA, ENAA), the Institute of High Energy Physics of the Academia Sinica (INAA), and the Institute of Geophysical and Geochemical Prosnecting of the Ministry of Geology and Mineral resources (INAA,PNAA). Both long and short irradiations and both Ge(Li) and HPGe detectors were used. A supplementary software nackage for data processing was developed. About 81% of the data determined by neutron activation agreed with recomended values with in 15%.     

钒的Kβ谱带精细结构的测定及钒的价态分析

用普通Ｘ射线荧光光谱仪测定了钒的氧化物、钒酸盐及含钒混合物中Ｖ的Ｋβ谱线,借助一套有效的谱处理程序,获得了有关Ｋβ谱线精细结构的谱峰参数,证实了谱线轮廓（Ｋβ″峰逐渐显著,Ｋβ５、Ｋβ″向高能端位移,Ｋβ５与Ｋβ１,３的分开趋势,Ｋβ１,３半峰宽发生变化）及谱峰参数（Ｋβ５峰能量,Ｋβ５与Ｋβ１,３能量差,Ｋβ５与Ｋβ１,３及Ｋβ″与Ｋβ１,３的强度比,以及Ｋβ５和Ｋβ１,３的不对称因子）与Ｖ的氧化数变化呈很强的相关性及规律性变化。     

南沙北部伸展构造的基本特征及其动力学意义

南沙地块辫啊以中南－美洲断裂为分界,其东、西两侧伸展构造的几何学与运动学表明,晚白垩世至早渐新世,其伸展作用以纯剪切为主;中渐新世至早中新世,伸展带东段转换为简单剪切,西段剪切渐停。伸展作用的主要动力来源于陆缘俯冲板片的拆沉、软流圈地幔热物质乘隙上拱和部分熔融作用及周边板块的相互作用。