黄土沉积物原生组分磁化率与风力的物质分选

本研究选取我国西北地区典型荒漠表土和黄土-古土壤序列样品为研究对象,探讨黄土沉积物及其潜在物源区表土的原生磁性矿物浓度在不同粒级间的变化规律、黄土剖面中粒度与磁化率的关系,以验证中国黄土沉积物中磁性组分在搬运过程中是否存在分选作用及其变化规律。来自西北地区表土的地质证据表明,磁性组分主要集中于>63 μm和31~63 μm粒径组分,并以后者的含量最高;与之相对应,黄土沉积中原生磁性组分主要集中于31~63 μm粒径组分,但>63 μm粒径组分不再是主要载磁组分,其磁性显著低于31~63 μm粒径组分。同时,多个剖面的证据表明黄土沉积的原生磁化率与31~63 μm粒径组分的含量是同相位变化的,进一步支持沉积物中原生组分的磁化率受到风动力的分选作用影响。需要强调的是,沉积物原生磁化率的主要载磁粒径组分为31~63 μm的颗粒物,而并非最粗粒组分。本研究结果暗示,相较于沉积物的全样粒度,干旱半干旱地区风成沉积的磁化率在指示古风场强度方面具有潜力。

     

内蒙古典型草原和草甸草原相对花粉产量重估

相对花粉产量（RPP）是利用地层花粉数据定量重建古植被的重要参数,但目前估算的不同地区同一植物类型的RPP多存在差异。为了解植被盖度计算方法对花粉产量的影响,本项研究利用卫星影像数字化重新计算了内蒙古锡林郭勒典型草原和乌拉盖草甸草原采样点周边100 m以外的植被数据,利用ERV模型重新估算了主要花粉类型的RPP,并运用景观重建算法（LRA）进行了检验。锡林郭勒典型草原ERV模型分析显示,ERV子模型1结合1/d距离加权法与植被-花粉数据拟合度最高,得到的相关花粉源范围（RSAP）为1470 m;以蒿属为参照种（RPP=1±0）,各科属RPP依次为藜科（0.53±0.03）、十字花科（0.17±0.01）、唐松草属（0.14±0.02）、菊科（0.09±0.01）、莎草科（0.08±0.006）、委陵菜属（0.07±0.01）、禾本科（0.050±0.003）。乌拉盖草甸草原ERV模型分析显示,ERV子模型1结合Prentice距离加权法与植被-花粉数据拟合度最高,得到的RSAP为770 m;以蒿属为参照种（RPP=1±0）,各科属RPP依次为藜科（5.85±0.58）、蓼科（5.27±0.37）、石竹科（5.15±0.47）、莎草科（4.16±0.13）、菊科（1.63±0.09）、百合科（0.49±0.08）、唇形科（0.38±0.06）、禾本科（0.200±0.004）。重估的RSAP和RPP均与首次估算时存在差异,表明植被盖度计算方法确实会影响RSAP和RPP。景观重建算法对RPP检验结果表明,卫星影像数字化估算的RPP重建的植被盖度与实际植被的相关性更高。

     

An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating

Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters.     

气象科学“内卷”了吗?

新中国气象科学经过70年的快速发展,已经触摸到了世界前沿。从20世纪中叶开始的长时间“跟跑”和中国具有世界上最高、尺度最大的地形等带来的气象预报复杂性问题,或许在21世纪20年代到来时,“内卷”带来的挑战会更严峻:在全球气象进入“准停滞期”等待突破时,我们还很少有领跑的机会和经验。     

Position-domain integrity risk-based ambiguity validation for the integer bootstrap estimator

Integrity monitoring for ambiguity resolution is of significance for utilizing the high-precision carrier phase differential positioning for safety–critical navigational applications. The integer bootstrap estimator can provide an analytical probability density function, which enables the precise evaluation of the integrity risk for ambiguity validation. In order to monitor the effect of unknown ambiguity bias on the integer bootstrap estimator, the position-domain integrity risk of the integer bootstrapped baseline is evaluated under the complete failure modes by using the worst-case protection principle. Furthermore, a partial ambiguity resolution method is developed in order to satisfy the predefined integrity risk requirement. Static and kinematic experiments are carried out to test the proposed method by comparing with the traditional ratio test method and the protection level-based method. The static experimental result has shown that the proposed method can achieve a significant global availability improvement by 51% at most. The kinematic result reveals that the proposed method obtains the best balance between the positioning accuracy and the continuity performance.     

Numerical characterization of slope rock mass through considerations of hydraulic and mechanical properties

Landslides - In this paper, the slope rock mass is numerically characterized by considering hydraulic and mechanical properties using two distinct element models. The flow rate and permeability are...     

China’s national carbon emissions trading scheme: lessons from the pilot emission trading schemes,academic literature,and known policy details

Upon completion, China’s national emissions trading scheme (C-ETS) will be the largest carbon market in the world. Recent research has evaluated China’s seven pilot ETSs launched from 2013 on, and academic literature on design aspects of the C-ETS abounds. Yet little is known about the specific details of the upcoming C-ETS. This article combines currently understood details of China’s national carbon market with lessons learned in the pilot schemes as well as from the academic literature. Our review follows the taxonomy of Emissions Trading in Practice: A Handbook on Design and Implementation (Partnership for Market Readiness & International Carbon Action Partnership. (2016). Retrieved from www.worldbank.org): The 10 categories are: scope, cap, distribution of allowances, use of offsets, temporal flexibility, price predictability, compliance and oversight, stakeholder engagement and capacity building, linking, implementation and improvements.

Key policy insights

• Accurate emissions data is paramount for both design and implementation, and its availability dictates the scope of the C-ETS.

• The stakeholder consultative process is critical for effective design, and China is able to build on its extensive experience through the pilot ETSs.

• Current policies and positions on intensity targets and Clean Development Mechanism (CDM) credits constrain the market design of the C-ETS.

• Most critical is the nature of the cap. The currently discussed rate-based cap with ex post adjustment is risky. Instead, an absolute, mass-based emissions cap coupled with the conditional use of permits would allow China to maintain flexibility in the carbon market while ensuring a limit on CO₂ emissions.

     

Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素

城市经济脆弱性作为当前脆弱性研究中的重要领域,为人-地系统耦合研究提供了新的视角,并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵,基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系,运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性,并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年,河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）;（2）河西走廊地区的城市经济脆弱性具有明显的空间特征,经历了东西高、中部低到整体较高的演变过程;（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子,提出针对性优化措施。