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371.
Sewage sludge ash (SSA), the waste generated in sewage sludge incineration, was obtained from Wuhan Sewage Treatment Plant and used as a low-cost sorbent for removing Cu(Ⅱ) from wastewaters. The sorbent was first modified with 5 % sulfuric acid to increase its sorption capacity. The specific surface area, porosity, cation-exchange capacity (CEC) and pHZPC of the sorbent were measured. Batch experiments were made to study the effect of contact time, solution pH value and temperature on sorption. Both Langmuir and Freundlich models well described the Cu(Ⅱ) sorption process, with correlation coefficient (R2) values of 0.993 4 and 0.989 9 respectively. And the sorption process follows the Lagergren first order kinetic model. The equilibrium sorption capacity of acidified SSA to Cu(Ⅱ) is estimated to be 7.78 mg/g under optimal conditions. 相似文献
372.
Genesis of Kanggur Gold Deposit in Eastern Tianshan Orogenic Belt, NW China: Fluid Inclusion and Oxygen and Hydrogen Isotope Constraints 总被引:3,自引:0,他引:3
Abstract. Primary fluid inclusions in quartz and carbonates from the Kanggur gold deposit are dominated by aqueous inclusions, with subsidiary CO2 -H2 O inclusions that have a constant range in CO2 content (10–20 vol %). Microthermometric results indicate that total homogenization temperatures have a wide but similar range for both aqueous inclusions (120 to 310C) and CO2 -H2 O inclusions (140 to 340C). Estimates of fluid salinity for CO2 -H2 O inclusions are quite restricted (5.9∼10.3 equiv. wt% NaCl), whereas aqueous inclusions show much wider salinity ranging from 2.2 to 15.6 equivalent wt %NaCl.
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ18 O and δD values of the ore-forming fluids can be achieved by exchanged meteoric water after isotopic equilibration with wall rock by fluid/rock interaction at a low water/rock ratio. However, the exchanged meteoric water alone cannot explain the full range of δ18 O and δD values, magmatic and/or meta-morphic water should also be involved. The wide salinity in aqueous inclusions may also result from mixing of meteoric water and magmatic and/or metamorphic water. 相似文献
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ
373.
Methane-rich fluid inclusions in skarn near the giant REE–Nb–Fe deposit at Bayan Obo, Northern China
We report fluid inclusion data for skarn, formed at the contact between Hercynian granitoids and dolomite of the Proterozoic Bayan Obo Group, in the vicinity of Bayan Obo REE–Nb–Fe deposit, Inner Mongolia, China. Three types of fluid inclusions are identified: two-phase CH4-rich, three-phase liquid–vapour–solid and two-phase aqueous inclusions. Using microthermometry and laser Raman microprobe analysis to calculate isochores for CH4-bearing inclusions, we estimate fluid trapping conditions at T=280 to 344 °C and P<1 to 2.3 kbar. Such conditions are compatible with formation of CH4 inclusions as a result of reaction between graphite in the country rocks (black slate sequence) and fluids derived from magma. The lack of carbonaceous material in the inclusions supports the hypothesis that CH4 was generated during fluid migration rather than by in situ reaction. In contrast to the skarn, and despite the fact that similar graphite-bearing slates are found in the host rocks, no CH4-bearing inclusions have been so far reported from Bayan Obo REE ores. We therefore conclude that the skarn-forming fluids in the contact aureole of the Hercynian granitoids were not involved at any stage in the formation of the Bayan Obo deposit. 相似文献
374.
TianJun WangPinxian ChengXinrong 《中国地质大学学报(英文版)》2004,15(3):283-289
The continuous wavelet transform (CWT) analysis reveals the instantaneous variability of the foraminiferal δ18O and δ13C of Site 1143 for the past 5 Ma at the eccentricity, obliquity and precession bands. The cross CWT analysis further demonstrates nonstationary phases of the benthic -δ18O relative to ETP at the three primary Milankovitch bands in the last 5 Ma. The instantaneous phases between benthic -δ18O and δ13C at the precession band display a prominent 128 ka period, probably the cyclicity of the nonstationary climate close to the eccentricity. To explain these nonstationary phases, it is desirable to introduce a nonlinear response model to the global climate system, in which the output has a prominent cycle around 100 ka to match the 128 ka cycle of the instantaneous phase of the δ13C and -δ18O on the precession band. 相似文献
375.
Dating deposits in caves formed by rivers may yield insight into rates and processes of bedrock incision. Three cave passages at different levels have developed in the walls of the Qianyou River valley in the Qinling mountains, south of the city of Xian, China. Twelve speleothem samples near the position of palaeowater tables in three cave passages are dated by the 230Th dating method. The results show that the river cut down at the rate of 0.23 ± 0.02 mm/yr from 358,000 ± 38,000 to 247,000 ± 28,000 yr ago, 0.19 ± 0.03 mm/yr from 247,000 ± 28,000 to 118,000 ± 19,000 yr ago, and 0.51 ± 0.08 mm/yr from 118,000 ± 19,000 yr ago until today. These fall very close to the glacial-interglacial transition following marine oxygen isotope stages 10, 8, and 6, respectively. The increase in downcutting rates during the interglacial period is consistent with warm, wet weather, increasing rates of erosion. This may lead us toward an underlying mechanism for modulating incision that is not in a direct response to the presence of headwater glaciers. 相似文献
376.
Chen-Tung Arthur Chen Jiunn-Tzong Wu Bing-Jye Wang Kuo-Ming Huang 《Aquatic Geochemistry》2004,10(1-2):33-57
One hundred and eighty lakes, ponds and reservoirs in Taiwan, and the offshore islands have been investigated since 1985. Effects such as warming/cooling, mixing, photosynthesis and respiration on pH have been identified. These effects were found to be less profound than those resulting from the geology. Since there is little rain or lake water pH data available prior to 1970, it was necessary to use proxy data in order to ascertain the history of lake acidification. In this study, we present data based on diatoms in a sediment core collected from a lake in the remote subalpine region of southern Taiwan. The acidity of this lake water was found to have increased since 1900. We measured the concentrations of 55 chemical species in lake water samples. In addition, concentrations of 26 chemical species were obtained from sediments. Conductivity, alkalinity (HCO3 ?), most other major and minor chemical species, as well as the non sea-salt SO4/Na ratio in lake water clearly decrease with elevation. Distribution of pH is similar, although the trend is less clear. Distribution of trace metals, however, shows a different trend as anthropogenic pollution, diagenetic reduction and lake acidification are at play. 相似文献
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