Investigating Bermuda's pollution history through stable isotope analyses of modern and museum-held gorgonian corals

For centuries, Bermuda has been challenged with wastewater management for the protection of human and environmental health. By quantifying the δ¹⁵N of the common sea fan Gorgonia ventalina sampled from 30 sites throughout Bermuda we show that sewage-derived nitrogen is detectable on nearshore coral reefs and declines across the lagoon to the outer rim. We also sampled gorgonians from two museum collections representing a 50y time-series (1958–2008). These samples revealed an increase in δ¹⁵N of > 4.0‰ until the mid-1970s, after which δ¹⁵N values slowly declined by ~ 2.0‰. A δ¹⁵N chronology from a gorgonian skeleton exhibited a similar decline over the last 30–40 years of approximately 0.6‰. We conclude that policies have been effective in reducing sewage impacts to Bermudian reefs. However, significant sources of sewage pollution persist and are likely have a strong impact on harbor and nearshore coral communities and human health.     

Paleosols and prehistoric populations in the high plains

Excavations in 1980–1981 at sites (32MZ319 and 32MZ380) along Cinnamon Creek Ridge in the Little Missouri River Badlands of McKenzie County, North Dakota, unexpectedly revealed at each locality the presence of one or more deeply buried paleosols with associated cultural materials. At both sites, 32MZ319 and 32MZ380, multiple paleosols are present, each of which is terminated by an episode of aeolian deposition. Fifteen radiocarbon dates on these paleosols establish an incipient chronology for paleosol development in the study area and permit correlation with other High Plains archaeological complexes. Geological and archaeological data for the two multiple paleosol sites are summarized.     

Age and source material of the Kingash ultramafic-mafic massif,East Sayan

The REE distribution patterns and Nd whole-rock and mineral isotope ratios of the Kingash ultramafic-mafic massif enabled us to propose a multistage history for its evolution at 1410 and 875 Ma. These stages reflect the magmatic evolution of the Siberian paleocontinent margin during the Late Precambrian. The age of metamorphism of the massif during collision and accretion in the Early Paleozoic (∼500 Ma) was obtained based on a Sm-Nd mineral isochron from rheomorphic veined albitite. The Nd and Sr isotopic compositions of rocks from the Kingash massif suggest mantle sources for picritic and basic magmas, which are thought to have originated by mixing of different proportions of depleted (PREMA or DM) and enriched (EM) melts. The initial isotope ratios of the parental melts transformed during interaction with Sr-rich material from the host metasedimentary complexes.     

Scope for a small circumsolar annular gravitational contribution to the Pioneer anomaly without affecting planetary orbits

All proposed gravitational explanations of the Pioneer anomaly must crucially face the Equivalence Principle. Thus, if Pioneers 10 and 11 were influenced by anomalous gravitational effects in regions containing other Solar System bodies, then those bodies should likewise be influenced, irrespective of their shape, composition or mass. Although the lack of any observed influence upon planetary orbits severely constrains such explanations, here we aim to construct by computer modeling, hypothetical gravitating annuli having no gravitational impact on planetary orbits from Mercury to Neptune. One model has a central zone, free of radial gravitation in the annular plane, and an ‘onset’ beyond Saturn’s orbit, where sunward annular gravitation increases to match the Pioneer anomaly data. Sharp nulls are included so that Uranus and Neptune escape this influence. Such models can be proportionately reduced in mass: a 1 % contribution to the anomaly requires an annulus of approximately 1 Earth mass. It is thus possible to comply with the JPL assessment of newly recovered data attributing 80 %, or more, of the anomaly to spacecraft heat, which appears to allow small contributions from other causes. Following the possibility of an increasing Kuiper belt density at great ranges, another model makes an outward small anomalous gravitation in the TNO region, tallying with an observed slight indication of such an effect, suggesting that New Horizons may slightly accelerate in this region.     

Ice-sheet growth and high-latitudes sea-surface temperature

The response of the LLN 2-D climate model to the insolation and CO₂ forcings during the Eemian interglacial is compared to reconstructions obtained from deep-sea cores drilled in the Norwegian Sea and in the North Atlantic. Both reconstructions and modeling results show a decrease of sea-surface temperature (SST) in the higher latitudes (70–75 °N zonal belt for the model and the Norwegian Sea for the proxy records), associated with a more moderate cooling at lower latitudes (50–55 °N and North Atlantic), at the middle of isotopic substage 5e, several millenia before the beginning of continental ice-sheet growth. Such a comparison between the simulated SST and ice volume of the Northern Hemisphere has been extended to the whole last glacial-interglacial cycle. The influence of the insolation forcing on SST and the shortcomings of the model due to its zonal character are discussed. Received: 6 July 1995/Accepted: 19 December 1995     

A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.