Surface and groundwater quality characterization of Deoria District,Ganga Plain,India

A water quality investigation was carried out in the Deoria district, Ganga plain, to assess the suitability of surface and groundwaters for domestic, agricultural, and industrial purposes. As much as 50 representative samples from river and groundwater were collected from various stations to monitor the water chemistry of various ions, comprising Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ⁻, SO₄ ²⁻, NO₃ ⁻, Cl⁻, F⁻, and trace metals, such as Fe, Cu, Mn, Zn, Cd, and Pb. The results showed that electrical conductance (EC), total dissolved solids (TDS), HCO₃ ⁻, Mg²⁺, Na⁺, and total hardness (TH) are above the maximum desirable limit, and apart from Fe and Mn all other trace metals are within the maximum permissible limit for drinking water. The calculated values for sodium absorption ratio (SAR), salinity, residual sodium carbonate (RSC), and permeability index (PI) indicate well to permissible use of water for irrigation. High values of Na%, RSC, and Mg-hazard (MH) at some stations restrict its use for agricultural purpose. Anthropogenic activities affect the spatial variation of water quality. Economic and social developments of the study area is closely associated with the characteristics of the hydrological network.     

Tropospheric Ozone in a Global-Scale Three-Dimensional Lagrangian Model and Its Response to NOX Emission Controls

A three-dimensional Lagrangian tropospheric chemistry modelis used toinvestigate the impact of human activities on the tropospheric distributionofozone and hydroxyl radicals. The model describes the behaviour of 50 speciesincluding methane, carbon monoxide, oxides of nitrogen, sulphur dioxide andnineorganic compounds emitted from human activities and a range of other sources.Thechemical mechanism involves about 100 chemical reactions of which 16 arephotochemical reactions whose diurnal dependence is treated in full. The modelutilises a five minute chemistry time step and a three hour advection timestepfor the 50,000 air parcels. Meteorological data for the winds, temperatures,clouds and so on are taken from the UK Meteorological Office global model for1994 onwards. The impacts of a 50% reduction in European NO_Xemissions onglobal ozone concentrations are assessed. Surface ozoneconcentrations decrease in summertime and rise in wintertime, but to differentextents.     

Assessment of rock slope stability by probabilistic-based Slope Stability Probability Classification method along highway cut slopes in Adilcevaz-Bitlis (Turkey)

Rock slope stability is of great concern along highway routes as stability problems on cut slopes may cause fatal events as well as loss of property. In rock slope engineering, stability evaluations are commonly performed by means of analytical or numerical analyses, principally considering the factor of safety concept. As a matter of fact, the probabilistic assessment of slope stability is progressively getting popularity due to difficulties in assigning the most appropriate values to design parameters in analytical or numerical methods. Additionally, the effect of heterogeneities in rock masses and discontinuities on the analysis results is minimized through the probabilistic concept. In this study, slope stability of high and steep sedimentary rock cut slopes along a state highway in Adilcevaz-Bitlis (Turkey) was evaluated on the basis of probabilistic approach using the Slope Stability Probability Classification (SSPC) system. The probabilistic assessment indicates major slope stability problems because of discontinuity controlled and discontinuity orientation independent mass movements. Almost all studied cut slopes suffer from orientation-independent stability problems with very low stability probabilities. Additionally, the probability of planar and toppling failures is significantly high with respect to the SSPC system. The stability problems along the investigated rock slopes were also verified by field reconnaissance. Remedial measures such as slope re-design and reinforcement at the studied locations should be taken to prevent hazardous events along the highway. On the other hand, the probabilistic approach may be a useful tool during rock slope engineering to overcome numerous uncertainties when probabilistic and analytic results are compared.     

Misconceptions about the Hubble recession law

Almost all astronomers now believe that the Hubble recession law was directly inferred from astronomical observations. It turns out that this common belief is completely false. Those models advocating the idea of an expanding universe are ill-founded on observational grounds. This means that the Hubble recession law is really a working hypothesis. One alternative to the Hubble recession law is the tired-light hypothesis originally proposed by Zwicky (Proc. Nat. Acad. Sci. 15:773, 1929). This hypothesis leads to a universe that is an eternal cosmos continually evolving without beginning or end. Such a universe exists in a dynamical state of virial equilibrium. Observational studies of the redshift-magnitude relation for Type Ia supernovae in distant galaxies might provide the best observational test for a tired-light cosmology. The present study shows that the model Hubble diagram for a tired-light cosmology gives good agreement with the supernovae data for redshifts in the range 0<z<2. This observational test of a static cosmology shows that the real universe is not necessarily undergoing expansion nor acceleration. An erratum to this article can be found at     

A comparative study of sequential minimal optimization-based support vector machines,vote feature intervals,and logistic regression in landslide susceptibility assessment using GIS

Landslide susceptibility assessment using GIS has been done for part of Uttarakhand region of Himalaya (India) with the objective of comparing the predictive capability of three different machine learning methods, namely sequential minimal optimization-based support vector machines (SMOSVM), vote feature intervals (VFI), and logistic regression (LR) for spatial prediction of landslide occurrence. Out of these three methods, the SMOSVM and VFI are state-of-the-art methods for binary classification problems but have not been applied for landslide prediction, whereas the LR is known as a popular method for landslide susceptibility assessment. In the study, a total of 430 historical landslide polygons and 11 landslide affecting factors such as slope angle, slope aspect, elevation, curvature, lithology, soil, land cover, distance to roads, distance to rivers, distance to lineaments, and rainfall were selected for landslide analysis. For validation and comparison, statistical index-based methods and the receiver operating characteristic curve have been used. Analysis results show that all these models have good performance for landslide spatial prediction but the SMOSVM model has the highest predictive capability, followed by the VFI model, and the LR model, respectively. Thus, SMOSVM is a better model for landslide prediction and can be used for landslide susceptibility mapping of landslide-prone areas.     

Temperature dependence of the cation distribution in nickel aluminate (NiAl2O4) spinel: a powder XRD study

NiAl₂O₄ is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl₂O₄ quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a₀, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).     

Occurrence and characteristics of sporadic sodium layer observed by lidar at a mid-latitude location

Na lidar observations of SSL during the past 5 years at a mid-latitude location (Wuhan, China, 31°N, 114°E) are reported in this paper. From 26 SSL events detected in about 230 h of observation, an SSL occurrence rate of 1 event/9 h at our location was obtained. This result, combined with that reported by Nagasawa and Abo (Geophys. Res. Lett. 22 (1995) 263) at Tokyo, Japan, reveals that the SSL occurrence can be relatively frequent at some mid-latitude locations. The statistical analyses of main parameters for the 26 SSL events were made, and the results were compared with those previously reported. By examining the corresponding data from a nearby ionosonde, it was found that there was a fairly good correlation between SSL and Es. Of the 18 pairs of SSL and Es events checked, 15 of SSL were accompanied by Es, and 8 pairs of them were correlated within 1 h in time and within 5 km in altitude. From the analyses of observed perturbations during SSL development, the role of dynamic processes of atmosphere in the SSL formations were emphasized.     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

Qualitätsanforderungen an Oberflächengewässer: Zielvorgaben,Qualitätsziele und chemische Gewässergüteklassifizierung

Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.     

Die Radialgeschwindigkeit des Am Sternes 68 Tau

The radial velocity of the star 68 Tau is searched in dependence on the light variation period. No variations have been proved. The mean radial velocity of 22 spectra is 40.4 km/sec ± 0.7 km/sec.