Unraveling complex hydrogeological processes in Andean basins in south‐central Chile: An integrated assessment to understand hydrological dissimilarity

Groundwater storage, drainage, and interbasin water exchange are common hydrological processes but often difficult to quantify due to a lack of local observations. We present a study of three volcanic mountainous watersheds located in south‐central Chile (~36.9 ° S) in the Chillán volcanic complex (Chillán, Renegado, and Diguillín river basins). These are neighboring basins that are similar with respect to the metrics normally available for characterization everywhere (e.g., precipitation, temperature, and land cover). In a hydrological sense, similar (proportional) behavior would be expected if these catchments would be characterized with this general information. However, these watersheds show dissimilar behavior when analyzed in detail. The surface water balance does not fit for any of these watersheds individually; however, the water balance of the whole system can be explained by likely interbasin water exchanges. The Renegado river basin has an average annual runoff per unit of area on the order of 60–65% less than those of the Diguillín and Chillán rivers, which is contradictory to the hydrological similarity among the basins. To understand the main processes that control streamflow generation, two analyses were performed: (a) basin metrics (land cover, geologic, topographic, and climatological maps) and hydro‐meteorological data analyses and (b) a water balance model approach. The analyses contribute to a plausible explanation for the hydrogeological processes in the system. The soils, topography, and geology of the Chillán–Renegado–Diguillín system favor the infiltration and groundwater movements from the Renegado river basin, mainly to the neighboring Diguillín basin. The interbasin water exchanges affect hydrological similarity and explain the differences observed in the hydrological processes of these three apparently similar volcanic basins. The results highlight the complexity of hydrological processes in volcanic mountainous systems and suggest that a simple watershed classification approach based on widely available data is insufficient. Simple local analyses such as specific flow analysis with a review of the geology and morphology can contribute to a better understanding of the hydrology of volcanic mountainous areas.     

Assessing the ‘two water worlds’ hypothesis and water sources for native and exotic evergreen species in south‐central Chile

Recent studies using water‐stable isotopes (δ¹⁸O and δ²H) have suggested an ecohydrological separation of water flowing to streams or recharging groundwater and water used by trees, known as the ‘two water worlds’ (TWW) hypothesis. In this study, we measured water isotopic composition in precipitation [open field and throughfall, i.e. local meteoric water line (LMWL)] and the mobile water compartment (i.e. stream and soil solution), bulk soil water and xylem water over a period of 1.5 years in two headwater catchments: NF, covered with old growth native evergreen forest (Aetoxicon punctatum, Laureliopsis philippiana and Eucriphya cordifolia), and EP, covered with 4 and 16‐year‐old Eucalyptus nitens stands. Our results show that precipitation, stream and soil solution plot approximately along the LMWL, while xylem waters from all studied tree species plot below the LMWL, supporting the TWW hypothesis. However, we also found evidence of ecohydrological connectivity during the wet season, likely controlled by the amount of antecedent precipitation. These observations hold for all investigated tree species. On both sites, a different precipitation source for stream and xylem water was observed. However, in EP, bulk soil showed a similar precipitation source as xylem water from both E. nitens stands. This suggests that E. nitens may use water that is recharging the bulk soil compartment. We conclude that under a rainy temperate climate, the TWW hypothesis is temporal and does not apply during wet seasons. Copyright © 2016 John Wiley & Sons, Ltd.     

Bismuth‐melt trails trapped in cassiterite–quartz veins

Native bismuth in the form of metallic melt has been considered instrumental to the formation of some metallic ore deposits via a mechanism dubbed the “Liquid Bismuth Collector Model.” Here, we provide petrographical documentation of trail‐forming, μm‐sized blebs of native bismuth in cassiterite–quartz veins from the Santa Bárbara greisen Sn deposit in the Rondônia tin province of northern Brazil. These inclusions suggest the trapping of a Bi melt that took place during vein formation, in a mechanism similar to the entrapment of fluid inclusions.     

Short‐ and long‐term evapotranspiration rates at ecological restoration sites along a large river receiving rare flow events

Many large rivers around the world no longer flow to their deltas, due to ever greater water withdrawals and diversions for human needs. However, the importance of riparian ecosystems is drawing increasing recognition, leading to the allocation of environmental flows to restore river processes. Accurate estimates of riparian plant evapotranspiration (ET) are needed to understand how the riverine system responds to these rare events and achieve the goals of environmental flows. In 2014, historic environmental flows were released into the Lower Colorado River at Morelos Dam (Mexico); this once perennial but now dry reach is the final stretch to the mighty Colorado River Delta. One of the primary goals was to supply native vegetation restoration sites along the reach with water to help seedlings establish and boost groundwater levels to foster the planted saplings. Patterns in ET before, during, and after the flows are useful for evaluating whether this goal was met and understanding the role that ET plays in this now ephemeral river system. Here, diurnal fluctuations in groundwater levels and Moderate Resolution Imaging Spectroradiometer (MODIS) data were used to compare estimates of ET specifically at 3 native vegetation restoration sites during 2014 planned flow events, and MODIS data were used to evaluate long‐term (2002–2016) ET responses to restoration efforts at these sites. Overall, ET was generally 0–10 mm d^?1 across sites, and although daily ET values from groundwater data were highly variable, weekly averaged estimates were highly correlated with MODIS‐derived estimates at most sites. The influence of the 2014 flow events was not immediately apparent in the results, although the process of clearing vegetation and planting native vegetation at the restoration sites was clearly visible in the results.     

Carbon fluxes through major phytoplankton groups during the spring bloom and post-bloom in the Northwestern Mediterranean Sea

The carbon flux through major phytoplankton groups, defined by their pigment markers, was estimated in two contrasting conditions of the Northwestern Mediterranean open ocean ecosystem: the spring bloom and post-bloom situations (hereafter Bloom and Post-bloom, respectively). During Bloom, surface chlorophyll a (Chl a) concentration was higher and dominated by diatoms (53% of Chl a), while during Post-bloom Synechococcus (42%) and Prymnesiophyceae (29%) became dominant. The seawater dilution technique, coupled to high pressure liquid chromatography (HPLC) analysis of pigments and flow cytometry (FCM), was used to estimate growth and grazing rates of major phytoplankton groups in surface waters. Estimated growth rates were corrected for photoacclimation based on FCM-detected changes in red fluorescence per cell. Given the 30% average decrease in the pigment content per cell between the beginning and the end of the incubations, overlooking photoacclimation would have resulted in a 0.40 d^?1 underestimation of phytoplankton growth rates. Corrected average growth rates (μ_o) were 0.90±0.20 (SD) and 0.40±0.14 d^?1 for Bloom and Post-bloom phytoplankton, respectively. Diatoms, Cryptophyceae and Synechococcus were identified as fast-growing groups and Prymnesiophyceae and Prasinophyceae as slow-growing groups across Bloom and Post-bloom conditions. The higher growth rate during Bloom was due to dominance of phytoplankton groups with higher growth rates than those dominating in Post-bloom. Average grazing rates (m) were 0.58±0.20 d^?1 (SD) and 0.31±0.07 d^?1. The proportion of phytoplankton growth consumed by microzooplankton grazing (m/μ_o) tended to be lower in Bloom (0.69±0.34) than in Post-bloom (0.80±0.08). The intensity of nutrient limitation experienced by phytoplankton indicated by μ_o/μ_n (where μ_n is the nutrient-amended growth rate), was similar during Bloom (0.78) and Post-bloom (0.73). Primary production from surface water (PP) was estimated with ¹⁴C incubations. A combination of PP and Chl a synthesis rate yielded C/Chl a ratios of 34±21 and 168±75 (g:g) for Bloom and Post-bloom, respectively. Transformation of group-specific Chl a fluxes into carbon equivalents confirmed the dominant role of diatoms during Bloom and Synechococcus and Prymnesiophyceae during Post-bloom.     

Coastal Occupations in Tierra del Fuego,Southernmost South America: A Late Holocene Hunter‐Gatherer Context at Marazzi 2

This paper focuses on the late Holocene occupation of hunter‐gatherers at the Marazzi 2 site located on the northwestern steppe of Tierra del Fuego, Chile. Our aim is to understand stratigraphy, formation processes, and pedogenesis with respect to human occupation over the last 3000 years. Based on archaeological excavations on a fluvial terrace of the Torcido River, we integrate soil micromorphology, mineralogy, geochemistry, magnetic susceptibility, and geomorphology, as well as the micro‐ and macrofrequency distributions of archaeological material. A micro‐taphonomical perspective is also applied to anthropogenic components recorded in sedimentary thin sections. We discuss various events in the interplay between soil development and human occupation through time. Marazzi 2 was witness to aggradation and pedogenesis with an episode of surface stability coincident with a phase of more intense human occupation at about 860 BC. Taphonomic analysis suggests that there are multiple occupation events mixed together, probably by biomechanical processes, resulting in a palimpsest with poor temporal resolution.     

Provenance of Holocene beach sand in the Western Iberian margin: the use of the Kolmogorov–Smirnov test for the deciphering of sediment recycling in a modern coastal system

Detrital zircons from Holocene beach sand and igneous zircons from the Cretaceous syenite forming Cape Sines (Western Iberian margin) were dated using laser ablation – inductively coupled plasma – mass spectrometry. The U–Pb ages obtained were used for comparison with previous radiometric data from Carboniferous greywacke, Pliocene–Pleistocene sand and Cretaceous syenite forming the sea cliff at Cape Sines and the contiguous coast. New U–Pb dating of igneous morphologically simple and complex zircons from the syenite of the Sines pluton suggests that the history of zircon crystallization was more extensive (ca 87 to 74 Ma), in contrast to the findings of previous geochronology studies (ca 76 to 74 Ma). The U–Pb ages obtained in Holocene sand revealed a wide interval, ranging from the Cretaceous to the Archean, with predominance of Cretaceous (37%), Palaeozoic (35%) and Neoproterozoic (19%) detrital‐zircon ages. The paucity of round to sub‐rounded grains seems to indicate a short transportation history for most of the Cretaceous zircons (ca 95 to 73 Ma) which are more abundant in the beach sand that was sampled south of Cape Sines. Comparative analysis using the Kolmogorov–Smirnov statistical method, analysing sub‐populations separately, suggests that the zircon populations of the Carboniferous and Cretaceous rocks forming the sea cliff were reproduced faithfully in Quaternary sand, indicating sediment recycling. The similarity of the pre‐Cretaceous ages (>ca 280 Ma) of detrital zircons found in Holocene sand, as compared with Carboniferous greywacke and Pliocene–Pleistocene sand, provides support for the hypothesis that detritus was reworked into the beach from older sedimentary rocks exposed along the sea cliff. The largest percentage of Cretaceous zircons (<ca 95 Ma) found in Holocene sand, as compared with Pliocene–Pleistocene sand (secondary recycled source), suggests that the Sines pluton was the one of the primary sources that became progressively more exposed to erosion during Quaternary uplift. This work highlights the application of the Kolmogorov–Smirnov method in comparison of zircon age populations used to identify provenance and sediment recycling in modern and ancient detrital sedimentary sequences.     

Climate change and human impact in a sensitive ecosystem: the Holocene environment of the Northwest Icelandic highland margin

Complex interactions of climate and volcanic activity have shaped the environment of Iceland during the Holocene. Palaeoecological records from Iceland offer a unique look at a Holocene environment that was uninhabited by humans and free of mammal herbivores until about AD 870. We present a new reconstruction of Holocene vegetation and landscape dynamics from a small lake, Barðalækjartjörn, located near the highland margin in Northwest Iceland. A multi‐proxy approach was used to reconstruct vegetation based on pollen and plant macrofossil analysis and landscape stability based on lithological proxies. The record covers the period c. 10 300–200 cal. a BP. For the first two millennia aeolian processes probably played a part in vegetation development. This period is characterized by high input of minerogenic material into the lake and a vegetation assemblage in which plants tolerant of aeolian deposition are prominent. Betula pubescens woodland reached a maximum between c. 7400 and 6500 cal. a BP. Betula nana‐dominated dwarf shrub heath replaced woodland after c. 4000 cal. a BP, following the onset of Neoglaciation. Land use following human settlement caused an environmental shift at the highland margin. Betula pubescens probably disappeared from the vicinity of the lake soon thereafter. Large‐scale soil erosion began at c. 1000 cal. a BP in the wake of human activities, such as introduction of grazing livestock and woodcutting. This study offers an important long‐term perspective of the development of the highland ecosystem under both wholly natural and human‐influenced conditions.