Viability of pyrite pulled metabolism in the ‘iron-sulfur world’ theory: Quantum chemical assessment

The viability of pyrite-pulled metabolism in the ‘iron-sulfur world’ theory was assessed using a simple model of iron-nickel sulfide (Fe-Ni-S) surface and data obtained from quantum chemical calculations. We have investigated how the individual reactions in the carbon fixation cycle (carboxylic acids formation) on an Fe-Ni-S surface could have operated to produce carboxylic acids from carbon oxide and water. The proposed model cycle reveals how the individual reactions might have functioned and provides the thermodynamics of each step of the proposed pathway. The feasibility of individual reactions, as well the whole cycle was considered. The reaction of acetic acid production from CH₃SH and CO on an Fe-Ni sulfide surface was revealed to be endergonic with a few partial steps having positive Gibbs free energy. On the other hand, the pyrite formation was found to be slightly exergonic. The significance of the catalytic activity of transition metal sulfides in generation of acetic acid was shown. The Gibbs free energy values indicate that the acetic acid synthesis is unfavorable to proceed on the studied Fe-Ni-S model under simulated conditions. The importance of these results in terms of a primordial chemistry on iron-nickel sulfide surfaces is discussed.     

Chemical fingerprints of life in terrestrial soils and their possible use for the detection of life on Mars and other planets

Organic carbon in oxidizable forms and nitrogen are the only elements among some 40 elements studied that are significantly enriched in terrestrial soils as compared to the crust. This enrichment is due to and reflecting life activity in soils, and is characterized by a unique profile distribution. It is suggested that these facts can constitute the basis for the future chemical-biological search for life in planetary soils.     

Nonlinear Rate Dependent Model of High Damping Rubber Bearing

The accurate analysis of the response of isolated structures requires the application of appropriate models of isolation devices. The purpose of this paper is to analyse a nonlinear strain rate dependent model of a high damping rubber bearing which simulates the horizontal behaviour of the device under specified vertical load using a nonlinear elastic spring-dashpot element. The effectiveness of the model is checked by fitting the experimental data concerning three different rubber bearings. The results of the study show that the model can simulate the bearing behaviour over a wide shear strain range with small simulation errors. This revised version was published online in July 2006 with corrections to the Cover Date.     

Geochemistry and Rb–Sr geochronology of a ductile shear zone in the Orlica-Śnieżnik dome (West Sudetes, Poland)

Amphibolite-facies orthogneisses of the Orlica-vnie™nik dome in the West Sudetes (Poland) show a local continuous transition from weakly deformed augen gneisses to finely laminated mylonites. Field evidence indicates that ductile shearing developed pre- or syntectonically to a migmatization event. Bulk-rock compositions of variably deformed samples yield no indications for deformation- and/or fluid-enhanced element mobility and redistribution. ⁸⁷Rb-⁸⁶Sr geochronology (biotite, phengite, whole rock) places time constraints on the deformation process and the post-orogenic cooling history. Phengite- and biotite-whole-rock pairs yield Rb-Sr ages of 340 to 334 Ma and 335 to 294 Ma, respectively, independent of the degree of deformation. The weighted mean of phengite-whole-rock pairs indicates an age of 337.4DŽ.3 Ma. Combining most of the biotite-whole-rock data yields a weighted mean age of 328.6dž.4 Ma. Because of their different closure temperatures for the Rb-Sr system, these differences are interpreted to date cooling after a thermal event. Direct dating of the deformation is not possible, but the cooling history record defines a minimum age for the development of ductile shearing and the last migmatization event. These time constraints provide evidence for the initiation of crustal collapse during or immediately following peak metamorphic conditions. The results of this study further document the importance of Variscan metamorphism in the Orlica-vnie™nik dome.     

Preliminary evidence for human fecal contamination in corals of the Florida Keys,USA

Corals and reef environments are under increased stress from anthropogenic activities, particularly those in the vicinity of heavily populated areas such as the Florida Keys. The potential adverse impacts of wastewater can affect both the environment and human health; however, because of the high decay rate of bacterial indicators in coral reef waters it has been difficult to document the presence of microbial contaminants and to assign risks in these environments. Here we show initial evidence that microorganisms associated with human feces are concentrated along the surface of coral heads relative to the overlying water column in the Florida Keys. Bacterial indicators (fecal coliform bacteria, enterococci or Clostridium perfringens) were detected in 66.7% of the coral surface microlayer (CSM) samples at levels between five and 1000 CFU/100 ml, but were found infrequently and at low numbers in the overlying water column ( < or = 2.5 CFU/100 ml). Similarly, enterovirus nucleic acid sequences, an indicator of human-specific waste, were detected in 93.3% of the CSM samples and only once in the water column by cell culture. Results show that coral mucus may accumulate enteric microorganisms in reef environments, and may indicate a risk to public and environmental health despite low indicator levels in the surrounding water.     

An empirical test of household identification risk in geomasked maps

ABSTRACT

Geomasking techniques displace point data to new locations in order to protect privacy while maintaining overall spatial distributions. If the end users of geomasked data are unaware that the data are masked, there is a risk that they will incorrectly associate individuals at the new locations with the masked data attributes. The probability of correct and false household identification depends on human understanding of whether maps contain masked coordinates and the spatial relationships of the points to contextual geographic data. Using a map-based experiment, this study finds that confidence in performing a household identification is substantially lowered when masked points are situated equidistantly between residential parcels. Despite initial notifications that data are masked, map users often report confidence in assigning masked points to specific households. Only map users who receive frequent notifications that the points are masked have reduced confidence in associating them with particular households, thereby lowering identification risk.     

Analytical expression between the impact damping ratio and the coefficient of restitution in the non‐linear viscoelastic model of structural pounding

Earthquake‐induced structural pounding has been recently intensively studied with the help of different models of impact force. It has been verified through comparisons, that the non‐linear viscoelastic model may be considered somewhat the most accurate one among them. The aim of this short paper is to derive an approximating formula relating the impact damping ratio, as a parameter of the model mentioned, with a more widely used coefficient of restitution. The accuracy of the derived analytical formulation has been confirmed through the comparison with the results of numerical simulations. Copyright © 2005 John Wiley & Sons, Ltd.