Compatibility of NMEA GGA with GPS Receivers Implementation

The NMEA GGA standard for global positioning system (GPS) and GLONASS receiver interfaces provides smooth data transfer from receiver to computer for postprocessing. Specifically, the NMEA GGA specifies that the orthometric height and the undulation be listed in addition to other quantities. The Ashtech manual (Ashtech, 1997; p. 104), however, specifies that the respective field in the NMEA GGA message contains the ellipsoidal height when outputting from Ashtech's GG24 receiver. Because such an inconsistency between the official NMEA GGA specifications and the implementation by a manufacturer can potentially confuse the user, we carried out a numerical test to confirm Ashtech's implentation. The result indicates that Ashtech indeed gives the ellipsoidal height in the fielt that should actually contain the orthometric height according to the NMEA GGA specifications. Firmware version after and including GF02 have corrected this situation. ? 2000 John Wiley & Sons, Inc.     

Integer estimation in the presence of biases

 Carrier phase ambiguity resolution is the key to fast and high-precision GNSS (Global Navigation Satellite System) kinematic positioning. Critical in the application of ambiguity resolution is the quality of the computed integer ambiguities. Unsuccessful ambiguity resolution, when passed unnoticed, will too often lead to unacceptable errors in the positioning results. Very high success rates are therefore required for ambiguity resolution to be reliable. Biases which are unaccounted for will lower the success rate and thus increase the chance of unsuccessful ambiguity resolution. The performance of integer ambiguity estimation in the presence of such biases is studied. Particular attention is given to integer rounding, integer bootstrapping and integer least squares. Lower and upper bounds, as well as an exact and easy-to-compute formula for the bias-affected success rate, are presented. These results will enable the evaluation of the bias robustness of ambiguity resolution. Received: 28 September 2000 / Accepted: 29 March 2001     

A model for adjustment of differential gravity measurements with simultaneous gravimeter calibration

 A mathematical model is proposed for adjustment of differential or relative gravity measurements, involving simultaneously instrumental readings, coefficients of the calibration function, and gravity values of selected base stations. Tests were performed with LaCoste and Romberg model G gravimeter measurements for a set of base stations located along a north–south line with 1750 mGal gravity range. This line was linked to nine control stations, where absolute gravity values had been determined by the free-fall method, with an accuracy better than 10 μGal. The model shows good consistence and stability. Results show the possibility of improving the calibration functions of gravimeters, as well as a better estimation of the gravity values, due to the flexibility admitted to the values of the calibration coefficients. Received: 15 November 1999 / Accepted: 31 October 2000     

Atmospheric, oceanic and hydrological contributions to seasonal variations in length of day

 The annual and semiannual residuals derived in the axial angular momentum budget of the solid Earth–atmosphere system reflect significant signals. They must be caused by further excitation sources. Since, in particular, the contribution for the wind term from the atmospheric layer between the 10 and 0.3 hPa levels to the seasonal variations in length of day (LOD) is still missing, it is necessary to extend the top level into the upper stratosphere up to 0.3 hPa. Under the conservation of the total angular momentum of the entire Earth, variations in the oceanic angular momentum (OAM) and the hydrological angular momentum (HAM) are further significant excitation sources at seasonal time scales. Focusing on other contributions to the Earth's axial angular momentum budget, the following data are used in this study: axial atmospheric angular momentum (AAM) data derived for the 10–0.3 hPa layer from 1991 to 1997 for computing the missing wind effects; axial OAM functions as generated by oceanic general circulation models (GCMs), namely for the ECHAM3 and the MICOM models, available from 1975 to 1994 and from 1992 to 1994, respectively, for computing the oceanic contributions to LOD changes, and, concerning the HAM variations, the seasonal estimates of the hydrological contribution as derived by Chao and O'Connor [(1988) Geophys J 94: 263–270]. Using vector representation, it is shown that the vectors achieve a close balance in the global axial angular momentum budget within the estimated uncertainties of the momentum quantities on seasonal time scales. Received: 6 April 2000 / Accepted: 13 December 2000     

Degradation of native wheat straw lignin by Streptomyces viridosporus T7A

Lignin is one of the major contributing factors toward the recalcitrance of lignocellulosic biomass. Understanding the process of lignin degradation in natural biological processes will provide useful information to develop novel biomass conversion technologies. Functional group changes in the lignin entities during the process may contribute to the cellulose degradation (utilization) by the microorganisms. In this study, compositional and advanced Fourier transform infrared, pyrolysis gas chromatography/mass spectrometry and ¹³C cross polarization/magic angle spinning nuclear magnetic resonance analysis were performed to explore the mechanism of biodegradation of wheat straw by Streptomyces viridosporus T7A. The results indicated that S. viridosporus T7A removed lignin and hemicelluloses as indicated by the increased carbohydrate/lignin ratio. Significant modification of carbonyl and methoxyl groups in the complex lignin structure was also evident. Most importantly, the quantitative results showed that lignin degradation was featured by deduction of guaiacyl unit. The results provide new insight for understanding lignin degradation by bacteria.     

A Case Study on the Effects of Heterogeneous Soil Moisture on Mesoscale Boundary-Layer Structure in the Southern Great Plains, U.S.A. Part II: Mesoscale Modelling

The importance of soil moisture inputs and improved model physics in the prediction of the daytime boundary-layer structure during the Southern Great Plains Hydrology Experiment 1997 (SGP97) is investigated using the non-hydrostatic fifth-generation Pennsylvania State University/National Center for Atmospheric Research (PSU/NCAR) Mesoscale Model MM5. This is Part II of a two-part study examining the relationship of surface heterogeneity to observed boundary-layer structure. Part I focuses on observations and utilizes a simple model while Part II uses observations and MM5 modelling. Soil moisture inputs tested include a lookup table based on soil type and season, output from an offline land-surface model (LSM) forced by atmospheric observations, and high-resolution ( 800 m) airborne microwave remotely sensed data. Model physics improvements are investigated by comparing an LSM directly coupled with the MM5 to a simpler force-restore method at the surface. The scale of land surface heterogeneities is compared to the scale of their effects on boundary-layer structure.The use of more detailed soil moisture fields allowed the MM5 to better represent the large-scale (hundreds of km) and small-scale (tens of km) horizontal gradients in surface-layer weather and, to a lesser degree, the atmospheric boundary-layer (ABL) height, which was evaluated against observations measured by differential absorption lidar (DIAL). The benefits of coupling an LSM to the MM5 were not readily evident in this summertime case, with the model having particular difficulty simulating the timing of maximum surface fluxes while underestimating the depth of the mixed layer.     

Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts

Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO₂) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺) and Cu²⁺/Cu⁺ with increasing fO₂ between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO₂ implies a reciprocal relationship between a(Fe²⁺O) and a(Fe³⁺O_1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO₂ in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO₂ in silicic, but less so in mafic bulk systems.     

AIRFLOW PATTERNS FROM PHOTOGRAMMETRIC MEASUREMENTS OF WINDBLOWN TIMBER

Aerial photography may be used to quickly locate and measure the extent and severity of forest damage due to windblow. This paper describes such an application in a small area of semi-natural woodland in central Scotland after the “Great Gale” of 14th and 15th January, 1968. A 1 : 2000 scale map, showing the location and direction of fall of each windblown tree, suggests certain relationships between topography and the severity of woodland damage and gives considerable information on the airflow pattern existing over the area during the gale.     

Controlling factors of the δ 11B-pH proxy and its research direction

Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between ¹⁰B and ¹¹B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ ¹¹B_carb), and then calculation of the past pCO₂ have become important issues for the international isotope geochemistry community, and are called the δ ¹¹B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ ¹¹B) in nature (especially in bio-carbonates) and controlling factors of the δ ¹¹B-pH proxy, such as the dissociation constant of B(OH)₃ in seawater (pK_a), the δ ¹¹B of seawater (δ ¹¹B_SW), the boron isotopic fractionation factor between B(OH) ₄ ^? and B(OH)₃ (α _4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pK_a, δ ¹¹B_sw, and α _4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) ₄ ^? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ ¹¹B_carb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ ¹¹B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ ¹¹B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present.