Absolute spectrophotomery of comets 1973XII and 1975IX: II. Profiles of the Swan bands

Absolute spectrophotometric measurements of the Swan bands of two comets have been compared with computed synthetic spectra using modern Franck-Condon and Hönl-London factors, and varying rotational, vibrational, and electronic excitation temperatures. Rotational and vibrational temperatures were obtained for the comets. Although the electronic excitation temperature and the molecular column density cannot be separated, a relationship is found between these two quantities. A review is made of recent determinations of column densities for CN in comets.     

Molecular simulations of metal adsorption to bacterial surfaces

The atomic-scale interactions that occur between cations and the metal-binding cell wall components common to many gram-positive bacteria were investigated using molecular simulations techniques. We examined the adsorption of Cd and Pb onto peptidoglycan and teichoic acid components of the bacterial cell wall using classical energy force field methods. Within the framework of molecular mechanics and the Cerius² modeling software, we used energy minimization, conformational analysis, and molecular dynamics to examine the different components of the cell wall and to determine relative binding energies and structural configurations of the cell wall components, both with and without the metals present. Electronic structure calculations of representative metal-organic complexes validate the more practical classical methods required in simulating the large number of atoms associated with the cell wall components. The classical force field simulations were conducted in both gas phase and solvated periodic cells. Force field-based simulation techniques can adequately describe the interactions of Cd with the cell wall, defining both metal ion coordinations and binding distances. However, the classical force field approach is inconsistent in describing the observed Pb-cell wall interactions due to possible limitations in the force field parameters, the propensity for Pb to form hydroxides at circumneutral pH, or the dominance of other adsorption mechanisms.     

Effect of supplemental feeding on spatial distribution and browse utilization by white-tailed deer in semi-arid rangeland

We investigate the risk that supplemental feeding of white-tailed deer (Odocoileus virginianus) to improve trophy quality may degrade rangeland through overutilization of forage plants near the feeders. We divided a South Texas ranch into 6 areas (each 1100 ha). Supplemental feed was provided year-round in a centrally placed feeder in 3 areas, no supplement was provided in the 3 control areas. Radio-telemetry collars were fitted on 2 bucks and 2 does in each area. Spatial distribution of these deer was assessed using the CALHOME program. Feed supplementation did not alter home range size of does but did reduce their 50% core area. Bucks without supplemental feed showed 2 spatial strategies; sedentary bucks had home range distributions similar to supplemented bucks, while commuter bucks moved to supplemented areas during the breeding season. Browsing pressure near feeders and control sites was assessed by measuring consumption of seedlings set in arrays radiating from feeders and control points. Deer browsing was heavier near feeders than at the control sites, and the probability of a seedling being browsed increased with proximity to the feeder. We caution against long-term supplemental feeding in fixed locations because of the potential for localized range degradation around the feeders.     

Post-depositional 137Cs Mobility in the Sediments of Three Shallow Coastal Lagoons, SW England

We present ¹³⁷Cs profiles for three low lying coastal lagoons in Southwest England that show a decline in activity with sediment depth. ¹³⁷Cs inventories are lower than expected by comparison with local reference inventories despite the fact that sampling was undertaken in the deep-water zone of each lake where sediment and ¹³⁷Cs focusing would be expected. At all three locations, lake sediment ⁷Be and unsupported ²¹⁰Pb (²¹⁰Pb_un) inventories are not significantly lower than the local reference inventory. ¹³⁷Cs inventories in the study cores range from 38 to 95% of local reference inventories. The standing water level and mud: water interface at two sites are below maximum tide level and, at all three sites, salinity increases significantly in the water columns between low and high tide and in the pore waters of the underlying sediments. We suggest that the difference in hydrostatic pressure between sea level and standing water levels in the lagoons forces salt water up through the sediment column and that monovalent cations (especially Na⁺ and K⁺) replace ¹³⁷Cs on exchange sites leading to the upward migration and loss of ¹³⁷Cs. Rising sea levels may therefore contribute to remobilisation and release of ¹³⁷Cs to the aquatic environment from the sediments of coastal lagoons.     

Crustal structure across the Grand Banks–Newfoundland Basin Continental Margin – II. Results from a seismic reflection profile

New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins.     

Mining Association Rules in Spatio-Temporal Data: An Analysis of Urban Socioeconomic and Land Cover Change

This research demonstrates the application of association rule mining to spatio‐temporal data. Association rule mining seeks to discover associations among transactions encoded in a database. An association rule takes the form A→B where A (the antecedent) and B (the consequent) are sets of predicates. A spatio‐temporal association rule occurs when there is a spatio‐temporal relationship in the antecedent or consequent of the rule. As a case study, association rule mining is used to explore the spatial and temporal relationships among a set of variables that characterize socioeconomic and land cover change in the Denver, Colorado, USA region from 1970–1990. Geographic Information Systems (GIS)‐based data pre‐processing is used to integrate diverse data sets, extract spatio‐temporal relationships, classify numeric data into ordinal categories, and encode spatio‐temporal relationship data in tabular format for use by conventional (non‐spatio‐temporal) association rule mining software. Multiple level association rule mining is supported by the development of a hierarchical classification scheme (concept hierarchy) for each variable. Further research in spatio‐temporal association rule mining should address issues of data integration, data classification, the representation and calculation of spatial relationships, and strategies for finding ‘interesting’ rules.     

Anthropogenic Impacts on Summer Precipitation in Central Arizona,U.S.A.

This article explores the possibility of urbanization‐ and irrigation‐induced increases in summer precipitation totals in central Arizona. Maximum precipitation impacts are hypothesized to occur downwind of the Phoenix area in the Lower Verde basin. Results from statistical tests indicate that summer precipitation totals in the Lower Verde basin are greater than totals in nearby basins. Precipitation totals in the basin also appear to be equivalent to totals at more monsoon‐impacted stations in eastern Arizona. While this research is preliminary, the results do provide encouraging evidence of the existence of anthropogenically enhanced summer precipitation in central Arizona.     

Lower-crustal rifting in the Rukwa Graben, East Africa

An M_w 5.9 earthquake occurred in the Lake Rukwa rift, Tanzania, on 1994 August 18, and was well recorded by 20 broad-band seismic stations at distances of 160 to 800 km and 21 broad-band stations at teleseismic distances. The regional and teleseismic waveforms have been used to investigate the source characteristics of the main shock, and also to locate aftershocks that occurred within three weeks of the main shock. Teleseismic body-wave modelling yields the following source parameters for the main shock: source depth of 25 ± 2 km, a normal fault orientation, with a horizontal tension axis striking NE-SW and an almost vertical pressure axis (Nodal Plane I: strike 126°–142°, dip 63°–66°, and rake 280°–290°; Nodal Plane II: strike 273°–289°, dip 28°–31°, and rake 235°–245°), a scalar moment of 4.1 times 10¹⁷ N m, and a 2 s impulsive source time function. Four of the largest aftershocks also nucleated at depths of 25 km, as deduced from regional sPmp–Pmp times. The nodal planes are broadly consistent with the orientation of both the Lupa and Ufipa faults, which bound the Rukwa rift to the northeast and southwest, respectively. The rupture radius of the main shock, assuming a circular fault, is estimated to be 4 km with a corresponding stress drop of 6.5 MPa. Published estimates of crustal thickness beneath the Rukwa rift indicate that the foci of the main shock and aftershocks lie at least 10 km above the Moho. The presence of lower-crustal seismicity beneath the Rukwa rift suggests that the pre-rift thermal structure of the rifted crust has not been strongly modified by the rifting, at least to depths of 25 km.     

Seasonal and inter-annual relationships between vegetation and climate in central New Mexico, USA

Linear correlations between seasonal and inter-annual measures of meteorological variables and normalized difference vegetation index (NDVI) are calculated at six nearby yet distinct vegetation communities in semi-arid New Mexico, USA Monsoon season (June–September) precipitation shows considerable positive correlation with NDVI values from the contemporaneous summer, following spring, and following summer. Non-monsoon precipitation (October–May), temperature, and wind display both positive and negative correlations with NDVI values. These meteorological variables influence NDVI variability at different seasons and time lags. Thus vegetation responds to short-term climate variability in complex ways and serves as a source of memory for the climate system.     

Turbulent flow over a dune: Green River,Colorado

Detailed echo‐sounder and acoustic Doppler velocimeter measurements are used to assess the temporal and spatial structure of turbulent flow over a mobile dune in a wide, low‐gradient, alluvial reach of the Green River. Based on the geometric position of the sensor over the bedforms, measurements were taken in the wake, in transitional flow at the bedform crest, and in the internal boundary layer. Spatial distributions of Reynolds shear stress, turbulent kinetic energy, turbulence intensity, and correlation coefficient are qualitatively consistent with those over fixed, two‐dimensional bedforms in laboratory flows. Spectral and cospectral analysis demonstrates that energy levels in the lee of the crest (i.e. wake) are two to four times greater than over the crest itself, with minima over the stoss slope (within the developing internal boundary layer). The frequency structure in the wake is sharply defined with single, dominant peaks. Peak and total spectral and cross‐spectral energies vary over the bedform in a manner consistent with wave‐like perturbations that ‘break’ or ‘roll up’ into vortices that amalgamate, grow in size, and eventually diffuse as they are advected downstream. Fluid oscillations in the lee of the dune demonstrate Strouhal similarity between laboratory and field environments, and correspondence between the peak frequencies of these oscillations and the periodicity of surface boils was observed in the field. Copyright © 2005 John Wiley & Sons, Ltd.