Determination of Trace Elements in the Quartz Reference Material UNS-SpS and in Natural Quartz Samples by ICP-MS

A procedure for the digestion and analysis of quartz samples was developed to measure trace element concentrations in natural quartz. The certified glass sand reference material UNS-SpS was chosen to assess the precision, accuracy and detection limit of the analytical method. Quartz was digested with HF/HNO₃ in a closed glassy carbon vessel and analysed by means of quadrupole ICP-MS with external calibration. Analyte concentrations of the sand UNS-SpS were compared with certified and other values from the literature. The abundances of a number of elements (Pr, Gd, Ho and Er) in the reference material are reported here for the first time. The procedure was then applied to three quartz samples from different geological settings to show that trace element data by ICP-MS can distinguish the origin of the sample.     

Depth colonization of eelgrass (<Emphasis Type="Italic">Zostera marina</Emphasis>) and macroalgae as determined by water transparency in Danish coastal waters

We present a comparative analysis of lower depth limits for growth of eelgrass, large brown algae and other macroalgae measured by SCUBA-diving along 162 transects in 27 Danish fjords and coastal waters, coupled to 1,400 data series of water chemistry (especially nitrogen) and Secchi depth transparency collected between March and October. Danish coastal waters are heavily eutrophied and characterized by high particle concentrations, turbid water and lack of macrophyte growth in deep water. Median values are 3.6 m for Secchi depth and median lower-depth limits are 4.0 m for eelgrass, 5.3 m for brown algae and 5.0 m for other macroalgae. Depth limits for growth of eelgrass and macroalgae increase linearly with transparency in the coastal waters. The relationships are highly significant (p<10⁻⁶) and transparency accounts for about 60% of the variability of depth limits. Eelgrass extends approximately to half the maximum depth of macroalgae, presumably because of greater respiratory costs to maintain the below-ground rhizomes and roots of eelgrass, which often constitutes half the plant weight. As a reflection of the importance of total nitrogen (TN) in controlling phytoplankton biomass and thus Secchi depth in coastal marine waters, we found that TN could explain 48–73% of the variation in depth limits of eelgrass and macroalgae, according to a multiplicative model (Y=aX^b). As with Secchi depth, the relationship to eelgrass showed a lower slope, reflecting the higher respiratory costs of eelgrass. The models show great sensitivity and a profound quantitative response with proportional effects on Secchi depth and depth limits when total-N concentrations are reduced.     

Mineral paragenesis of the Kalahari managanese field, South Africa

The mineralogy of the managanese ores of the giant Paleoproterozoic Kalahari manganese deposit of the Transvaal Supergroup has been subject of many studies and up to now 135 different ore and gangue minerals have been described, of which eight represent new mineral species. Through correlation of different mineral assemblages with specific geological events and by determining relative ages of minerals in outcrop, hand specimen and under the microscope an attempt is made in this publication to construct a paragenetic sequence for this complex mineral assemblage. Sedimentation and early diagenesis of the Hotazel Formation, composed of interbedded iron formation and braunite lutite, was followed by low-grade metamorphism and associated stratabound metasomatism. Braunite lutite of sedimentary origin, comprising 97% of the total ore reserve, is composed of braunite, hematite and kutnahorite, and abundant early diagenetic kutnahorite and manganoan calcite forming laminae and ovoids. Fluid flow during late diagenesis or lower greenschist facies metamorphism led to stratabound metasomatic oxidation of Mn-bearing carbonates to hausmannite and Mn-poor calcite. Three structurally controlled hydrothermal alteration events succeed metamorphism. These events are referred to as Wessels, Mamatwan and Smartt events. The Wessels alteration event is the oldest of the three events and it is of great economic importance because virtually all of the high-grade ore (> 42% Mn), 3% of the total ore reserve, formed during this event through alteration of carbonate-rich low-grade Mamatwan-type ore (braunite lutite) to high-grade, carbonate-poor Wessels-type manganese ore. This Wessels hydrothermal alteration event took place in the northwestern part of the Kalahari deposit, associated with a system of major north-south- and minor east-west-striking normal faults. The Mamatwan alteration event is observed throughout the Kalahari manganese deposit but alteration is very localized. Reduction halos and discolouration of braunite lutite around fracture or joint-hosted sulphide-carbonate mineralization are typical of the Mamatwan alteration event. In contrast, the Smartt alteration event is characterized by oxidation of braunite lutite and the formation of todorokite and manganomelane. Syn- and Post-Kalahari supergene alteration has taken place below the suboutcrop of the Hotazel Formation against the calcretized sediments of the Cenozoic Kalahari Formation. Cryptomelane and pyrolusite are the predominant products of surficial weathering.     

Generation and regulation of summer runoff in a boreal flat fen

Hydrometric measurements, electrical conductivity, water isotopic and hydrochemical components of stream water were used to study summer runoff generation in a flat fen. Different processes generated runoff at low- and high-flows. At storm-flows, fen runoff was generated from overland flow, originating from upland surface water. Temporary storage of water on the fen surface attenuated and delayed flow peaks. At low-flows, runoff at the fen outlet was generated from shallow subsurface flow in the Acrotelm. During low-flow periods, water originated mainly from peat storage water while during episodic events the wetland water storage was renewed by inflowing stream water. Assessment and modeling of hydrological effects of peatlands should be performed separately for low-flows and high-flows, based on the dominating runoff generating processes. Attenuation and retardation of storm-flows in fens by temporary surface storage will depend on the geometric properties of both storage sections and sections controlling outflow. A routing reservoir model adapted for flat fens can be used for simulation of attenuation and retardation in runoff events, and it is suggested that the model concept should be tested for a broader range of peatlands.     

The deglaciation of Upernavik trough,West Greenland,and its Holocene sediment infill: processes and provenance

Under glacial climates, continental ice sheets such as, e.g., the Greenland Ice Sheet, extended onto the continental shelves and often carved out deep cross-shelf troughs. The sedimentary infill of such troughs commonly is a product of the complex interactions between the ice sheets, largely driving sediment input into the ocean, and the surrounding water masses. Off West Greenland, research has focused on the Disko and Uummannaq troughs, leaving the northerly adjacent Upernavik trough relatively understudied. Hence, neither the chronology of deglaciation nor the details of its postglacial infill are sufficiently well understood. Here, we combine computed tomography image-derived information with geochemical and granulometric data from four sediment cores recovered from the Upernavik trough that point to (i) deglaciation of the mid-shelf probably around 13.4 cal. ka BP that was most likely driven by a northward advection of warmer Atlantic waters during the Bølling–Allerød, (ii) the presence of widespread mass wasting around 8 cal. ka BP on the inner shelf and (iii) the complex interplay between various modes of sediment input, transport and deposition under hemipelagic sedimentation afterwards. While this interplay complicates provenance studies, we identify two major sediment delivery mechanisms that control transport and deposition from four sediment source areas. Through the Early Holocene the relative contributions of sediments from the various sources changed from a predominantly local origin to more southerly sources, mainly driven by decreasing input from the local sources. The integration of relative sediment source contributions with varying sedimentation rates challenges previous studies postulating intensified sediment delivery from the south through a greater influence of the West Greenland Current and highlights the need for the integration of sediment input and transport mechanisms into provenance studies in the area.     

Carbonate diagenesis and feldspar alteration in fracture-related bleaching zones (Buntsandstein,central Germany): possible link to CO<Subscript>2</Subscript>-influenced fluid–mineral reactions

Fracture-related bleaching of Lower Triassic Buntsandstein red beds of central Germany was related to significant carbonate diagenesis and feldspar alteration caused by CO₂-rich fluids. Using cathodoluminescence microscopy and spectroscopy combined with electron microprobe analysis and stable carbon isotope study, two major fluid–mineral interactions were detected: (1) zoned, joint-filling calcites and zoned pore-filling calcite cements, the latter replacing an earlier dolomite, were formed during bleaching. During the calcite formation and dolomite–calcite transformation, iron was incorporated into the calcite cement crystal cores due to Fe availability from the coeval bleaching. The dedolomitisation was ultimately associated with a volume increase. The related permeability decrease implies a certain degree of sealing and increasing retention of CO₂, and the volume increase offers a minor CO₂ sink. Carbonate-rich sandstone, therefore, can provide advantages for underground CO₂ storage especially when situated in the fringes of the reservoir. (2) Alkali-feldspar alteration due to the bleaching fluids is reflected in cathodoluminescence spectra predominantly by the modulation of a brown luminescence emission peak (~620 nm). This peak represents a newly discovered effect related to alkali-feldspar alteration not solely associated with bleaching. Its modulation by the bleaching is interpreted to be due to Na depletion or a lattice defect in the Si–O bonds of the SiO₄-tetrahedron. Alteration reflected by this luminescence feature has a destructive effect on the feldspars implying the possibility of diminished rock integrity due to bleaching and, hence, CO₂-rich fluids. Two further CL spectral changes related to bleaching occur, (a) decreased intensity between around 570 nm assigned to Mn-depletion, and (b) increased amplitude and wavelength shift of the red (~680 nm) band. Converging evidence from carbonate and feldspar diagenesis, stable carbon isotope data and analysis of fracture directions suggests that CO₂ fluids contributed to a significant extent to the bleaching phenomena and alteration in the studied Buntsandstein strata.     

Evolutionary synthesis models for galaxy transformation in clusters

The galaxy population in rich local galaxy clusters shows a ratio of one quarter elliptical galaxies, two quarters S0 galaxies, and one quarter spiral galaxies. Observations of clusters at redshift 0.5 show a perspicuously different ratio, the dominant galaxy type are spiral galaxies with a fraction of two quarters while the number of S0 galaxies decreases to a fraction of one quarter (Dressler et al. 1997). This shows an evolution of the galaxy population in clusters since redshift 0.5 and it has been suspected that galaxy transformation processes during the infall into a cluster are responsible for this change. These could be merging, starburst or ram-pressure stripping. We use our evolutionary synthesis models to describe various possible effects of those interactions on the star formation of spiral galaxies infalling into clusters. We study the effects of starbursts of various strengths as well as of the truncation of star formation at various epochs on the color and luminosity evolution of model galaxies of various spectral types. As a first application we present the comparison of our models with observed properties of the local S0 galaxy population to constrain possible S0 formation mechanisms in clusters. Application to other types of galaxies is planned for the future. This revised version was published online in August 2006 with corrections to the Cover Date.     

Marine‐target craters on Mars? An assessment study

Abstract— Observations of impact craters on Earth show that a water column at the target strongly influences lithology and morphology of the resultant crater. The degree of influence varies with the target water depth and impactor diameter. Morphological features detectable in satellite imagery include a concentric shape with an inner crater inset within a shallower outer crater, which is cut by gullies excavated by the resurge of water. In this study, we show that if oceans, large seas, and lakes existed on Mars for periods of time, marine‐target craters must have formed. We make an assessment of the minimum and maximum amounts of such craters based on published data on water depths, extent, and duration of putative oceans within “contacts 1 and 2,” cratering rate during the different oceanic phases, and computer modeling of minimum impactor diameters required to form long‐lasting craters in the seafloor of the oceans. We also discuss the influence of erosion and sedimentation on the preservation and exposure of the craters. For an ocean within the smaller “contact 2” with a duration of 100,000 yr and the low present crater formation rate, only ?1–2 detectable marine‐target craters would have formed. In a maximum estimate with a duration of 0.8 Gyr, as many as 1400 craters may have formed. An ocean within the larger “contact 1‐Meridiani,” with a duration of 100,000 yr, would not have received any seafloor craters despite the higher crater formation rate estimated before 3.5 Gyr. On the other hand, with a maximum duration of 0.8 Gyr, about 160 seafloor craters may have formed. However, terrestrial examples show that most marine‐target craters may be covered by thick sediments. Ground penetrating radar surveys planned for the ESA Mars Express and NASA 2005 missions may reveal buried craters, though it is uncertain if the resolution will allow the detection of diagnostic features of marine‐target craters. The implications regarding the discovery of marine‐target craters on Mars is not without significance, as such discoveries would help address the ongoing debate of whether large water bodies occupied the northern plains of Mars and would help constrain future paleoclimatic reconstructions.