Raman spectroscopic and calorimetric observations on natural gas hydrates with cubic structures I and II obtained from Lake Baikal

This study reports measurements of the Raman spectra of Lake Baikal gas hydrates and estimations of the hydration number of methane-rich samples. The hydration number of gas hydrates retrieved from the southern Baikal Basin (crystallographic structure I) was approx. 6.1. Consistent with previous results, the Raman spectra of gas hydrates retrieved from the Kukuy K-2 mud volcano in the central Baikal Basin indicated the existence of crystallographic structures I and II. Measurements of the dissociation heat of Lake Baikal gas hydrates by calorimetry (from the decomposition of gas hydrates to gas and water), employing the hydration number, revealed values of 53.7–55.5?kJ?mol^–1 for the southern basin samples (structure I), and of 54.3–55.5?kJ?mol^–1 for the structure I hydrates and 62.8–64.2?kJ?mol^–1 for the structure II hydrates from the Kukuy K-2 mud volcano.     

Thermal anomalies associated with shallow gas hydrates in the K-2 mud volcano, Lake Baikal

Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m^–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.     

The geochemistry of deepwater particulate matter over the hydrothermal field at 9°d50′ N (the East Pacific Rise)

The results of geochemical studies of particulate matter in the water mass over the hydrothermal field at 9°50′ N on the East Pacific Rise are presented. The particulate matter was tested in background waters, in the buoyant plume, and in the near-bottom waters. The contents of Si, Al, P, C_org, Fe, Mn, Cu, Zn, Ni, Co, As, Cr, Cd, Pb, Ag, and Hg were determined. No definite correlations were found between the ele-ments in the background waters. Many of the chemical elements correlated with Fe and associated with its oxyhydroxides in the buoyant plume. In the near-bottom waters, microelements are associated with Fe, Zn, and Cu (probably, to their sulfides formed under fluid mixing with seawater). The matter precipitated in a sed-imentation trap was similar to the near-bottom particulate matter in the elemental composition.     

On the geologic structure of the Explora Escarpment (Weddell Sea,Antarctica) revealed by satellite and Shipboard data evaluation

Bathymetric, gravity, and magnetic data from Antarctic expeditions with RV POLARSTERN and satellite altimeter data from the Geosat Geodetic Mission are analysed using methods from geostatistics and geophysical inverse theory.The Explora Escarpment represents the edge between the Antarctic Continental Shelf and the Weddell Abyssal Plain. It is an important link in the reconstruction of Gondwana breakup, but a feature as large as the 2000 m deep Wegener Canyon was only discovered in 1984, when extensive bathymetric, gravimetric, and magnetic surveys with RV POLARSTERN began.Geostatistics, the theory of regionalized variables, is applied to integrate dense surveys of Wegener Canyon and sparse observations in adjacent areas into maps with full coverage of the 230 km by 330 km area at 10°–20° W/70°–72° S. The resultant highresolution bathymetric and gravity maps reveal detailed structures of the Explora Escarpment. Using geophysical inversion, the gravity terrain effect is calculated. Satellite data are used for their better coverage, but have much lower resolution. Nevertheless, the structures of Wegener Canyon and other more prominent features appear with surprisingly good correlation also in the Geosat altimeter data. While it was initially supposed that Wegener Canyon is purely an erosional structure, the magnetic map now provides evidence of the canyon's tectonic origin.     

Concentrations of unsubstituted polynuclear aromatic hydrocarbons in bay mussels (Mytilus edulis) from Oregon, USA

Concentrations of fifteen unsubstituted polynuclear aromatic hydrocarbons (PNAH) were measured in Mytilus edulis from two sites in Yaquina Bay, Oregon, USA, during 1979–1980. There were significant differences in PNAH levels between the two populations. The average total concentration in mussels inhabiting the more industrialized bayfront was 986·2 μg/kg compared with 273·9 μg/kg in mussels from a more remote site across the bay. Substantial differences were found in the concentrations of different PNAH in M. edulis examined during this study. The smaller more water soluble, compounds were concentrated to one or two orders of magnitude above the larger, less soluble PNAH.     

Environmental overview of Eckernförde Bay,northern Germany

This environmental overview of Eckernförde Bay (northern Germany) summarizes the results of previous studies relevant to the Office of Naval Research's Coastal Benthic Boundary Layer (CBBL) Baltic field exercise conducted during 1993–1994. Significant environmental characteristics include the following: (1) surface sediment distribution is related to water depth, dictated primarily by hydrodynamic reworking of older glacial deposits; (2) the origin and characteristics of small-scale sedimentary structures depend on storm-generated waves and currents; (3) the proximity of the sea surface and sediment —water interface results in a pelagic—benthic coupling that drives biogeochemical processes and produces organicrich, acoustically turbid sediments; and (4) the bay floor is complicated topographically by pockmarks and manmade sedimentary structures.     

Sensitivity to stress of the estuarine bivalve Macoma balthica from areas between the Netherlands and its southern limits (Gironde)

Variation in the sensitivity to stress of Macoma balthica was measured in several French and Dutch estuaries. For adult and juvenile Macoma balthica exposed to copper under conditions of starvation, differences in mortality rate, condition, glycogen, burrowing rate and copper content were assessed. No significant differences were observed between adults and juveniles; the influence of treatment and origin was always evident. Animals from the most southern estuaries, Loire and Gironde, near to the species's southern limit of distribution, showed, in the field, the strongest deviations for the ecophysiological traits measured, and were in the experiments the most sensitive to stress.     

Tectonic setting of the Azores Plateau deduced from a OBS survey

The studies of Azores seismicity generally show shocks with either normal faulting or right-lateral strike-slip along the ESE direction, compatible with a eastward relative motion of the Eurasian (EU) relative to the African (AF) plate. However, the 1 January 1980 earthquake was interpreted as a clear left-lateral strike-slip shock along the N150E direction. This pattern is difficult to explain in terms of the relative motion between the EU, AF and North American (NA) plates: all available models for the present day movement of this triple junction fail to explain the regional variability in the stress conditions of the area. Here we present data from a 34-day long Ocean Bottom Seismograph array deployment. We show that the seismicity is distributed along a band aligned with the island chain itself, and is concentrated along several faults with an approximate N150E strike, cutting the Azores plateau in all the area covered by the OBS network. The combination of these new results with other geophysical data permits us to conclude that the tectonic setting of the Azores plateau is characterised by the existence of two sets of faults, in the N120E and N150E directions, defining several crustal blocks, whose relative motion accommodates the interaction of the three megaplates. The deformation of these tectonic blocks is probably driven by the shear between the EU and AF plates. This model explains well the spatial variability of the stress conditions in the Azores domain, the combination of dextral and sinistral strike slip mechanisms and the observed seismotectonics of the Azores islands.     

Transverse vibrations of a rectangular cantilever plate with thickness varying in a discontinuous fashion

A numerical solution is obtained for the title problem by means of the popular finite element method. An experimental investigation of the problem is also presented for plates of square planform. The agreement between theoretical and experimental values is very good in the case of the fundamental frequency, and reasonably good when the second and third normal modes of transverse vibration are considered. It is concluded that beneficial effects are obtained in the sense that one generates a lighter structural element with higher fundamental frequency of transverse vibration. Hence, dynamic stiffening is achieved.