Exploration geochemistry—Distribution of elements and recognition of anomalies

The exploration geochemist faces a serious problem in reconciling theoretical statistics with the empirical distribution of elements in materials in the earth's crust. The results of computer-simulation experiments being conducted by the Exploration Geochemistry Group at the University of New Brunswick illustrate some of the problems of the relation between frequency distributions and spatial distributions of elements and raise some interesting questions about sampling patterns and physical size of samples. Most importantly, the simulation experiments and empirical examples support the contention that attempts to make an assumption of normality more efficient by performing log transformations on positively skewed data may defeat the purpose of statistical analysis for exploration work. New developments in computer-data presentation and interpretation, including population sorting and classification, illustrate the increasing use of the computer in exploration geochemistry.     

In situ U–Pb SIMS (IN-SIMS) micro-baddeleyite dating of mafic rocks: Method with examples

An in situ U–Pb SIMS (IN-SIMS) method to date micro-baddeleyite crystals as small as 3 μm is presented with results from three samples that span a variety of ages and geologic settings. The method complements ID-TIMS geochronology by extending the range of dateable crystals to sizes smaller than can be recovered by physical separation. X-ray mapping and BSE imaging are used to locate target grains in thin section, followed by SIMS analysis on a CAMECA ims 1270, using the field aperture in the transfer column to screen out ions from host phases. Internal age precisions for the method are anticipated to range from 0.1% for Precambrian rocks to 3–7% for Phanerozoic rocks. Results establish a 2689 ± 5 Ma age for mafic dikes in the Wyoming craton, USA, a 1540 ± 30 Ma age for a subaerial lava flow from the Thelon Basin of northern Canada, and a 457 ± 34 Ma age for mafic dikes in the platform sequence of southeastern Siberia. The method is ideal for relatively non-destructive dating of small samples such as extraterrestrial rocks and precious terrestrial samples.     

The impact of precipitation on speed–flow relationships along a UK motorway corridor

Although the fundamental traffic diagram provides the characteristics of a typical road traffic speed–flow relationship, little consideration has been given to the impact of adverse weather conditions on the relationship and the subsequent impact on local speed–flow. For the first time, this study uses precipitation radar along with a state-of-the art traffic information system to ascertain the relationship between speed–flow and precipitation on a UK transport corridor at the local (junction to junction) scale. It is evident that precipitation causes a significant reduction in speed and maximum flow on many links of the corridor as well as a downward reduction in the overall speed-flow relationship. With increased instances of heavy precipitation predicted in the UK as a result of climate change, these findings highlight the subsequent impact on journey travel times and associated economic costs.     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Canada-France-Hawaii Telescope's “redeye” infrared camera system: Array performance

The Canada-France-Hawaii Telescope (CFHT) has recently commissioned two facility infrared cameras for astronomical observations in the 1.0 to 2.5 micron region. These cameras use NICMOS3 256×256 pixel arrays fabricated from Hg:Cd:Te. We report here on array performance and discuss two unique features of these arrays, namely corner glow and residual images. We have developed techniques for reducing corner glow and a method of clearing residual image charge. We discuss our techniques and their side effects.     

Estimation of ocean-bottom properties by matched-field inversion ofacoustic field data

A method for estimating properties of the ocean bottom such as bathymetry and geoacoustic parameters such as sound speed, density and attenuation, using matched-field inversion is considered. The inversion can be formulated as an optimization problem by assuming a discrete model of unknown parameters and a bounded search space for each parameter. The optimization then involves finding the set of parameter values which minimizes the mismatch between the measured acoustic field and modeled replica fields. Since the number of possible models can be extremely large, the method of simulated annealing, which provides an efficient optimization that avoids becoming trapped in suboptimal solutions, has been used. The matching fields are computed using a normal mode model. In inversions for range-dependent parameters, the adiabatic approximation is employed. This allows mode values to be precomputed for a grid of parameter values and stored in look-up tables for fast reference, which greatly improves computational efficiency. Synthetic inversion examples are presented for realistic range-independent and range-dependent environments     

The Growth of Facular Area Surrounding Large, Decaying Sunspots

In a previous paper, we investigated the facular area around 31 decaying sunspots of varied size. The growth of facular area as a function of spot decay was marginally significant (r ² = 0.1255, p = 0.05). Using new data, this paper examines the change in facular area surrounding large decaying sunspots some of which grew very rapidly. The data are from full-disk photometric images taken with CFDT2 (2.5″ pixels). For 10 sunspots, we find a statistically significant increase in facular area as a function of the spot decay rate with a regression coefficient, squared, of r ² = 0.611 (p < 0.02).     

Refractory Black Carbon Results and a Method Comparison between Solid-state Cutting and Continuous Melting Sampling of a West Antarctic Snow and Firn Core

This work presents the refractory black carbon(rBC)results of a snow and firn core drilled in West Antarctica(79°55'34.6"S,94°21'13.3"W)during the 2014?15 austral summer,collected by Brazilian researchers as part of the First Brazilian West Antarctic Ice Sheet Traverse.The core was drilled to a depth of 20 m,and we present the results of the first 8 m by comparing two subsampling methods—solid-state cutting and continuous melting—both with discrete sampling.The core was analyzed at the Department of Geological Sciences,Central Washington University(CWU),WA,USA,using a single particle soot photometer(SP2)coupled to a CETAC Marin-5 nebulizer.The continuous melting system was recently assembled at CWU and these are its first results.We also present experimental results regarding SP2 reproducibility,indicating that sample concentration has a greater influence than the analysis time on the reproducibility for low rBC concentrations,like those found in the Antarctic core.Dating was carried out using mainly the rBC variation and sulfur,sodium and strontium as secondary parameters,giving the core 17 years(1998?2014).The data show a well-defined seasonality of rBC concentrations for these first meters,with geometric mean summer/fall concentrations of 0.016μg L^?1 and geometric mean winter/spring concentrations of 0.063μg L^?1.The annual rBC concentration geometric mean was 0.029μg L^?1(the lowest of all rBC cores in Antarctica referenced in this work),while the annual rBC flux was 6.1μg m^?2 yr^?1(the lowest flux in West Antarctica records so far).     

The Chinese comet observation in AD 773 January

The strong ¹⁴C increase in the year AD 774/5 detected in one German and two Japanese trees was recently suggested to have been caused by an impact of a comet onto Earth and a deposition of large amounts of ¹⁴C into the atmosphere (Liu et al. 2014). The authors supported their claim using a report of a historic Chinese observation of a comet ostensibly colliding with Earth's atmosphere in AD 773 January. We show here that the Chinese text presented by those authors is not an original historic text, but that it is comprised of several different sources. Moreover, the translation presented in Liu et al. is misleading and inaccurate. We give the exact Chinese wordings and our English translations. According to the original sources, the Chinese observed a comet in mid January 773, but they report neither a collision nor a large coma, just a long tail. Also, there is no report in any of the source texts about “dust rain in the daytime” as claimed by Liu et al. (2014), but simply a normal dust storm. Ho (1962) reports sightings of this comet in China on AD 773 Jan 15 and/or 17 and in Japan on AD 773 Jan 20 (Ho 1962). At the relevant historic time, the Chinese held that comets were produced within the Earth's atmosphere, so that it would have been impossible for them to report a “collision” of a comet with Earth's atmosphere. The translation and conclusions made by Liu et al. (2014) are not supported by the historical record. Therefore, postulating a sudden increase in ¹⁴C in corals off the Chinese coast precisely in mid January 773 (Liu et al. 2014) is not justified given just the ²³⁰Th dating for AD 783 ± 14. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)