Radiation-enhanced release of uranium from accessory minerals in crystalline rocks

Implantation of low energy (~ 1 keV/amu) Pb ions, simulating α-recoils, greatly increases the dissolution rate of U-bearing minerals in aqueous solutions above a critical dose $\text{~5 × 10}{}^{12}\text{ions·cm}{}^{\mathrm{?2}}$. A Monte-Carlo code of etching indicates that this phenomenon corresponds to a percolation threshold due to the accumulation of ion-induced defects above a critical concentration. Such a radiationenhanced dissolution could be produced by α-recoil damage in U-rich accessory minerals of sufficient U-content and/or age. Therefore, this process could be the primary source of this element in the formation of U ores associated with crystalline rocks.     

A peculiar distribution of radial velocities of faint radio-galaxies with 13.0≤m corr≤15.5

A sample of 41 radio-galaxies with 13.0m _corr15.5 has been analyzed to test the angular redshift anisotropy discovered on Sc I galaxies by Rubin, Rubin and Ford. The sample does not present their anisotropy but contains an even more curious distribution of radial velocities which suggests that the Rubin-Ford effect results from an anomalous redshift of light when it travels through clusters of galaxies.     

Observation of isotopes in the water cycle—the Swiss National Network (NISOT)

The Swiss National Network for the Observation of Isotopes in the Water Cycle (NISOT) includes eleven precipitation, seven surface water (river) and three groundwater stations, where tritium, deuterium and oxygen-18 are monthly measured in composite samples. The network provides a good overview of the characteristic isotope signatures in recharge waters in Switzerland and of the relations between isotopes and altitude, orography and the amount of precipitation. Mixing of air water vapour and surface waters can be observed along a NW/SE cross section through the Alps. With increasing length of the data series, the network provides a valuable contribution for national and international scientific and practical applications in surface and subsurface hydrology, climatology and biology. The Swiss Geological Survey at the Federal Office for Water and Geology operates the isotope network within the legal framework of the Federal Law on the Protection of Waters and guarantees quality, access and distribution of the isotope data.     

Early diagenetic processes in coastal marine sediments disturbed by a catastrophic sedimentation event

Following a catastrophic flash flood in July 1996, as much as 50 cm of post-glacial clays were deposited in less than 2 days in the upper reaches of the Saguenay Fjord (Quebec, Canada), disrupting the normal sedimentation and diagenetic regimes. We report detailed geochemical analyses of sediments (porosity, Eh, organic and inorganic carbon, Fe and Mn reactive solid phases, and acid volatile sulfide) and porewaters (salinity, dissolved organic carbon (DOC), Fe(II), Mn(II), nitrate, ammonium, and sulfate) for seven stations located in the Saguenay Fjord. Three of these (SAG-05, SAG-09, and SAG-30) were visited in 1996 and once per year thereafter to document the chemical evolution of the sediment toward a new steady state. The flood deposits contain less organic carbon and more inorganic carbon than the indigenous fjord sediments. The flood deposit modified the distribution patterns of reactive Mn and Fe as a result of the reduction of Mn and Fe oxides delivered with the deposit and those concentrated at the now buried former sediment-water interface. Most of the Mn(II) migrated to the new sediment-water interface, where a Mn-rich layer was formed. In contrast, much of the Fe(II) was precipitated as sulfides and remained trapped at or close to the old interface. A nitrate peak developed in the porewater at the old sediment-water interface, possibly because of the oxidation of ammonia by Mn oxides. The distributions of porewater DOC within the flood deposit correlate with the distributions of dissolved Mn(II) and Fe(II), suggesting that adsorbed DOC was released when metal oxides were reduced.     

Contribution à l'étude d'une partie du bassin d'Essaouira (Maroc) par sismique réflexionContribution to part of the Essaouira Basin (Morocco) by seismic reflection

A large number of seismic reflection lines and boreholes have been carried out in the Essaouira Basin by the oil industry. The present study concentrates on the reinterpretation of these data in the restricted area of Khemis Meskala, in order to better characterise the structure of the Cretaceous aquiferous system. The reflector corresponding to the bottom of the Vraconian formation has been identified on the different seismic sections. This horizon, which marks the base of the aquiferous system, was first digitised on time migration sections and then converted to depth sections using a suitable linear velocity law. The isobath map of the bottom of the Vraconian resulting from this study images the 3D geometrical structure of this horizon and shows that it is slightly folded in domes and basins. This document will be useful for rationalising the future hydrogeological researches that will be undertaken in the Khemis Meskala area. To cite this article: M. Jaffal et al., C. R. Geoscience 334 (2002) 229–234.     

Méthodologie de l'extraction des hydrocarbures aromatiques polycycliques. Application à des sédiments de la lagune de Bizerte (Tunisie)Methodology of extraction of polycyclic aromatic hydrocarbons. Application to sediment from the Bizerte Lagoon (Tunisia)

The marine environment is very complex, with several important chemical, biological, and sedimentological interactions. Sediments constitute a reservoir for numerous pollutants, including polycyclic aromatic hydrocarbons (PAHs). PAHs are known by their mutagenic and/or carcinogenic effect. This study evaluates contamination levels in Bizerte Lagoon with respect to PAHs. The extraction efficiency of PAHs from sediment has been evaluated using Soxhlet or ultrasonic procedures, based on the recovery of an internal standard (9,10-dihydroanthracene). Several PAHs were found, including sixteen that are reported in the priority list of pollutants of the US Environmental Protection Agency (EPA). PAHs analysis was carried out by GC–FID and GC–MS for 16 samples sampled in two seasons: summer and winter. Results permit an assessment of PAHs pollution in the Bizerte Lagoon. To cite this article: N. Mzoughi et al., C. R. Geoscience 334 (2002) 893–901.     

An Assessment of the RAIM Performance of a Combined Galileo/GPS Navigation System Using the Marginally Detectable Errors (MDE) Algorithm

Integrity relates to the trust that can be placed in the correctness of information supplied by a navigation system. It includes the ability of the navigation system to provide timely warning to users when the system fails to meet its stated accuracy. Specifically, a navigation system is required to deliver a warning (alarm) when the error in the derived user position solution exceeds an allowable level (alarm limit). This warning must be issued to the user within a given period of time (time-to-alarm) and with a given probability (integrity risk). The two main approaches to monitoring the integrity of satellite navigation systems are Receiver Autonomous Integrity Monitoring (RAIM), and monitoring based on an independent network of integrity monitoring stations and a dedicated Ground Integrity Channel (GIC). More recently Satellite Autonomous Integrity Monitoring (SAIM) methods have also been investigated. This article presents the results of a study to assess the RAIM capability of the Galileo system when used alone and when combined with the Global Positioning System (GPS). The assessment was based on the Marginally Detectable Error (MDE) algorithm. The results show a significant improvement in the capability to perform RAIM using a combined Galileo/GPS system compared to the performance using the Galileo system alone. This study was supported by Alcatel Space and was a contribution to the Galileo definition studies carried out for the European Community under the GALA project. ? 2002 Wiley Periodicals, Inc.     

Glacial to Holocene implications of the new 27000-year dust record from the EPICA Dome C (East Antarctica) ice core

Insoluble dust concentrations and volume-size distributions have been measured for the new 581 m deep Dome C-EPICA ice core (Antarctica). Over the 27000 years spanned by the record, microparticle measurements from 169 levels, to date, confirm evidence of the drastic decrease in bulk concentration from the Last Glacial Maximum (LGM) to the Holocene (interglacial) by a factor of more than 50 in absolute value and of about 26 in flux. Unique new features revealed by the EPICA profile include a higher dust concentration during the Antarctic Cold Reversal phase (ACR) by a factor of 2 with respect to the Holocene average. This event is followed by a well-marked minimum that appears to be concomitant with the methane peak that marks the end of the Younger Dryas in the Northern Hemisphere. Particle volume-size distributions show a mode close to 2 7m in diameter, with a slight increase from the LGM to the Holocene; the LGM/Holocene concentration ratio appears to be dependent on particle size and for diameters from 2 to 5 7m it changes from 50 to 6. Glacial samples are characterised by well-sorted particles and very uniform distributions, while the interglacial samples display a high degree of variability and dispersion. This suggests that different modes of transport prevailed during the two climatic periods with easier penetration of air masses into Antarctica in the Holocene than during Glacial times. Assuming that southern South America remained the main dust source for East Antarctica over the time period studied, the higher dust content recorded during the ACR which preceded the Younger Dryas period, represents evidence of a change in South America environmental conditions at this time. A wet period and likely mild climate in South America is suggested at circa 11.5-11.7 kyr BP corresponding to the end of the Younger Dryas. The Holocene part of the profile also shows a slight general decrease in concentration, but with increasingly large particles that may reflect gradual changes at the source.