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941.
Frédéric Zagury 《Astrophysics and Space Science》2007,312(1-2):113-125
This study establishes that SMC, LMC and Milky Way extinction curves obey the same extinction law which depends on the 2200 Å bump size and one parameter, and generalizes the Cardelli, Clayton and Mathis (Cardelli et al., Astrophys. J. 345, 245, 1989) relationship. This suggests that extinction in all three galaxies is of the same nature. The role of linear reddening laws over all the visible/UV wavelength range, particularly important in the SMC but also present in the LMC and in the Milky Way, is also highlighted and discussed. 相似文献
942.
Thomas Pape André Bahr Janet Rethemeyer John D. Kessler Heiko Sahling Kai-Uwe Hinrichs Stephan A. Klapp William S. Reeburgh Gerhard Bohrmann 《Chemical Geology》2010,269(3-4):350-363
Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C1–C4, CO2]). Molecular ratios of LMWHC (C1/[C2 + C3] > 1000) and stable isotopic compositions of methane (δ13C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C1/C2+ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C1–C4, CO2]) relative to the other gas types and the virtual lack of 14C–CH4 indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C1–C4, CO2)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of 14C–CH4 (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area. 相似文献
943.
Fleurice Parat François Holtz Miloš René Renat Almeev 《Contributions to Mineralogy and Petrology》2010,159(3):331-347
The equilibrium phase relations of a mafic durbachite (53 wt.% SiO2) from the Třebíč pluton, representative of the Variscan ultrapotassic magmatism of the Bohemian Massif (338–335 Ma), have
been determined as a function of temperature (900–1,100°C), pressure (100–200 MPa), and H2O activity (1.1–6.1 wt.% H2O in the melt). Two oxygen fugacity ranges were investigated: close to the Ni–NiO (NNO) buffer and 2.6 log unit above NNO
buffer (∆NNO + 2.6). At 1,100°C, olivine is the liquidus phase and co-crystallized with phlogopite and augite at 1,000°C for
the whole range of investigated pressure and water content in the melt. At 900°C, the mineral assemblage consists of augite
and phlogopite, whereas olivine is not stable. The stability field of both alkali feldspar and plagioclase is restricted to
low pressure (100 MPa) at nearly water-saturated conditions (<3–4 wt.% H2O) and T < 900°C. A comparison between experimental products and natural minerals indicates that mafic durbachites have a near-liquidus
assemblage of olivine, augite, Ti-rich phlogopite, apatite and zircon, followed by alkali feldspar and plagioclase, similar
to the mineral assemblage of minette magma. Natural amphibole, diopside and orthopyroxene were not reproduced experimentally
and probably result from sub-solidus reactions, whereas biotite re-equilibrated at low temperature. The crystallization sequence
olivine followed by phlogopite and augite reproduces the sequence inferred in many mica-lamprophyre rocks. The similar fractionation
trends observed for durbachites and minettes indicate that mafic durbachites are probably the plutonic equivalents of minettes
and that K- and Mg-rich magmas in the Bohemian Massif may have been generated from partial melting of a phlogopite–clinopyroxene-bearing
metasomatized peridotite. Experimental melt compositions also suggest that felsic durbachites can be generated by simple fractionation
of a more mafic parent and mixing with mantle-derived components at mid crustal pressures. 相似文献
944.
Harold Clénet Georges Ceuleneer Patrick Pinet Bénédicte Abily Yves Daydou Esther Harris Isma Amri Céline Dantas 《Lithos》2010,114(3-4):265-281
Using the HyMap instrument, we have acquired visible and near infrared hyperspectral data over the Maqsad area of the Oman ophiolite (~ 15 × 60 km). This survey allowed us to identify and map the distribution of clinopyroxene-rich cumulates (inter-layered clinopyroxenites and wehrlites) whose occurrence was previously undocumented in this area. The cumulates reach several hundred meters in thickness and crop out at distances exceeding 15 km on both sides of the Maqsad former spreading centre. They occur either in mantle harzburgites, as km-sized layered intrusions surrounded by fields of pegmatitic dykes consisting of orthopyroxene-rich pyroxenite and gabbronorites, or at the base of the crustal section where they are conformably overlain by cumulate gabbros. These ultramafic cumulates crystallized from silica- and Mg-rich melts derived from a refractory mantle source (e.g. high Cr#, low [Al2O3], low [TiO2]). These melts are close to high-Ca boninites, although, strictly speaking, not perfect equivalents of present-day, supra-subduction zone, boninites. Chemical stratigraphy reveals cycles of replenishment, mixing and fractional crystallization from primitive (high Mg#) melts, typical of open magma chambers and migration of inter-cumulus melts. The TiO2 content of clinopyroxene is always low (≤ 0.2 wt.%) but quite variable compared to the associated pegmatites that are all derived from a source ultra-depleted in high field strength elements (HFSE). This variability is not caused by fractional crystallization alone, and is best explained by hybridization between the ultra-depleted melts (parent melts of the pegmatites) and the less depleted mid-ocean ridge basalts (MORB) parent of the dunitic–troctolitic–gabbroic cumulates making up the crustal section above the Maqsad diapir.We propose that, following a period of magma-starved spreading, the Maqsad mantle diapir, impregnated with tholeiitic melts of MORB affinity, reached shallow depths beneath the ocean ridge. This diapir induced melting of the formerly accreted and hydrothermally altered lithosphere. At this stage, these boninitic-like lithospheric melts crystallized as pegmatitic dykes. As the diapir continued to rise, the amount of MORB reaching shallow depths increased, together with the surrounding temperature, leading to the formation of magma chambers where the crystallization of layered cumulates became possible. These cumulates remained rich in pyroxene and devoid of plagioclase as long as the contribution of MORB-derived melts was moderate relative to the lithospheric-derived melts. As the contribution of MORB to the refilling of the magma chamber increased, gabbroic cumulates started to crystallize. 相似文献
945.
Thomas Heymes Patrick Monié Nicolas Arnaud Arnaud Pêcher Jean-Pierre Bouillin Roberto Compagnoni 《Lithos》2010,114(3-4):451-472
This study provides new 40Ar/39Ar geochronological constraints on the age of the Alpine tectonics in the Aspromonte Massif (southern part of the Calabrian–Peloritan belt). This massif exposes the upper units of the Calabride Complex which originated from the European continental margin. The Calabride Complex was incorporated in the Alpine orogenic wedge and then integrated into the Apennines and Maghrebides fold-and-thrust belts. Throughout the Calabride Complex there is evidence for a two stage tectonic history, which remains however rather poorly dated: Alpine nappe stacking is followed by extensional reworking along the former thrust contacts or along new detachment surfaces. Our new ages suggest that exhumation of the uppermost units, which accompanied nappe stacking, probably started at 45 Ma and that the deepest units were almost completely exhumed at 33 Ma. This kinematics probably corresponds to syn-orogenic extension while the end of exhumation is clearly related to the extensional tectonics dated at 28.6 Ma along detachment structures.Our geochronological data reveal a very short lag time between accretional and extensional processes in this part of the Mediterranean Alpine orogenic belt. The direction of extension, when the units are restored to their initial position (i.e. before the opening of the Western Mediterranean basins and the bending of the arc) is NNE–SSW. Such a direction does not fit with the eastward slab-retreat model generally put forward to explain extension in the Western Mediterranean. In contrast, we provide evidence for roughly N–S middle Oligocene extension in the accretionary prism, not previously described in this part of the Mediterranean domain. 相似文献
946.
Katharina Marquardt Elena Petrishcheva Rainer Abart Emmanuel Gardés Richard Wirth Ralf Dohmen Hans-Werner Becker Wilhelm Heinrich 《Physics and Chemistry of Minerals》2010,37(10):751-760
In this study, we address volume diffusion of ytterbium in yttrium aluminum garnet (YAG) using thin-film single crystal diffusion
couples. We employ analytical transmission electron microscopy (ATEM) as a tool for combined microstructural and microchemical
analysis and compare the results to Rutherford backscattering (RBS) analysis. Given the high spatial resolution of the method,
we focus on microstructural changes of the thin-film diffusant source during the diffusion anneal. We evaluate the potential
influence of the associated changes in its transport properties on the evolution of concentration profiles in the single crystal
substrate. This approach allows us to test the reliability of determination of volume diffusion coefficients from thin-film
diffusion experiments. We found that for the chosen experimental setting, the influence of thin-film re-crystallization is
small when compared with the experimental uncertainty and good estimates for the volume diffusion coefficients of Yb in YAG
can be obtained using standard assumptions. Both Yb-concentration profiles analyzed with ATEM and with RBS give similar results.
At 1,450°C and 1 bar, we infer log D
Yb (m2/s) values of −19.37 ± 0.07 (TEM) and −19.84 ± 0.02 (RBS). Although the change in thin-film transport properties associated
with successive crystallization during the diffusion anneal does not play a major role for our experimental setup, this effect
cannot generally be ignored. 相似文献
947.
F. A. Lopes G. Michard M. Poulin A. Roué F. Prévot D. Jézéquel E. Viollier 《Aquatic Geochemistry》2010,16(4):587-610
A reactive transport model was developed to describe seasonal variations of biogeochemical and physical processes in Lake
Aydat. The model includes physical processes such as vertical mixing, sedimentation and advection related to inflows into
the lake and biogeochemical conversion processes in the water column and in the sediment surface layer. The reactions described
in the model include primary redox reactions such as primary production, aerobic and anaerobic respiration, methanogenesis
and secondary reactions established between oxidants and reducers produced by the primary reactions. After adjusting various
kinetic constants, the model reasonably reproduced the main features of seasonal variations of dissolved oxygen and nitrate
depth profiles and pH. The reactive transport model was also used to quantify the relative importance of different biogeochemical
pathways. For instance, ferrous denitrification seems to play an important role when stratification is increasing. 相似文献
948.
In this article, an approach for the efficient numerical solution of multi-species reactive transport problems in porous media
is described. The objective of this approach is to reformulate the given system of partial and ordinary differential equations
(PDEs, ODEs) and algebraic equations (AEs), describing local equilibrium, in such a way that the couplings and nonlinearities
are concentrated in a rather small number of equations, leading to the decoupling of some linear partial differential equations
from the nonlinear system. Thus, the system is handled in the spirit of a global implicit approach (one step method) avoiding
operator splitting techniques, solved by Newton’s method as the basic algorithmic ingredient. The reduction of the problem
size helps to limit the large computational costs of numerical simulations of such problems. If the model contains equilibrium
precipitation-dissolution reactions of minerals, then these are considered as complementarity conditions and rewritten as
semismooth equations, and the whole nonlinear system is solved by the semismooth Newton method. 相似文献
949.
Ali Salim Joodi Stanislas Sizaret Stéphane Binet Ary Bruand Patrick Alberic Michel Lepiller 《Hydrogeology Journal》2010,18(2):295-309
Darcy’s law is the equation of reference widely used to model aquifer flows. However, its use to model karstic aquifers functioning with large pores is problematic. The physics occurring within the karstic conduits requires the use of a more representative macroscopic equation. A hydrodynamic model is presented which is adapted to the karstic aquifer of the Val d’Orléans (France) using two flow equations: (1) Darcy’s law, used to describe water flow within the massive limestone, and (2) the Brinkman equation, used to model water flow within the conduits. The flow equations coupled with the transport equation allow the prediction of the karst transfer properties. The model was tested by using six dye tracer tests and compared to a model that uses Darcy’s law to describe the flow in karstic conduits. The simulations show that the conduit permeability ranges from 5?×?10?6 to 5.5?×?10?5?m2 and the limestone permeability ranges from 8?×?10?11 to 6?×?10?10?m2. The dispersivity coefficient ranges from 23 to 53 m in the conduits and from 1 to 5 m in the limestone. The results of the simulations carried out using Darcy’s law in the conduits show that the dispersion towards the fractures is underestimated. 相似文献
950.
The southeast area of the Argentine Pampas is characterized by the presence of an unconfined aquifer in a wide plain. A methodology is proposed that deals with the aquifer vulnerability where the homogeneity of the hydrogeological variables used by traditional methods (in this case, DRASTIC-P) causes vulnerability maps to show more than 80% of the territory under the same class. This absence of discrimination renders vulnerability maps of little use to decision-makers. In addition, the proposed methodology avoids the traditional vague classification (high, low, and moderate vulnerability) which is highly dependent on subjectivity in its association of each class with hydrogeological considerations. That traditional vulnerability assessment methodology was adapted using a geographic information system to reclassify classes, based on the Natural Breaks (Jenks) method. The pixel-to-pixel comparison between the result obtained by the DRASTIC-P and the reclassified classes generates the so-called operational vulnerability index (OVI), which shows four classes, associating each with different hydrogeological requirements to make decisions. 相似文献