(Pre-) historic changes in natural and anthropogenic heavy metals deposition inferred from two contrasting Swiss Alpine lakes

Continuous high-resolution sedimentary record of heavy metals (chromium (Cr), copper (Cu), lead (Pb), zinc (Zn), manganese (Mn), and mercury (Hg)), from lakes Lucerne and Meidsee (Switzerland), provides pollutant deposition history from two contrasting Alpine environments over the last millennia. The distribution of conservative elements (thorium (Th), scandium (Sc) and titanium (Ti)) shows that in absence of human disturbances, the trace element input is primarily controlled by weathering processes (i.e., runoff and erosion). Nonetheless, the enrichment factor (EF) of Pb and Hg (that are measured by independent methods), and the Pb isotopic composition of sediments from the remote lake Meidsee (which are proportionally more enriched in anthropogenic heavy metals), likely detect early mining activities during the Bronze Age. Meanwhile, the deposition of trace elements remains close to the range of natural variations until the strong impact of Roman activities on atmospheric metal emissions. Both sites display simultaneous increases in anthropogenic trace metal deposition during the Greek and Roman Empires (ca 300 BC to AD 400), the Late Middle Ages (ca AD 1400), and the Early Modern Europe (after ca AD 1600). However, the greatest increases in anthropogenic metal pollution are evidenced after the industrial revolution of ca AD 1850, at low and high altitudes. During the twentieth century, industrial releases multiplied by ca 10 times heavy metal fluxes to hydrological systems located on both sides of the Alps. During the last decades, the recent growing contribution of low radiogenic Pb further highlights the contribution of industrial sources with respect to wood and coal burning emissions.     

European summer temperature response to annually dated volcanic eruptions over the past nine centuries

The drop in temperature following large volcanic eruptions has been identified as an important component of natural climate variability. However, due to the limited number of large eruptions that occurred during the period of instrumental observations, the precise amplitude of post-volcanic cooling is not well constrained. Here we present new evidence on summer temperature cooling over Europe in years following volcanic eruptions. We compile and analyze an updated network of tree-ring maximum latewood density chronologies, spanning the past nine centuries, and compare cooling signatures in this network with exceptionally long instrumental station records and state-of-the-art general circulation models. Results indicate post-volcanic June–August cooling is strongest in Northern Europe 2 years after an eruption (?0.52?±?0.05 °C), whereas in Central Europe the temperature response is smaller and occurs 1 year after an eruption (?0.18?±?0.07 °C). We validate these estimates by comparison with the shorter instrumental network and evaluate the statistical significance of post-volcanic summer temperature cooling in the context of natural climate variability over the past nine centuries. Finding no significant post-volcanic temperature cooling lasting longer than 2 years, our results question the ability of large eruptions to initiate long-term temperature changes through feedback mechanisms in the climate system. We discuss the implications of these findings with respect to the response seen in general circulation models and emphasize the importance of considering well-documented, annually dated eruptions when assessing the significance of volcanic forcing on continental-scale temperature variations.     

Variable sequence of events during the past seven terminations in two deep-sea cores from the Southern Ocean

The relationships among internally consistent records of summer sea-surface temperature (SSST), winter sea ice (WSI), and diatomaceous stable isotopes were studied across seven terminations over the last 660 ka in sedimentary cores from ODP sites 1093 and 1094. The sequence of events at both sites indicates that SSST and WSI changes led the carbon and nitrogen isotopic changes in three Terminations (TI, TII and TVI) and followed them in the other four Terminations (TIII, TIV, TV and TVII). In both TIII and TIV, the leads and lags between the proxies were related to weak glacial mode, while in TV and TVII they were due to the influence of the mid-Pleistocene transition. We show that the sequence of events is not unique and does not follow the same pattern across terminations, implying that the processes that initiated climate change in the Southern Ocean has varied through time.     

Strong metal–support interaction as activity requirement of palladium-supported tin oxide sol–gel catalyst for water denitration

Two nanocrystalline palladium-supported tin oxide catalysts for water denitration were synthesized by a modified sol?Cgel technique using appropriate chloride precursors for both support and active phases, and citric acid to tune the rate of hydrolysis and condensation. The difference among sample preparation procedures refers to the moment of the noble metal loading to the support, as well as to the calcination temperature altitude followed. Thus, mesoporous tin oxide was synthesized by a sol?Cgel method following calcination at 700°C. The palladium active phase was introduced afterwards by means of palladium chloride solution impregnation, followed by calcination at 400°C (sample 1). Alternatively, simultaneous complexation of both metal and support precursors followed by single calcination at 700°C was applied for preparation of sample 2. The former sample showed higher activity and selectivity in hydro-denitration of water model system initially containing 100?ppm of nitrates. This was explained by preferential textural, morphological and structural properties accomplished by early contact of metal and support nanoparticles, while achieved by calcination at high single temperature forcing diffusion of palladium ions into the tin oxide matrix. The outcome is very well distribution of palladium and strong metal?Csupport interaction leading to multivalent tin. This indicates partly reduced tin oxide formation in the course of its reduction in hydrogen, which may act as active site in denitration reaction.     

A New Understanding of the Provinces of the Amazon Craton Based on Integration of Field Mapping and U-Pb and Sm-Nd Geochronology

New conventional and sensitive high-resolution ion microprobe zircon U-Pb dating has led to a new understanding of the subdivision and evolution of the Amazon Craton during Precambrian time, with major improvements and changes made to the previous Rb-Sr based model. The interpretation of U-Pb and Sm-Nd isotopic data identifies eight main Precambrian tectonic provinces in the Craton, with ages ranging from 3.1 to 0.99 Ga. Some of the provinces were generated by accretional, arc-related processes (Carajás, Transamazonic, Tapajós-Parima and Rondônia-Juruena) and others by recycling of continental crust (Central Amazon, Rio Negro and Sunsas). The exposed Archean crust is restricted to the east (Carajás and south Amapá in Brazil) and north (Imataca in Venezuela) of the craton, indicating that the Amazon Craton is largely a Proterozoic crust. The Carajás-Imataca (3.10–2.53 Ga) and Transamazonian (2.25–2.00 Ga) Provinces are composed predominantly of granite-greenstone terranes. The Tapajós-Parima (2.10–1.87 Ga) and Rondônia-Juruena (1.75–1.47 Ga) Provinces represent new crust added as orogenic belts, while the Rio Negro (1.86–1.52 Ga) and Sunsas (1.33–0.99 Ga) Provinces originated mainly by magmatic-tectonic recycling of the above two orogenic belts. The only zone with a prominent northeast trend is the poorly known K'Mudku Shear Belt, characterized by a 1.20 Ga shear zone which deforms the rocks of at least three different provinces (Rio Negro, Tapajós-Parima and Transamazonic). The Central Amazon Province comprises mostly Orosirian volcano-plutonic rocks (Uatumã Magmatism) and is a terrane in which the exposed crustal structure and deformation are pluton-related. The Sm-Nd T_DM model ages and _Nd suggest that the Central Amazon Province was generated by the partial melting of Archean continental crust (Carajás Province?), perhaps related to underplating that began at the end of the Tapajós-Parima Orogeny (1.88–1.86 Ga).     

Formation and age of sphalerite mineralization in carbonate rocks of Bajocian age in the Swiss Jura Mountains: evidence of Mesozoic hydrothermal activity

A combination of petrographic and geochemical techniques was applied to better constrain the origin and evolution of the fluid systems responsible for the formation of disseminated, Cd-rich (up to 0.6 wt%), sphalerite (ZnS) mineralization in the northeastern part of the Jura Mountains, Switzerland. The Rb–Sr ages of sphalerite samples indicate that a main phase of sphalerite formation occurred near the boundary between the late Middle and early Late Jurassic, at around 162 Ma. The negative δ³⁴S values (?22.3 to ?5.3 ‰) suggest that biogenic sulfide sulfur was involved in ZnS precipitation. The strontium isotope composition is more radiogenic than that of contemporaneous seawater, reflecting the interaction of mineralizing fluids with silicate rocks. Lead isotope signatures are very uniform (²⁰⁶Pb^/204Pb = 18.63–18.67, ²⁰⁷Pb^/204Pb = 15.63–15.64, ²⁰⁸Pb^/204Pb = 38.51–38.63), indicating an isotopically well-homogenized fluid system. The basement rocks underlying the Jurassic strata are considered to be the main source of metals for the sphalerite mineralization. The migration of deep-sourced hydrothermal saline metal-bearing fluids into the Bajocian host carbonates containing sedimentary reduced sulfur resulted in the precipitation of sulfides. The period of sphalerite formation near the Middle–Late Jurassic boundary is characterized by enhanced tectonic and hydrothermal activity in Europe, related to the opening of the Central Atlantic and tectonic/thermal subsidence during spreading of the Alpine Tethys. Our study provides evidence that the Bajocian carbonate rocks in the Jura Mountains area were affected by the circulation of deep-sourced metal-bearing hydrothermal fluids in response to these continent-wide tectonothermal events. The presence of sphalerite mineralization and associated geochemical anomalies in Zn and Cd contents in carbonate rocks may also be used to trace basement features.     

Polyphase tectonics and late Variscan extension in Austria (Moldanubian Zone,Strudengau area)

New data suggest syn-convergent extrusion and polyphase tectonics followed by late Variscan extension in the Strudengau area of the southern Moldanubian zone in Austria. The tectonic history can be summarized as follows: (1) The oldest ductile event is observed in HT/LP metamorphic pelitic gneisses, which preserve E-dipping foliation planes (D₁-fabric) with NW–SE-trending lineations. (2) The overlying gneisses record HT/HP conditions with decompression-induced anatexis in the central part of the domain. These gneisses exhibit N–S trending, horizontal lineations along steep-dipping foliation planes (D₂-fabric) crosscutting the D₁-fabric of the pelitic gneisses. Along the margin, these rocks have been strongly mylonitized under amphibolite facies conditions (D₂). D₂ is interpreted as a significant vertical shear zone, which juxtaposes the HT/LP rocks against the orogenic lower crust. (3) Lastly, the whole area is overprinted by localized shear zones (D₃-fabric) with top-to-the-NW kinematics. This newly discovered Strudengau shearing event is associated with isoclinal folding that possesses axial planes parallel to the mylonitic foliation and fold axes parallel to the stretching lineations. Initial mylonitization occurred under greenschist facies, representing the latest ductile event of the Strudengau area. The new geochronological data presented here indicate a narrow time frame (c. 323–318 Ma) for the D₃ deformation. Therefore, this event is contemporaneous with the intrusion of the granites of the South Bohemian Batholith (330–310 Ma). The nearby South Bohemian Batholith and generally steep dyke swarms in the Strudengau area and to the north trend in a NE–SW preferred orientation, interpreted to be D₃-synkinematic magmatism. In a regional context, the NW–SE stretching during D₃ together with the synkinematic intrusion of dykes is associated with late orogenic extension in the Austrian Moldanubian Zone. Kinematic data of brittle normal faults and tension gashes are consistent with NW–SE-oriented extension under cooler conditions.     

Radar and infrared observations of binary near-Earth Asteroid 2002 CE26

We observed near-Earth Asteroid (NEA) 2002 CE26 in August and September 2004 using the Arecibo S-band (2380-MHz, 12.6-cm) radar and NASA's Infrared Telescope Facility (IRTF). Shape models obtained based on inversion of our delay-Doppler images show the asteroid to be 3.5±0.4 km in diameter and spheroidal; our corresponding nominal estimates of its visual and radar albedos are 0.07 and 0.24, respectively. Our IRTF spectrum shows the asteroid to be C-class with no evidence of hydration. Thermal models from the IRTF data provide a size and visual albedo consistent with the radar-derived estimate. We estimate the spin-pole to be within a few tens of degrees of λ=317°, β=−20°. Our radar observations reveal a secondary approximately 0.3 km in diameter, giving this binary one of the largest size differentials of any known NEA. The secondary is in a near-circular orbit with period 15.6±0.1 h and a semi-major axis of 4.7±0.2 km. Estimates of the binary orbital pole and secondary rotation rate are consistent with the secondary being in a spin-locked equatorial orbit. The orbit corresponds to a primary mass of M=1.95±0.25×¹⁰¹³ kg, leading to a primary bulk density of , one of the lowest values yet measured for a main-belt or near-Earth asteroid.     

Exoplanet status report: Observation, characterization and evolution of exoplanets and their host stars

After the discovery of more than 400 planets beyond our Solar System, the characterization of exoplanets as well as their host stars can be considered as one of the fastest growing fields in space science during the past decade. The characterization of exoplanets can only be carried out in a well coordinated interdisciplinary way which connects planetary science, solar/stellar physics and astrophysics. We present a status report on the characterization of exoplanets and their host stars by reviewing the relevant space- and ground-based projects. One finds that the previous strategy changed from space mission concepts which were designed to search, find and characterize Earth-like rocky exoplanets to: A statistical study of planetary objects in order to get information about their abundance, an identification of potential target and finally its analysis. Spectral analysis of exoplanets is mandatory, particularly to identify bio-signatures on Earth-like planets. Direct characterization of exoplanets should be done by spectroscopy, both in the visible and in the infrared spectral range. The way leading to the direct detection and characterization of exoplanets is then paved by several questions, either concerning the pre-required science or the associated observational strategy.     

Evaluation of the influence of experimental conditions on H/V results from ambient noise recordings

The H/V-noise technique is now widely used to estimate site effect parameters (fundamental frequency and sometimes the associated soil amplification), and many surveys using this technique have provided convincing results. However, a general agreement on a methodology for data acquisition, data processing and result interpretation has yet to be found. H/V measurements from ambient noise recordings imply both reliability of the results and rapidity of data collection. It is therefore important to understand which experimental conditions (1) influence data quality and reliability, and (2) can help speeding up the recording process. Within the framework of the SESAME European project, a specific task was defined to investigate the reliability of the H/V spectral ratio technique in assessing the site effects. The aim of WP02, one specific Work Package of the SESAME project, is to study the effects of experimental conditions on both stability and reproducibility of H/V results. This study has been conducted in a purely experimental way, by testing the possible influence of various experimental conditions on H/V results both on the frequency peak value and on its amplitude. WP02 results help setting up the experimental conditions under which ambient noise recordings have to be performed in order to provide reproducible, reliable and meaningful H/V results. In this paper we present the results of the WP02 SESAME project concerning the evaluation of the influence of experimental conditions of ambient noise recording on H/V results.