Determining past atmospheric HCl mixing ratios from ice core analyses

Laboratory and field measurements have been performed in order to improve our understanding of the HCl air-snow transfer function. The solubility and diffusion of HCl in laboratory grown single crystals of ice have been measured as a function of HCl partial pressure,P _HCl, between –8 and –25 °C. Measurements ofP _HCl and of the mole fraction of HCl in snow,X'_HCl, have been measured at Summit, Greenland. Comparison of the field and laboratory measurements show that theX'_HCl values are well below equilibrium values. The major processes involved in the formation of snow crystals and in their evolution after deposition are discussed in order to attempt to understand theX'_HCl values and their variations. The discussion is focussed on a few well identified snow layers. It is concluded that sublimation and recrystallization of snow probably play a major role in the evolution ofX'_HCl, but that our understanding of the HCl transfer function is very incomplete. Laboratory and field measurements are suggested to improve this situation.     

Numerical modeling of the Amazon River plume

Marine circulation above the northern Brazilian continental shelf is subject to energetic forcing factors of various origins: high water buoyancy fluxes induced by the Amazon River freshwater discharge, a strong coastal current associated with a mesoscale current (North Brazil Current (NBC)), a forcing by semidiurnal tide and by Northeast or Southeast trade winds according to the season. Using a three-dimensional (3-D) hydrodynamic numerical model (MOBEEHDYCS), and realistic bathymetry and coastline of the northern Brazilian shelf, this paper aims at studying the influence of some specific physical processes on the morphology of the Amazon plume. The very large volume discharge (180 000 m³/s on average) and the weak effect of Coriolis force are additional characteristics of the studied system, which induce a particular dynamics. The various forcing factors are successively introduced into the model in order to simulate and to determine their respective influences upon the plume extent and the hydrodynamics at the shelf scale. Simulation reveal that the coastal current is at the origin of the permanent northwestward Amazon plume extension while wind effect can either reinforce or moderate this situation. The tide intervenes also to modify the position of the salinity front: a horizontal migration of salinity front is observed under its action.     

Sedimentology,mineralogy, and geochemistry of the Late Quaternary Meyghan Playa sediments,NE Arak,Iran: palaeoclimate implications

Playas are shallow ephemeral lakes that form in arid and semi-arid regions. Iran has a large number of playas such as Meyghan Playa, which is located in the northeast of Arak city that borders the central Iran and Sanandaj-Sirjan zones. This study aims to investigate the mineralogical, sedimentological, and geochemical characteristics of the playa sediments. In order to determine the palaeoenvironment, we carried out X-ray diffraction (XRD), X-ray fluorescence (XRF), and scanning electron microscopy (SEM) studies. Meyghan Playa sediments consist of very fine-grained sediments and contain both evaporite and clastic minerals. The evaporite minerals include calcite, gypsum, halite, glauberite, and thenardite, whereas clastic minerals are quartz and clay. The calcite abundance decreases from the margin to the central portion of the playa but gypsum and halite abundances show an increasing trend from the margin to the center. This observation is consistent with the general zonation of other playas. Variations of calcite and gypsum concentration profiles present increasing and decreasing trends with depth, which could be ascribed to the changes in climatic factors. These factors include brine chemical modifications owing to changes in evaporation and precipitation rates and variations in relative abundance of anions-cations or in the rate of clastic and evaporite minerals due to variations in the freshwater influx (climatic changes) with time. A decrease in calcite and increase in sulfate minerals (especially gypsum) with depth is probably due to the higher water level and rainfall, a more humid climate, and salinity variations.     

Potential and limits of double-difference tomographic methods

Double-difference tomographic methods use directly accurate time delays computed between similar signals. Such methods are designed to image very heterogeneous media, such as volcanoes or fault zones. In seismological applications, similar signals are recorded at a given station from earthquakes sharing similar and close-by sources. In seismic exploration experiments, similar signals are often recorded at neighbouring receivers. After a brief presentation of the tomographic algorithm used, a seismological application is summarized. The potential and limits of double-difference tomographic methods are explored using various numerical experiments. They show that two effects are competing in double-difference tomography: (i) the degradation of the stability of the inversion due to the geometrical proximity of the rays used in the differentiation and (ii) the decrease in modelling error, which allows improving the stability of the inversion and using smaller quantities of a priori information when data are sufficiently accurate. The best resolution is obtained for an optimal value of the inter-source or inter-receiver distance. For optimal values of these distances and a priori information, tomography using traveltime differences provides significantly better resolved results than using traveltimes.     

Evolution of the Upper Rhone River discharge and suspended sediment load during the last 80 years and some implications for Lake Geneva

: During this century, the characteristics of the Upper Rhone River discharge, flowing into Lake Geneva, have been altered in response to the changes which have occurred in its watershed. Principally, numerous hydroelectric dams have been constructed on the course of the Rhone River tributaries. At present the major reservoirs can hold about 122010⁶m³ of water, which represents 1/5 of the total annual Rhone River flow. Flow regime characteristics of the river have been modified by the dam operations. Water is released from reservoirs during winter and stored in summer. Large floods have also been reduced in amplitude and frequency. From the available literature data, sediment rating curves have been calculated and used to estimate the evolution of the sediment load from the Rhone River to Lake Geneva. They show that sediment input has decreased by at least a factor 2. This reduction has impacted the occurrence of underflows along the lake bottom, due to the reduction of sediment-laden floods, which in turn may have considerable negative effects on the reoxygenation of Lake Geneva deep waters.     

Terrace reconstruction and long profile projection: a case study from the Solent river system near Southampton,England

River terrace sequences are important frameworks for archaeological evidence and as such it is important to produce robust correlations between what are often fragmentary remnants of ancient terraces. This paper examines both conceptual and practical issues related to such correlations, using a case study from the eastern part of the former Solent River system near Southampton, England. In this region two recent terrace schemes have been constructed using different data to describe the terrace deposits: one based mainly on terrace surfaces; the other on gravel thicknesses, often not recording the terrace surface itself. The utility of each of these types of data in terrace correlation is discussed in relation to the complexity of the record, the probability of post-depositional alteration of surface sediments and comparison of straight-line projections with modern river long profiles. Correlation using age estimates is also discussed, in relation to optically stimulated luminescence dating of sand lenses within terrace gravels in this region during the PASHCC project. It is concluded that the need for replication at single sites means that this approach has limited use for correlative purposes, although dating of sediments is important for understanding wider landscape evolution and patterns of human occupation.     

Chronology of the Lower and Middle Palaeolithic in NW Europe: developer-funded investigations at Dunbridge,Hampshire, southern England

This paper reports important findings relating to the chronology of Palaeolithic occupation, artefact typology and Quaternary fluvial deposits from a geoarchaeological watching brief undertaken over 17 years at Kimbridge Farm Quarry, Dunbridge, Hampshire. Sections were recorded and sampled and 198 artefacts, principally hand axes, were collected, with the primary aim of enhancing understanding of the geological context of the richest Lower Palaeolithic assemblage from Hampshire. Digital terrain modelling was used to characterize the three-dimensional form of the fluvial geology. Two gravel terraces have been confirmed: an upper Belbin Formation, which contained most of the archaeological artefacts, and a lower Mottisfont Formation. Results of specific note included recovery of artefacts demonstrating elements of ‘proto-Levallois’ technology from within the Belbin Gravel deposition. Fully developed Levallois technology was present across both the Belbin Gravel and the Mottisfont Formation at Dunbridge, the latter having an otherwise relatively sparse Palaeolithic content. Previously published OSL dating, supplemented by new data, has been combined with uplift modelling to suggest dates of MIS 9b and MIS 8, respectively, for these two gravels. This fits well with evidence from other sites in England and the near Continent for the timing of the earliest Levallois at around MIS 9. The results from the Dunbridge watching brief have demonstrated that this response provides a relatively cost effective method by which important scientific data can be salvaged from commercial quarrying.