Analytical model of the long-period forced longitude librations of Mercury

The shaking of Mercury’s orbit by the planets forces librations in longitude in addition to those at harmonics of the orbital period that have been used to detect Mercury’s molten core. We extend the analytical formulation of Peale et al. (Peale, S.J., Margot, J.L., Yseboodt, M. [2009]. Icarus 199, 1-8) in order to provide a convenient means of determining the amplitudes and phases of the forced librations without resorting to numerical calculations. We derive an explicit relation between the amplitude of each forced libration and the moment of inertia parameter (B-A)/C_m. Far from resonance with the free libration period, the libration amplitudes are directly proportional to (B-A)/C_m. Librations with periods close to the free libration period of ∼12 years may have measurable (∼arcsec) amplitudes. If the free libration period is sufficiently close to Jupiter’s orbital period of 11.86 years, the amplitude of the forced libration at Jupiter’s period could exceed the 35 arcsec amplitude of the 88-day forced libration. We also show that the planetary perturbations of the mean anomaly and the longitude of pericenter of Mercury’s orbit completely determine the libration amplitudes.While these signatures do not affect spin rate at a detectable level (as currently measured by Earth-based radar), they have a much larger impact on rotational phase (affecting imaging, altimetry, and gravity sensors). Therefore, it may be important to consider planetary perturbations when interpreting future spacecraft observations of the librations.     

New experimental determination of Li and B partition coefficients during upper mantle partial melting

Despite the growing interest for Li and B as geochemical tracers, especially for material transfer from subducting slabs to overlying peridotites, little is known about the behaviour of these two elements during partial melting of mantle sources. In particular, mineral/melt partition coefficients for B and to a lesser extent Li are still a matter of debate. In this work, we re-equilibrated a synthetic basalt doped with ~10 ppm B and ~6 ppm Li with an olivine powder from a spinel lherzolite xenolith at 1 GPa–1,330°C, and we analyzed Li and B in the run products by secondary ion mass spectrometry (SIMS). In our experiment, B behaved as a highly incompatible element with mineral/melt partition coefficients of the order of 10⁻² (D ^ol/melt = 0.008 (0.004–0.013); D ^opx/melt = 0.024 (0.015–0.033); D ^cpx/melt = 0.041 (0.021–0.061)), and Li as a moderately incompatible element (D ^ol/melt = 0.427 (0.418–0.436); D ^opx/melt = 0.211 (0.167–0.256); D ^cpx/melt = 0.246 (0.229–0.264)). Our partition coefficients for Li are in good agreement with previous determinations. In the case of B, our partition coefficients are equal within error to those reported by Brenan et al. (1998) for all the mineral phases analyzed, but are lower than other coefficients from literature for some of the phases (up to 5 times for cpx). Our measurements complement the data set of Ds for modelling partial melting of the upper mantle and basalt generation, and confirm that, in this context, B is more incompatible than previously anticipated.     

Distribution and origin of lead in stream sediments from small agricultural catchments draining Miocene molassic deposits (SW France)

Total Pb concentrations and isotopic composition were determined in stream-bed sediments and bedrock from 29 small agricultural or forested catchments in the Gascogne area (SW France). The contribution of Pb from various natural and anthropogenic sources was investigated in this rural area which is very weakly impacted by industrial or urban emissions. Environmental parameters in catchments (importance of forest cover, organic matter and oxide content in sediments) were considered. A combination of geochemical (enrichment calculation, sequential extraction) and isotopic investigations was performed to constrain the origin of Pb and the distribution of anthropogenic Pb in sediments. Most of the sediments have low total Pb content compared to other agricultural regions more impacted by industrial or urban emissions. The results indicated a moderate but significant Pb enrichment, particularly for catchments draining forested areas. This enrichment was positively related to organic C content in sediment and catchment forest cover, whereas in entirely cultivated catchments it was related to Fe-oxide content.     

MuSET: A multiparameter and high precision sensor for downhole spontaneous electrical potential measurements

On the basis of an existing multiparameter borehole fluid sensor (p, T, Cw, pH, Eh), a new downhole tool designed for 200 bars and 75 °C was developed to measure the spontaneous electrical potential in situ with great precision (better than a μV). To this end, the new sensor is based on the use of unpolarizable Pb/PbCl₂ electrodes either at the surface or downhole. In situ testing has demonstrated a capacity to identify several subsurface sources of natural electrical potential such as diffusion ones (membrane potential in the presence of clays, Fickian processes due to pore fluid salinity gradients), or else the electrokinetic mechanisms with gradients in pore fluid pressure. As a consequence, Multi-Sensors Electrical Tool (MuSET) might be used as an “electrical flowmeter” sensitive to both horizontal and vertical fluid flow in a vertical borehole.     

Iron and other transition metals in Patagonian riverborne and windborne materials: geochemical control and transport to the southern South Atlantic Ocean

The bulk of particulate transition metals transported by Patagonian rivers shows an upper crustal composition. Riverine particulate 0.5 N HCl leachable trace metal concentrations are mainly controlled by Fe-oxides. Complexation of Fe by dissolved organic carbon (DOC) appears to be an important determinant of the phases transporting trace metals in Patagonian rivers. In contrast, aeolian trace elements have a combined crustal and anthropogenic origin. Aeolian materials have Fe, Mn, and Al contents similar to that found in regional topsoils. However, seasonal concentrations of some metals (e.g., Co, Pb, Cu, and Zn) are much higher than expected from normal crustal weathering and are likely pollutant derived.We estimate that Patagonian sediments are supplied to the South Atlantic shelf in approximately equivalent amounts from the atmosphere (∼30 × 10⁶ T yr⁻¹) and coastal erosion (∼40 × 10⁶ T yr⁻¹) with much less coming from the rivers (∼2.0 × 10⁶ T yr⁻¹). Low trace metal riverine fluxes are linked to the low suspended particulate load of Patagonian rivers, inasmuch most of it is retained in pro-glacial lakes as well as in downstream reservoirs. Based on our estimation of aeolian dust fluxes at the Patagonian coastline, the high nutrient-low chlorophyll sub Antarctic South Atlantic could receive 1.0 to 4.0 mg m⁻² yr⁻¹ of leachable (0.5 N HCl) Fe. Past and present volcanic activity in the southern Andes—through the ejection of tephra—must be highlighted as another important source of Fe to the South Atlantic Ocean. Based on the 1991 Hudson volcano eruption, it appears that volcanic events can contribute several thousand-fold the mass of “leachable” Fe to the ocean as is introduced by annual Patagonian dust fallout.     

The problem of regionalization among geographers: the case of Switzerland

The lack of any unified view amongst geographers in their conceptions of the articulation of Swiss space is evidence, in the dialectical sense, of the complexity of the reality. It is also, however, a sympton of methodological uncertainty. The purpose of this article is an analysis of this malaise, usually passed over in silence.The evolution of geography during the last hundred years cannot be easily defined, but against a general trend opposed approaches have always been present.The manner of conceiving Swiss space is still affected by the changes in the physiognomy of the country, but the analysis of reality and reality itself are out of phase.It appears possible that the presuppositions admitted by authors or the intellectual paths followed by them in regionalisation should be considered and treated as one of the fundamentals of all studies concerned with the organisation of space.     

Le volcanisme cambrien du Maroc central : implications géodynamiques

In southeastern Central Morocco, the Bou-Acila volcanic complex is considered of Cambrian age. In spite of low-grade metamorphic effect, initial volcanic texture and mineralogy can be recognized and volcanic rocks are dominated by dolerites and porphyric dolerites. The initial mineralogy is composed of plagioclases, pyroxenes and dark minerals. A secondary mineral assemblage is composed of albite, epidote, chlorite and calcite. According to their immobile elements compositions, the southeastern central Morocco metavolcanites are of within-plate continental tholeiites. This volcanism and those recognized in many other areas in Morocco confirm a Cambrian extensive episode within the Gondwana supercontinent. To cite this article: H. Ouali et al., C. R. Geoscience 335 (2003).To cite this article: H. Ouali et al., C. R. Geoscience 335 (2003).     

New strategies to detect life on Mars

If we are to find unequivocal evidence for life on Mars, we will need new ways to search for it. Jeff L Bada and the MOD team describe the innovative strategy developed for the ExoMars mission.     

Determining past atmospheric HCl mixing ratios from ice core analyses

Laboratory and field measurements have been performed in order to improve our understanding of the HCl air-snow transfer function. The solubility and diffusion of HCl in laboratory grown single crystals of ice have been measured as a function of HCl partial pressure,P _HCl, between –8 and –25 °C. Measurements ofP _HCl and of the mole fraction of HCl in snow,X'_HCl, have been measured at Summit, Greenland. Comparison of the field and laboratory measurements show that theX'_HCl values are well below equilibrium values. The major processes involved in the formation of snow crystals and in their evolution after deposition are discussed in order to attempt to understand theX'_HCl values and their variations. The discussion is focussed on a few well identified snow layers. It is concluded that sublimation and recrystallization of snow probably play a major role in the evolution ofX'_HCl, but that our understanding of the HCl transfer function is very incomplete. Laboratory and field measurements are suggested to improve this situation.