The East Caledonian Current: A Case Example for the Intercomparison between AltiKa and In Situ Measurements in a Boundary Current

This paper presents an assessment of SARAL/AltiKa satellite altimeter for the monitoring of a tropical western boundary current in the south-western Pacific Ocean: the East Caledonian Current. We compare surface geostrophic current estimates obtained from two versions of AltiKa along-track sea level height (AVISO 1 Hz and PEACHI 40 Hz) with two kinds of dedicated in situ datasets harvested along the satellite ground tracks: one deep-ocean current-meter mooring deployed in the core of the boundary current and five glider transects. It is concluded that the AltiKa-derived current successfully captures the velocity of the boundary current, with a standard error of 11 cm/s with respect to the in situ data. It also appears important to reference AltiKa sea level anomaly to the latest mean dynamic topography available in our area. Doing so, Ka-band altimetry provides a satisfactory representation of the western boundary current. Thereby, it usefully contributes to observing its variability in such a remote and under-observed ocean region. However, the rather long repeat period of SARAL (35 days) in comparison to the high frequency variability seen in the flow velocity of the boundary current calls for a combined use of SARAL with the other satellite altimetry missions.     

Solubility measurements of synthetic neodymium monazite as a function of temperature at 2 kbars, and aqueous neodymium speciation in equilibrium with monazite

The solubility of synthetic NdPO₄ monazite end-member was experimentally determined from 300 up to 800 °C, at 2000 bars in pure water, and in aqueous chloride or phosphate solutions. Both the classical weight-loss method and a new method based on isotope dilution coupled with thermal ionization mass spectrometer were used. In the range of temperature studied monazite showed a prograde solubility from 10^−5.4 m at 300 °C up to 10^−2.57 m at 800 °C. Experiments in H₂O-H₃PO₄-NaCl-HCl solutions suggested Nd(OH)₃⁰ was the major species that was formed at high temperature and pressure. The equilibrium constants (log K) for the reaction:

     

The impact of vegetation on fractionation of rare earth elements (REE) during water–rock interaction

Previous studies on waters of a streamlet in the Vosges mountains (eastern France) have shown that Sr and rare earth elements (REE) principally originate from apatite dissolution during weathering. However, stream water REE patterns normalized to apatite are still depleted in light REE (LREE, La–Sm) pointing to the presence of an additional LREE depleting process. Speciation calculations indicate that complexation cannot explain this additional LREE depletion. In contrast, vegetation samples are strongly enriched in LREE compared to water and their Sr and Nd isotopic compositions are comparable with those of apatite and waters. Thus, the preferential LREE uptake by the plants at the root–water–soil (apatite) interface might lead to an additional LREE depletion of the waters in the forested catchment. Mass balance calculations indicate that the yearly LREE uptake by vegetation is comparable with the LREE export by the streamlet and, therefore, might be an important factor controlling the LREE depletion in river waters.     

Quartz fabric evidence for early Pan-African penetrative east-directed shearing in the Itremo Supracrustal Group of central Madagascar

ABSTRACT The Pan-African orogeny left a strong imprint on the basement rocks of Madagascar, which were metamorphosed up to granulite facies conditions. The supracrustal Itremo Group of central Madagascar, comprising quartzites, schists and carbonates of lower metamorphic grade, has to date been described as a folded sedimentary sequence. Despite their fine-grained 'sugary' appearance, most quartzites are plastically deformed tectonites. Quartzite microstructures are mainly of the elongate mosaic type, indicating significant grain boundary migration, and are compatible with dynamic recrystallization under lower amphibolite facies conditions. Consistent asymmetric quartz c -axis fabrics indicate a dominant top-to-the-east shear sense. Hence, the Itremo quartzites bear evidence for a major eastward-directed tectonic event of Pan-African age, possibly resulting from an early Pan-African thrust motion. Younger deformational events, responsible for localized mylonites with top-to-the-WSW sense of motion and N–S-trending folds and shear zones, were superimposed on this first fabric.     

Radioisotopic evidence of perturbations of recent sedimentary record in lakes: a word of caution for climate studies

The rate of climatic change estimated from the gradient of signals recorded in lake sediments may be erroneous if post-depositional perturbations are overlooked. A smear out of a pulse signal, over a variable thickness of core section, due to physical or biological mixing, is a well known phenomena. Much less attention is paid to a possible overestimation of the rate of change when a part of record is missing due to an erosion event. In this paper we show a few examples of recent lake sediment perturbations and the resulting distortions in the time scale, as documented by short-lived radionuclides.Contribution to Clima Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate Program     

Two examples of subaqueously welded ash-flow tuffs: the Visean of southern Vosges (France) and the Upper Cretaceous of northern Anatolia (Turkey)

Pyroclastic deposits interpreted as subaqueous ash-flow tuff have been recognized within Archean to Recent marine and lacustrine sequences. Several authors proposed a high-temperature emplacement for some of these tuffs. However, the subaqueous welding of pyroclastic deposits remains controversial.The Visean marine volcaniclastic formations of southern Vosges (France) contain several layers of rhyolitic and rhyodacitic ash-flow tuff. These deposits include, from proximal to distal settings, breccia, lapilli and fine-ash tuff. The breccia and lapilli tuff are partly welded, as indicated by the presence of fiamme, fluidal and axiolitic structures. The lapilli tuff form idealized sections with a lower, coarse and welded unit and an upper, bedded and unwelded fine-ash tuff. Sedimentary structures suggest that the fine-ash tuff units were deposited by turbidity currents. Welded breccias, interbedded in a thick submarine volcanic complex, indicate the close proximity of the volcanic source. The lapilli and fine-ash tuff are interbedded in a thick marine sequence composed of alternating sandstones and shales. Presence of a marine stenohaline fauna and sedimentary structures attest to a marine depositional environment below storm-wave base.In northern Anatolia, thick massive sequences of rhyodacitic crystal tuff are interbedded with the Upper Cretaceous marine turbidites of the Mudurnu basin. Some of these tuffs are welded. As in southern Vosges, partial welding is attested by the presence of fiamme and fluidal structures. The latter are frequent in the fresh vitric matrix. These tuff units contain a high proportion of vitroclasis, and were emplaced by ash flows. Welded tuff units are associated with non-welded crystal tuff, and contain abundant bioclasts which indicate mixing with water during flowage. At the base, basaltic breccia beds are associated with micritic beds containing a marine fauna. The welded and non-welded tuff sequences are interbedded in an alternation of limestones and marls. These limestones are rich in pelagic microfossils.The evidence above strongly suggest that in both examples, tuff beds are partly welded and were emplaced at high temperature by subaqueous ash flows in a permanent marine environment. The sources of the pyroclastic material are unknown in both cases. We propose that the ash flows were produced during submarine fissure eruptions. Such eruptions could produce non-turbulent flows which were insulated by a steam carapace before deposition and welding. The welded ash-flow tuff deposits of southern Vosges and northern Anatolia give strong evidence for existence of subaqueous welding.     

Magnetic transition at 30–34 Kelvin in pyrrhotite: insight into a widespread occurrence of this mineral in rocks

A characteristic magnetic transition at 30–34 K is shown to provide a powerful tool for the identification of pyrrhotite with concentration down to 10 ppm through the same low-temperature techniques as applied to magnetite and hematite, extended down to liquid helium temperature. A review of rock magnetic and petrological data on pyrrhotite suggests that this mineral should be considered as a major carrier of paleomatnetic signals. Unblocking temperature up to 350°C and extreme resistance against AF may be encountered in fine grained pyrrhotite.