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71.
The global composition of the early solar system is thought to be roughly chondritic in terms of refractory components, and this means that metal and silicate should be present together in early planetesimals. To fully understand the metal-silicate differentiation process within the eucrite parent body (EPB), it is important to try and identify the metal reservoir that is complementary to the silicate part. The isotope 182 of tungsten (W), a siderophile element, is partly formed from the decay of 182Hf, and W isotopes are useful for examining metal-silicate segregation. The W isotopic composition expected for the metal that is complementary to eucrites falls in the range of iron meteorites. However, mesosiderites seem to be genetically linked to eucrites based on petrologic and oxygen isotopic similarities. Therefore, we undertook the analysis of the metal phase of these stony-irons. Here we present tungsten isotopic data for mesosiderite and pallasite metal to characterize their parent body (bodies) and to assess possible relationships with eucrites.All stony-iron metals are depleted in radiogenic tungsten by −1.3 to −4.2 ε units, relative to the terrestrial standard, while chondrites, for comparison, are depleted by −1.9 ε units. In addition to W isotopic heterogeneity from one stony-iron to another, there is also W isotopic heterogeneity within individual meteorites. A formation model is tentatively proposed, where we show that mesosiderites, pallasites, and eucrites could possibly come from the same parent body. Several hypotheses are discussed to explain the isotopic heterogeneity: the production of cosmogenic tungsten, the in situ decay of hafnium present in inclusions, and tungsten diffusion processes after metal-silicate mixing during the cooling of the meteorites. The two latter hypotheses provide the best explanation of our data. 相似文献
72.
Peter van der Beek Xavier Robert Jean-Louis Mugnier Matthias Bernet Pascale Huyghe Erika Labrin 《Basin Research》2006,18(4):413-434
Thermochronological analysis of detrital sediments derived from the erosion of mountain belts and contained in the sedimentary basins surrounding them allows reconstructing the long-term exhumation history of the sediment source areas. The effective closure temperature of the thermochronological system analysed determines the spatial and temporal resolution of the analysis through the duration of the lag time between closure of the system during exhumation and its deposition in the sedimentary basin. Here, we report apatite fission-track (AFT) data from 31 detrital samples collected from Miocene to Pliocene stratigraphic sections of the Siwalik Group in western and central Nepal, as well as three samples from modern river sediments from the same area, that complement detrital zircon fission-track (ZFT) and U–Pb data from the same samples presented in a companion paper. Samples from the upper part of the stratigraphic sections are unreset and retain a signal of source-area exhumation; they show spatial variations in source-area exhumation rates that are not picked up by the higher-temperature systems. More deeply buried samples have been partially reset within the Siwalik basin and provide constraints on the thermal and kinematic history of the fold-and-thrust belt itself. The results suggest that peak source-area exhumation rates have been constant at ∼1.8 km Myr−1 over the last ∼7 Ma in central Nepal, whereas they ranged between 1 and ∼1.5 km Myr−1 in western Nepal over the same time interval; these spatial variations may be explained by either a tectonic or climatic control on exhumation rates, or possibly a combination of the two. Increasing lag times within the uppermost part of the sections suggest an increasing component of apatites that have been recycled within the Siwalik belt and are corroborated by AFT ages of modern river sediment downstream as well as the record of the distal Bengal Fan. The most deeply buried and most strongly annealed samples record onset of exhumation of the frontal Siwaliks along the Himalayan frontal thrust at ∼2 Ma and continuous shortening at rates comparable with the present-day shortening rates from at least 0.3 Ma onward. 相似文献
73.
At present the most powerful tree-ring based climate reconstructions use high numbers of growth proxy series (ring width and density) to produce spatially smoothed estimates, such as average Northern Hemisphere summer temperatures. These single parameter reconstructions might be supplemented with regional climate reconstructions capable of capturing variability in more than one climate variable without lower replication compromising statistical quality, if multiple tree ring proxies were used. Pinus sylvestris and Pinus uncinata latewood density, width and δ13C series are presented from two sites in the French subalpine zone, east of Briançon. Where two proxies have the same dominant climate control their combination enhances that signal. Where proxies differ in dominant controlling climate variable, combining series allows access to bi-variable calibrations. Using this approach, multi-proxy reconstructions of both temperature and precipitation would better reflect complex synoptic variability in climate on spatially useful scales. 相似文献
74.
Henri J. Dumont Christine Cocquyt Michel Fontugne Maurice Arnold Jean-Louis Reyss Jan Bloemendal Frank Oldfield Cees L.M. Steenbergen Henk J. Korthals Barbara A. Zeeb 《Journal of Paleolimnology》1998,20(4):409-422
We reconstruct aspects of the history of Easter Island over the last 4-5 centuries based on the study of a core from Rano Raraku Lake, situated in the crater that contains the quarry of the island's giant statues or moai. We use microfossils of plants and animals to identify five zones. The last three of these are separated by waves of immigration from South America and from the subantarctic. We argue that the first or South American wave, dated to the second half of the 14th century, may represent a visit by South American Indians. Magnetic information, pollen, diatoms, chrysophyte stomatocysts and fossil plant pigments reveal a synchronism between the South American contact and the cessation of moai quarrying. We therefore suggest that Amerindians contributed to the cultural collapse of the island. The second or subantarctic wave may reflect an early European visit to the island, possibly by Cpt. James Cook in 1774, or by Jacob Roggeveen in 1722. 相似文献
75.
A well-developed subglacial drainage system consisting of large cavities developed in the lee of bedrock steps connected together by a network of Nye channels is exposed on an area of recently deglaciated limestone bedrock in front of Glacier de Tsanfleuron, Switzerland. This system covers some 51 per cent of the bedrock surface area, and is believed to have transported the bulk of supraglacially-derived meltwaters through the glacier. Using the cavity hydraulics model of Kamb (1987), it is shown that the geometry of the system rendered it stable against collapse by meltback of channel roofs into a tunnel-dominated system. For likely combinations of glacier geometry and meltwater discharge, the steady state water pressure in this system would have been only a small fraction of that required for flotation, and for discharges of less than about 0·5–5 m3 s?1 water would have flowed at atmospheric pressure. The system appears to have adjusted to varying discharges by a combination of varying water pressure and changing the total cross-sectional area of flow by altering the number of active channels connecting cavities. Glacier sliding velocity would have been independent of meltwater discharge for discharges at which water flowed at atmospheric pressure, but would have risen with increasing discharge for higher flows. Velocities on the order of 0·1 m d?1 are predicted for a realistic range of discharges and effective pressures, and these are believed to be plausible. Episodes of enhanced sliding in glaciers with similar drainage systems could be triggered by a rise in meltwater discharge across the threshold between flows at atmospheric pressure and flow under pressure from the glacier. 相似文献
76.
J.L Reyss N Lemaitre T.L Ku V Marchig J.R Southon D.E Nelson J.S Vogel 《Geochimica et cosmochimica acta》1985,49(11):2401-2408
Attempts have been made to study the entire growth history of a manganese nodule from the northern part of Peru Basin in the Pacific using radiochemical profiles of , , and . Combined with the observations on Fe-Mn contents and textural variation, the radiochemical data indicate that the nodule grew more or less concentrically throughout most of its existence since it formed 1.5 my ago, receiving Mn from both bottom water and pore water. This condition appeared to have changed about 180 ky ago when the growth became asymmetric in that the top and bottom sides became fixed in their relative positions on the sea floor. Since then, the bottom side accreted with a fast rate of close to 200 mm/my, apparently fueled by the supply of diagenetically remobilized Mn in pore water from the sediment substrate. In the meantime, the top side accumulated at about 6 mm/my, a value which is in the normal range for deep-sea nodules having their Mn supplied from the hydrogenous source. 相似文献
77.
Kazuaki Nakamura Vincent Renard Jacques Angelier Jacques Azema Jacques Bourgois Christine Deplus Kantaro Fujioka Yozo Hamano Philippe Huchon Hajimu Kinoshita Pierre Labaume Yujiro Ogawa Tetsuzo Seno Akira Takeuchi Manabu Tanahashi Akinori Uchiyama Jean-Louis Vigneresse 《Earth and Planetary Science Letters》1987,83(1-4)
Leg 2 of the French-Japanese 1984 Kaiko cruise has surveyed the Suruga and the Sagami Troughs, which lie on both sides of the northwestward moving and colliding Izu-Bonin Ridge, the northernmost part of the Philippine Sea plate. The transition from the Nankai Trough to the Suruga Trough is characterized by northward decrease in width of the accretionary prism, in good agreement with the increasing obliquity between the through axis and the direction of the convergence, as the strike of the convergent boundary changes from ENE-NNE to south-north. South of the area, the southern margin of the Zenisu Ridge shows contractional deformations. This supports the interpretation made by the team of Leg 1 who studied the western extension of the area we studied, that it is an intra-oceanic thrusting of the ridge over the Shikoku Basin. In the Sagami Trough, where the relative motion is highly oblique to the plate boundary, active subduction is mostly confined in the east-west trending portions of the trough located south of the Boso Peninsula and along the lower Boso Canyon, near the TTT triple junction. In between, the present motion is mainly right-lateral along the northwest trending Boso escarpment. However, an inactive but recent (Pliocene to lower Pleistocene) accretionary prism exists south of the Boso escarpment, which suggests that the relative motion was more northerly than at present before about 1 Ma ago. 相似文献
78.
Françoise Roger Jean-Patrick Respaut Maurice Brunel Philippe Matte Jean-Louis Paquette 《Comptes Rendus Geoscience》2004,336(1):19-28
We present new U–Pb results on felsic Augen orthogneisses from the Axial Zone of the Montagne Noire (French Massif Central). The data indicate Ordovician ages, 456±3 and 450±6 Ma for two samples collected at ‘Pont-de-Larn’ and ‘Gorges d'Héric’, respectively. These ages are interpreted as the igneous emplacement age of the granitic protolith. To cite this article: F. Roger et al., C. R. Geoscience 336 (2004). 相似文献
79.
Gleb S PokrovskiDenis Testemale Jean-Louis HazemannAndrew Y.u Bychkov Galina V Golikova 《Geochimica et cosmochimica acta》2002,66(19):3453-3480
The stoichiometry and stability of arsenic gaseous complexes were determined in the system As-H2O ± NaCl ± HCl ± H2S at temperatures up to 500°C and pressures up to 600 bar, from both measurements of As(III) and As(V) vapor-liquid and vapor-solid partitioning, and X-ray absorption fine structure (XAFS) spectroscopic study of As(III)-bearing aqueous fluids. Vapor-aqueous solution partitioning for As(III) was measured from 250 to 450°C at the saturated vapor pressure of the system (Psat) with a special titanium reactor that allows in situ sampling of the vapor phase. The values of partition coefficients for arsenious acid (H3AsO3) between an aqueous solution (pure H2O) and its saturated vapor (K = mAsvapor /mAsliquid) were found to be independent of As(III) solution concentrations (up to ∼1 to 2 mol As/kg) and equal to 0.012 ± 0.003, 0.063 ± 0.023, and 0.145 ± 0.020 at 250, 300, and 350°C, respectively. These results are interpreted by the formation, in the vapor phase, of As(OH)3(gas), similar to the aqueous As hydroxide complex dominant in the liquid phase. Arsenic chloride or sulfide gaseous complexes were found to be negligible in the presence of HCl or H2S (up to ∼0.5 mol/kg of vapor). XAFS spectroscopic measurements carried out on As(III)-H2O (±NaCl) solutions up to 500°C demonstrate that the As(OH)3 complex dominates As speciation both in dense H2O-NaCl fluids and low-density supercritical vapor. Vapor-liquid partition coefficients for As(III) measured in the H2O-NaCl system up to 450°C are consistent with the As speciation derived from these spectroscopic measurements and can be described by a simple relationship as a function of the vapor-to-liquid density ratio and temperature. Arsenic(III) partitioning between vapor and As-concentrated solutions (>2 mol As/kg) or As2O3 solid is consistent with the formation, in the vapor phase, of both As4O6 and As(OH)3. Arsenic(V) (arsenic acid, H3AsO4) vapor-liquid partitioning at 350°C for dilute aqueous solution was interpreted by the formation of AsO(OH)3 in the vapor phase.The results obtained were combined with the corresponding properties for the aqueous As(III) hydroxide species to generate As(OH)3(gas) thermodynamic parameters. Equilibrium calculations carried out by using these data indicate that As(OH)3(gas) is by far the most dominant As complex in both volcanic gases and boiling hydrothermal systems. This species is likely to be responsible for the preferential partition of arsenic into the vapor phase as observed in fluid inclusions from high-temperature (400 to 700°C) Au-Cu (-Sn, -W) magmatic-hydrothermal ore deposits. The results of this study imply that hydrolysis and hydration could be also important for other metals and metalloids in the H2O-vapor phase. These processes should be taken into account to accurately model element fractionation and chemical equilibria during magma degassing and fluid boiling. 相似文献
80.
High Precision Hf-W Isotopic Measurements in Meteoritic Material Using Negative Thermal Ionisation Mass Spectrometry (NTIMS) 总被引:1,自引:0,他引:1
Ghylaine Quitté Jean-Louis Birck Françoise Capmas Claude J. Allègre 《Geostandards and Geoanalytical Research》2002,26(2):149-160
This paper presents a two-stage anion-exchange procedure for tungsten extraction, an improved mass spectrometric procedure for tungsten analysis and a simplified chemical separation and TIMS procedure for the determination of Hf concentrations. The chemical separation of tungsten is based on its complexing properties with HF and H2 O2 . The blank level for a sample size of 300 mg is about 80 pg for tungsten. The procedure is designed for the high sensitivity of negative thermal ionisation mass spectrometry (NTIMS) provided by the use of Mg oxide as an emitter on Ir filaments. Tungsten can be readily measured with a high precision in various meteoritical material and especially in small W-poor silicate fractions. Samples containing as little as a few ng g-1 tungsten can be analysed reliably with this method. 相似文献